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The use of solid-state electrolytes to provide safer, next-generation rechargeable batteries is becoming more feasible as new materials with greater stability and higher ionic diffusion coefficients are designed. However, accurate…

Materials Science · Physics 2021-01-08 Ardeshir Baktash , James C. Reid , Tanglaw Roman , Debra J. Searles

Isothermal-isobaric molecular dynamics simulations are used to examine the microscopic structure and principal thermodynamic properties of a model solution consisting of NaCl salt dissolved in methanol solvent. Four united atom force fields…

Soft Condensed Matter · Physics 2020-05-26 M. Cruz Sanchez , H. Dominguez , O. Pizio

With the importance of Li-ion and emerging alternative batteries to our electric future, predicting new sustainable materials, electrolytes and complete cells that safely provide high performance, long life, energy dense capability is…

Materials Science · Physics 2022-07-26 Alex Grant , Colm O'Dwyer

Electrokinetic flows of an aqueous NaCl solution in nanochannels with negatively charged surfaces are studied using molecular dynamics (MD) simulations. The four transport coefficients that characterise the response to weak electric and…

Chemical Physics · Physics 2014-06-05 Hiroaki Yoshida , Hideyuki Mizuno , Tomoyuki Kinjo , Hitoshi Washizu , Jean-Louis Barrat

This paper addresses different aspects of "coupled" model descriptions in computational electromagnetics. This includes domain decomposition, multiscale problems, multiple or hybrid discrete field formulation and multi-physics problems.…

Computational Engineering, Finance, and Science · Computer Science 2023-03-16 Markus Clemens , Sebastian Schöps , Carsten Cimala , Nico Gödel , Simon Runke , Daniel Schmidthäusler , Thomas Timm

Microfluidic fuel cells (MFCs) are microfluidic electrochemical conversion devices that are used to power small pieces of electrical equipment. Their performance relies on the improvement of the mass transfer of the reactants at the…

The dynamics of the electrons for a molecule in solution is coupled to the dynamics of its polarizable environment, i.e., the solvent. To theoretically investigate such electronic dynamics, we have recently developed equations of motion…

Chemical Physics · Physics 2017-02-16 Silvio Pipolo , Stefano Corni , Roberto Cammi

Lithium-ion (Li-ion) batteries are ubiquitous in modern energy storage systems, highlighting the critical need to comprehend and optimize their performance. Yet, battery models often exhibit poor parameter identifiability which hinders the…

Systems and Control · Electrical Eng. & Systems 2024-06-14 Jorge Espin , Yuichi Kajiura , Dong Zhang

We explored the composition dependence of a rather comprehensive set of properties of liquid water-ethanol mixtures by using the isobaric-isothermal molecular dynamics computer simulations. The united atom non-polarizable model from the…

Soft Condensed Matter · Physics 2024-07-02 D. Benavides Bautista , M. Aguilar , O. Pizio

In this paper, we address the problem of online parameter estimation of a Proton Exchange Membrane Fuel Cell (PEMFC) polarization curve, that is the static relation between the voltage and the current of the PEMFC. The task of designing…

Signal Processing · Electrical Eng. & Systems 2023-08-15 Carlo Beltran , Alexey Bobtsov , Romeo Ortega , Diego Langarica-Cordoba , Rafael Cisneros , Luis H. Diaz-Saldierna

LiFePO4-based cathodes suffer from various degradation mechanisms which influences the battery performance. In this paper morphological and structural degradation phenomena in laboratory cathodes made of LiFePO4 (LFP) mixed with carbon…

Molecular dynamics simulations have been used extensively to determine equilibrium properties of the electrode-electrolyte interface in supercapacitors held at various potentials. While such studies are essential to understand and optimize…

Soft Condensed Matter · Physics 2024-02-26 Nicolas Gaudy , Mathieu Salanne , Céline Merlet

Two theory-driven models of electron ionization cross sections, the Binary-Encounter-Bethe model and the Deutsch-M\"ark model, have been design and implemented; they are intended to extend the simulation capabilities of the Geant4 toolkit.…

Computational Physics · Physics 2010-12-06 H. Seo , M. G. Pia , P. Saracco , C. H. Kim

The paper presents results and discussion of electron dynamics in molecules in which intense ultrafast pulse drives multiphoton ionization, high harmonic generation, and charge resonance due to the Rabbi flopping in the regime of Charge…

Atomic Physics · Physics 2025-08-15 L. Bauerle , A. Jaron

The simulation of borosilicate glasses is challenging due to the composition and temperature dependent coordination state of boron atoms. Here, we present a newly developed machine learning optimized classical potential for molecular…

Disordered Systems and Neural Networks · Physics 2025-11-20 Kai Yang , Ruoxia Chen , Anders K. R. Christensen , Mathieu Bauchy , N. M. Anoop Krishnan , Morten M. Smedskjaer , Fabian Rosner

Electrode polarization error is the biggest problem when measuring the low frequency dielectric properties of electrolytes or suspensions of particles, including cells, in electrolytes. We present a simple and robust method to remove the…

Soft Condensed Matter · Physics 2008-05-13 Camelia Prodan , Corina Bot

The question of if silica nanoparticles can enhance the ionic conductivity of a polymer electrolyte above its crystallization temperature has remained unclear for the two decades following the first experiments on these systems. We use…

Soft Condensed Matter · Physics 2024-02-29 Joel Martin Dalmas , Ambroise van Roekeghem , Natalio Mingo , Stefano Mossa

Electrochemical and equivalent-circuit modelling are the two most popular approaches to battery simulation, but the former is computationally expensive and the latter provides limited physical insight. A theoretical middle ground would be…

Chemical Physics · Physics 2020-06-05 Valentin Sulzer , S. Jon Chapman , Colin P. Please , David A. Howey , Charles W. Monroe

Lithium-ion batteries are widely used in electric vehicles and grid energy storage systems. Compared to cylindrical batteries, prismatic cells are the primary choice because of their advantage for dense packing. However, thermal runaway and…

Applied Physics · Physics 2024-07-23 Mehdi V. Bozorg , Juan F. Torres

We use a coarse-grained molecular dynamics model to study the electrophoretic behaviour of flexible polyelectrolyte chains. We first characterize the static properties of the model with respect to the chain length, the polyelectrolyte…

Soft Condensed Matter · Physics 2008-12-16 Kai Grass , Christian Holm
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