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Phonon modes found in low frequency Raman scattering from $CdS_{1-x}Se_x$ nanocrystals embedded in borosilicate glass arising from confined acoustic phonons are investigated. In addition to the breathing modes and quadrupolar modes, two…

Materials Science · Physics 2008-03-10 Sanjeev K. Gupta , Satyaprakash Sahoo , Prafulla K. Jha , A. K. Arora , Y. M. Azhniuk

We calculate low-frequency Raman scattering from the confined acoustic phonon modes of CdS1-xSex nanoparticles embedded in borosilicate glass. The calculation of the Raman scattering by acoustic phonons in nanoparticles has been performed…

Mesoscale and Nanoscale Physics · Physics 2009-04-16 Sanjeev K. Gupta , Prafulla K. Jha , Satyaprakash Sahoo , A. K. Arora , Y. M. Azhniuk

Extreme confinement of electromagnetic energy by phonon polaritons holds the promise of strong and new forms of control over the dynamics of matter. To bring such control to the atomic-scale limit, it is important to consider phonon…

Mesoscale and Nanoscale Physics · Physics 2019-05-01 Nicholas Rivera , Thomas Christensen , Prineha Narang

We present the vibrational properties and phonon dispersion for quasi-2D hybrid organic-inorganic perovskites (BA)$_2$CsPb$_2$I$_7$, (HA)$_2$CsPb$_2$I$_7$, (BA)$_2$(MA)Pb$_2$I$_7$, and (HA)$_2$(MA)Pb$_2$I$_7$ calculated from first…

Materials Science · Physics 2024-01-23 Emily Y. Chen , Bartomeu Monserrat

Halide perovskites are a promising class of materials for optoelectronic applications, due to their excellent optoelectronic performance. However, they suffer several dynamical degradation problems, the characterization of which is…

Materials Science · Physics 2021-11-01 Sander Raaijmakers , Mike Pols , José Manuel Vicent-Luna , Shuxia Tao

Two-dimensional hybrid organic-inorganic metal halide perovskites offer enhanced stability for perovskite-based applications. Their crystal structure's soft and ionic nature gives rise to strong interactions between charge carriers and…

A comparative analysis of two Raman line-shape functions has been carried out to validate the true representation of experimentally observed Raman scattering data for semiconducting nanomaterials. A modified form of already existing phonon…

Spin-phonon interactions are one of the mechanisms limiting the lifetime of spin qubits made in semiconductor quantum dots. At variance with other mechanisms such as charge noise, phonons are intrinsic to the device and can hardly be…

Mesoscale and Nanoscale Physics · Physics 2020-08-19 Jing Li , Benjamin Venitucci , Yann-Michel Niquet

Phonons are quasiparticles associated with mechanical vibrations in materials. They are at the root of the propagation of sound and elastic waves, as well as of thermal phenomena, which are pervasive in our everyday life and in many…

The assignment of an exact space group to the tetragonal CH$_3$NH$_3$PbI$_3$ perovskite structure is experimentally challenging and controversial in the literature. Average orientation of the methylammonium ion that gives symmetry to the…

Materials Science · Physics 2023-01-27 Kuntal Talit , David A. Strubbe

We present Raman and terahertz absorbance spectra of methylammonium lead halide single crystals (MAPbX3, X = I, Br, Cl) at temperatures between 80 and 370 K. These results show good agreement with density-functional-theory phonon…

The soft modes associated with continuous-order phase transitions are associated with strong anharmonicity. This leads to the overdamped limit where the phonon quasi-particle picture can breakdown. However, this limit is commonly restricted…

Materials Science · Physics 2023-10-10 Erik Fransson , Petter Rosander , Fredrik Eriksson , J. Magnus Rahm , Terumasa Tadano , Paul Erhart

Inspired by concepts developed for fermionic systems in the framework of condensed matter physics, topology and topological states are recently being explored also in bosonic systems. The possibility of engineering systems with…

We investigate the influence of three- and four-phonon scattering, perturbative anharmonic phonon renormalization, and off-diagonal terms of coherent phonons on the thermal conductivity of CsPbBr3 phase change perovskite, by using advanced…

Materials Science · Physics 2023-06-27 Xiaoying Wang , Zhibin Gao , Guimei Zhu , Jie Ren , Lei Hu , Jun Sun , Xiangdong Ding , Yi Xia , Baowen Li

The temperature dependence below $T_{c}$ of the lineshape of optical phonons of different symmetry as seen in Raman scattering is investigated for superconductors with anisotropic energy gaps. It is shown that the symmetry of the…

Condensed Matter · Physics 2009-10-22 T. P. Devereaux

Understanding the phase behavior of mixed-cation halide perovskites is critical for optimizing their structural stability and optoelectronic performance. Here, we map the phase diagram of MA$_{1-x}$FA$_x$PbI$_3$ using a machine-learned…

Materials Science · Physics 2025-03-31 Tobias Hainer , Erik Fransson , Sangita Dutta , Julia Wiktor , Paul Erhart

Perovskite nanoplatelets possess extremely narrow absorption and emission linewidths, which are crucial characteristics for many optical applications. However, their underlying intrinsic and extrinsic line-broadening mechanisms are poorly…

Halide perovskite has attracted intense research interest owing to its multifaceted and versatile applications in optoelectronics. This intrigue is further fueled by their propensity to undergo intricate structural modifications under…

Exciton transport in 2D semiconductors holds promise for room-temperature, ultra-compact optoelectronic devices, but it is limited by short propagation distances. Hybridization of excitons with cavity photons to form exciton-polaritons can…

Mesoscale and Nanoscale Physics · Physics 2025-07-08 Jamie M. Fitzgerald , Roberto Rosati , Ermin Malic

Metal halide perovskites have emerged as an exciting class of materials for applications in solar energy harvesting, optical devices, catalysis, and other photophysical applications. Many of the exciting properties of halide perovskites are…

Materials Science · Physics 2024-04-18 Colin M. Hylton-Farrington , Richard C. Remsing