Related papers: Heat capacity of dense liquids: A link between two…
The original Rosenfeld-Tarazona (RT) scaling of the excess energy in simple dense fluids predicts a $\propto T^{3/5}$ thermal correction to the fluid Madelung energy. This implies that the excess isochoric heat capacity scales as $C_{\rm…
We investigate the accuracy of the expression of Rosenfeld and Tarazona (RT) for the excess isochoric heat capacity, C_V^{ex} \propto T^{-2/5}, for eighteen model liquids. Previous investigations have reported no unifying features of…
Two-length-scale pair potentials arise ubiquitously in condensed matter theory as effective interparticle interactions in molecular, metallic and soft matter systems. The existence of two different bond lengths generated by the shape of…
Using a distinguishable-particle lattice model based on void-induced dynamics, we successfully reproduce the well-known linear relation between heat capacity and temperature at very low temperatures. The heat capacity is dominated by…
Supercooled liquids are characterized by relaxation times that increase dramatically by cooling or compression. Many liquids have been shown to obey power-law density scaling, according to which the relaxation time is a function of density…
Anomalous temperature dependence of heat capacity of glassy systems during a cooling-heating cycle has remained an ill-understood problem for a long time. Most of the features observed in the experimental measurement of the heat capacity of…
A reliable model of viscosity in liquids using a dual liquid model framework is developed. The analytical expression arrived at exhibits the correct T-dependence Arrhenius-like. It is compared with the values of viscosity for water with…
Many glass-forming fluids exhibit a remarkable thermodynamic scaling in which dynamic properties, such as the viscosity, the relaxation time, and the diffusion constant, can be described under different thermodynamic conditions in terms of…
This work studies the heat equation in a two-phase material with spherical inclusions. Under some appropriate scaling on the size, volume fraction and heat capacity of the inclusions, we derive a coupled system of partial differential…
It is shown that measured heat capacity depends on the rate of the temperature variation and on the initial state of a system. It is calculated here in the framework of two-level model. Fenomenological approach gives the same results.
Understanding thermodynamics in liquids at the atomic level is challenging because of strong atomic interactions and lack of symmetry. Recent prior theoretical works have focused on describing heat capacity of liquids in terms of…
Rosenfeld [Phys. Rev. A 15, 2545 (1977)] noticed that casting transport coefficients of simple monatomic, equilibrium fluids in specific dimensionless forms makes them approximately single-valued functions of excess entropy. This has…
It is shown that the isochoric heat capacity of dense gas, fluid and liquid decreases with increasing temperature at arbitrary values of a density for many pair interaction potentials, including bonded potentials; that a decrease of the…
A central question concerning glass-formation has been what governs the kinetic arrest of the quenched liquid - cooling reduces the thermal energy which molecules need to surmount local potential barriers, while the accompanying volume…
A solvable turbulent model is used to predict both the structure of the boundary layer and the scaling laws in thermal convection. The transport of heat depends on the interplay between the thermal, viscous and integral scales of…
We have used the generalized two-atom ideal gas model in Tsallis statistics for the statistical description of a real gas. By comparing the heat capacity with the experimental results for the two-atom molecule gases such as N2, O2 and CO,…
Strongly correlated amorphous solids are a class of glass-formers whose inter-particle potential admits an approximate inverse power-law form in a relevant range of inter-particle distances. We study the steady-state plastic flow of such…
Liquids displaying strong virial-potential energy correlations conform to an approximate density scaling of their structural and dynamical observables. This scaling property does not extend to the entire phase diagram, in general. The…
In this paper, we consider mathematical modeling and numerical simulation of non-isothermal compressible multi-component diffuse-interface two-phase flows with realistic equations of state. A general model with general reference velocity is…
A number of crystal structures of water have been `superheated' in Monte Carlo simulations. Two well known models for water were considered; namely the TIP4P model and the SPC/E model. By comparing the fluid-solid coexistence temperature to…