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We present an exact many-body framework for electrostatic interactions among $N$ arbitrarily charged spheres in an electrolyte, modeled by the linearized Poisson--Boltzmann equation. Building on a spectral analysis of nonstandard…

Soft Condensed Matter · Physics 2025-12-12 Sergii V. Siryk , Walter Rocchia

We present a fully analytical integration of the Maxwell stress tensor and derive exact relations for interparticle forces in systems of multiple dielectric spheres immersed in a polarizable ionic solvent, within the framework of the…

Soft Condensed Matter · Physics 2025-12-12 Sergii V. Siryk , Walter Rocchia

The interaction of particles in an electrolytic medium can be calculated by solving the Poisson equation inside the solutes and the linearized Poisson--Boltzmann equation in the solvent, with suitable boundary conditions at the interfaces.…

Soft Condensed Matter · Physics 2025-12-12 Sergii V. Siryk , Walter Rocchia

This paper builds on two previous works, Lindgren et al. J. Comp. Phys. 371, 712-731 (2018) and Quan et al. arXiv:1807.05384 (2018), to devise a new method to solve the problem of calculating electrostatic interactions in a system composed…

Soft Condensed Matter · Physics 2019-02-20 Eric B. Lindgren , Chaoyu Quan , Benjamin Stamm

In this work we derive a systematic short-range expansion of the many-body wave function. At leading order, the wave function is factorized to a zero-energy $s$-wave correlated pair and spectator particles, while terms that include energy…

Nuclear Theory · Physics 2023-07-13 Ronen Weiss , Diego Lonardoni , Stefano Gandolfi

Understanding the many-body dynamics of isolated quantum systems is one of the central challenges in modern physics. To this end, the direct experimental realization of strongly correlated quantum systems allows one to gain insights into…

We investigate theoretically polyelectrolyte bridging interactions on the two-body level. The model system is composed of two macroions with two oppositely charged flexible chains. The electrostatic interactions are treated on the Debye -…

Soft Condensed Matter · Physics 2009-11-10 Rudi Podgornik

We present a formal derivation of the many-body perturbation theory for a system of electrons and bosons subject to a nonlinear electron-boson coupling. The interaction is treated at an arbitrary high order of bosons scattered. The…

Strongly Correlated Electrons · Physics 2018-08-15 Andrea Marini , Yaroslav Pavlyukh

The electron-phonon interaction plays a crucial role in many fields of physics and chemistry. Nevertheless, its actual calculation by means of modern many-body perturbation theory is weakened by the use of model Hamiltonians that are based…

Materials Science · Physics 2015-05-15 Andrea Marini , Samuel Poncé , Xavier Gonze

We report various many-body theoretical approaches to the nonlinear decay rate and energy loss of charged particles moving in an interacting free electron gas. These include perturbative formulations of the scattering matrix, the…

Materials Science · Physics 2009-11-07 T. del Rio Gaztelurrutia , J. M. Pitarke

We study the superradiance dynamics in a dense system of atoms each of which can be generally a spin-$j$ particle with $j$ an arbitrary half-integer. We generalize Dicke's superradiance point of view to multiple-level systems, and compare…

Quantum Physics · Physics 2012-05-28 G. -D. Lin , S. F. Yelin

Free classical particles have well-defined momentum and position, while free quantum particles have well-defined momentum but a position fully delocalized over the sample volume. We develop a many-body formalism based on wave-packet…

Quantum Physics · Physics 2017-11-07 Aurélia Chenu , Monique Combescot

We review methods that allow one to detect and characterise quantum correlations in many-body systems, with a special focus on approaches which are scalable. Namely, those applicable to systems with many degrees of freedom, without…

Quantum Physics · Physics 2023-09-28 Irénée Frérot , Matteo Fadel , Maciej Lewenstein

Crystallization is a generic phenomenon in classical and quantum mechanics arising in a variety of physical systems. In this work we focus on a specific platform, ultracold dipolar bosons, which can be realized in experiments with dilute…

Quantum Gases · Physics 2018-12-31 Tommaso Macrì , Fabio Cinti

The Many-Body Expansion (MBE) is a useful tool to simulate condensed phase chemical systems, often avoiding the steep computational cost of usual electronic structure methods. However, it often requires higher than 2-body terms to achieve…

Chemical Physics · Physics 2019-11-21 Srimukh Prasad Veccham , Joonho Lee , Martin Head-Gordon

An effective pair potential for systems of uniformly charged lamellar colloids in the presence of an electrolytic solution of microscopic co- and counterions is derived. The charge distribution on the discs is expressed as a collection of…

Soft Condensed Matter · Physics 2009-10-31 D. G. Rowan , J. -P. Hansen , E. Trizac

In this thesis we study the lateral electrostatic interaction between a pair of non-identical, moderately charged colloidal particles trapped at an electrolyte interface in the limit of short inter-particle separations. Using a simplified…

Soft Condensed Matter · Physics 2017-10-17 Timo Schmetzer

We derive the multiparticle-correlation expansion of the excess entropy of classical particles in the canonical ensemble using a new approach that elucidates the rationale behind each term in the expansion. This formula provides the…

Statistical Mechanics · Physics 2011-10-25 S. Prestipino , P. V. Giaquinta

The electrostatic potential of a highly charged disc (clay platelet) in an electrolyte is investigated in detail. The corresponding non-linear Poisson-Boltzmann (PB) equation is solved numerically, and we show that the far-field behaviour…

Soft Condensed Matter · Physics 2009-11-10 R. Agra , E. Trizac , L. Bocquet

A survey is presented of various aspects of the interaction of charged particles with solids. In the framework of many-body perturbation theory, we study the nonlinear interaction of charged particles with a free gas of interacting…

Materials Science · Physics 2015-06-24 J. M. Pitarke , I. G. Gurtubay , V. U. Nazarov
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