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An ultimate goal of electron paramagnetic resonance (EPR) spectroscopy is to analyze molecular dynamics in place where it occurs, such as in a living cell. The nanodiamond (ND) hosting nitrogen-vacancy (NV) centers will be a promising EPR…

Electron paramagnetic resonance spectroscopy (EPR) is among the most important analytical tools in physics, chemistry, and biology. The emergence of nitrogen-vacancy (NV) centers in diamond, serving as an atomic-sized magnetometer, has…

Quantum Physics · Physics 2020-06-01 Fei Kong , Pengju Zhao , Pei Yu , Zhuoyang Qin , Zhehua Huang , Zhecheng Wang , Mengqi Wang , Fazhan Shi , Jiangfeng Du

Paramagnetic magnetic resonance, a powerful technique for characterizing and identifying chemical targets, is increasingly used for imaging; however, low spin polarization at room temperature and moderate magnetic fields poses challenges…

Mesoscale and Nanoscale Physics · Physics 2019-09-04 C. M. Purser , V. P. Bhallamudi , C. S. Wolfe , H. Yusuf , B. A. McCullian , C. Jayaprakash , M. E. Flatté , P. C. Hammel

We present an alternative to conventional Electron Paramagnetic Resonance (EPR) spectroscopy equipment. Avoiding the use of bulky magnets and magnetron equipment, we use the photoluminescence of an ensemble of Nitrogen-Vacancy centers at…

Applied Physics · Physics 2023-03-08 C. Mignon , A. R. Ortiz Moreno , H. Shirzad , S. K. Padamati , V. Damle , Y. Ong , R. Schirhagl , M. Chipaux

A key limitation of electron paramagnetic resonance (EPR), an established and powerful tool for studying atomic-scale biomolecular structure and dynamics is its poor sensitivity, samples containing in excess of 10^12 labeled biomolecules…

A nitrogen-vacancy (NV) center in diamond is a promising sensor for nanoscale magnetic sensing. Here we report electron spin resonance (ESR) spectroscopy using a single NV center in diamond. First, using a 230 GHz ESR spectrometer, we…

Mesoscale and Nanoscale Physics · Physics 2016-10-05 Chathuranga Abeywardana , Viktor Stepanov , Franklin H. Cho , Susumu Takahashi

High concentration of negatively charged nitrogen-vacancy ($\text{NV}^{-}$) centers was created in diamond single crystals containing approximately 100 ppm nitrogen using electron and neutron irradiation and subsequent thermal annealing in…

Spectral analysis of electron spin resonance (ESR) is a powerful technique for various investigations including characterization of spin systems, measurements of spin concentration, and probing spin dynamics. The nitrogen-vacancy (NV)…

Mesoscale and Nanoscale Physics · Physics 2019-07-19 Benjamin Fortman , Susumu Takahashi

Nitrogen-vacancy (NV) center in diamond is a promising quantum sensor with remarkably versatile sensing capabilities. While scanning NV magnetometry is well-established, NV electrometry has been so far limited to bulk diamonds. Here we…

Quantum Physics · Physics 2022-10-12 Ziwei Qiu , Assaf Hamo , Uri Vool , Tony X. Zhou , Amir Yacoby

Nitrogen-vacancy (NV) centers in diamond have shown promise as inherently localized electric-field sensors, capable of detecting individual charges with nanometer resolution. Working with NV ensembles, we demonstrate that a detailed…

Quantum Physics · Physics 2021-09-28 M. Block , B. Kobrin , A. Jarmola , S. Hsieh , C. Zu , N. L. Figueroa , V. M. Acosta , J. Minguzzi , J. R. Maze , D. Budker , N. Y. Yao

Solid state spins in diamond, in particular negatively charged nitrogen-vacancy centers (NV), are leading contenders in the field of quantum sensing. While addressing of single NVs offers nanoscale spatial resolution, many implementations…

Quantum Physics · Physics 2023-01-11 Yuchun Zhu , Elena Losero , Christophe Galland , Valentin Goblot

The application of magnetic resonance (MR) spectroscopy at progressively smaller length scales may eventually permit "chemical imaging" of spins at the surfaces of materials and biological complexes. In particular, the negatively charged…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 Hai-Jing Wang , Chang S. Shin , Scott J. Seltzer , Claudia E. Avalos , Alexander Pines , Vikram S. Bajaj

Substitutional nitrogen atoms in a diamond crystal (P1 centers) are, on one hand, a resource for creation of nitrogen-vacancy (NV) centers, that have been widely employed as nanoscale quantum sensors. On the other hand, P1's electron spin…

Nitrogen-vacancy (NV) quantum defects in diamond are sensitive detectors of magnetic fields. Due to their atomic size and optical readout capability, they have been used for magnetic resonance spectroscopy of nanoscale samples on diamond…

High frequency electron spin resonance (ESR) spectroscopy is an invaluable tool for identification and characterization of spin systems. Nanoscale ESR using the nitrogen-vacancy (NV) center has been demonstrated down to the level of a…

Mesoscale and Nanoscale Physics · Physics 2020-05-05 Benjamin Fortman , Junior Pena , Karoly Holczer , Susumu Takahashi

We propose an original analog method to perform instantaneous and quantitative spectral analysis of microwave signals. An ensemble of nitrogen-vacancy (NV) centers held in a diamond plate is pumped by a 532 nm laser. Its photoluminescence…

Materials Science · Physics 2016-01-20 M. Chipaux , L. Toraille , C. Larat , L. Morvan , S. Pezzagna , J. Meijer , T. Debuisschert

Many applications of nitrogen-vacancy (NV) centers in diamond crucially rely on a spectrally narrow and stable optical zero-phonon line transition. Though many impressive proof-of-principle experiments have been demonstrated, much work…

Quantum Physics · Physics 2021-07-21 Albert Liu , Steven T. Cundiff , Diogo B. Almeida , Ronald Ulbricht

Nitrogen vacancy (NV) centers in diamond have been used as ultrasensitive magnetometers to perform nuclear magnetic resonance (NMR) spectroscopy of statistically polarized samples at 1 - 100 nm length scales. However, the spectral linewidth…

The nitrogen-vacancy (NV) center in diamond is a solid-state spin defect that has been widely adopted for quantum sensing and quantum information processing applications. Typically, experiments are performed either with a single isolated NV…

Quantum Physics · Physics 2025-03-19 Matthew Cambria , Saroj Chand , Caitlin Reiter , Shimon Kolkowitz

Using an optical tweezers apparatus, we demonstrate three-dimensional control of nanodiamonds in solution with simultaneous readout of ground-state electron-spin resonance (ESR) transitions in an ensemble of diamond nitrogen-vacancy (NV)…

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