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We present a full ab-inito description of the coupled out-of-equilibrium dynamics of photons, phonons, and electrons. In the present approach the quantised nature of the electromagnetic field as well as of the nuclear oscillations is fully…

Mesoscale and Nanoscale Physics · Physics 2015-12-24 Pedro Melo , Andrea Marini

The first-principles calculation of contributions of phonon and electron excitations to free formation, binding, and migration energies of defects is illustrated in the case of bcc-Fe. First of all, the ground state properties of the…

Materials Science · Physics 2015-08-11 D. Murali , M. Posselt , M. Schiwarth

Phonon quasi-particles have been monumental in microscopically understanding thermodynamics and transport properties in condensed matter for decades. Phonons have one-to-one correspondence with harmonic eigenstates and their energies are…

Materials Science · Physics 2024-08-27 Jaeyun Moon , Leo Zella , Lucas Lindsay

Phase-space electronic structure theory offers up a new and powerful approach for tackling problems with coupled nuclear-electronic dynamics in a fashion that goes beyond Born-Oppenheimer (BO) theory. Whereas BO theory stipulates that we…

The renormalization of electronic eigenenergies due to electron-phonon coupling is sizable in many materials with light atoms. This effect, often neglected in ab-initio calculations, can be computed using the perturbation-based…

We investigate Born-Oppenheimer breakdown (BOB) effects (beyond the usual mass scaling) for the electronic ground states of a series of homonuclear and heteronuclear alkali-metal diatoms, together with the Sr$_2$ and Yb$_2$ diatomics.…

Chemical Physics · Physics 2017-01-04 Jesse J. Lutz , Jeremy M. Hutson

We consider electron-phonon (\textit{e-ph}) energy loss rate in 3D and 2D multi-component electron systems in semiconductors. We allow general asymmetry in the \textit{e-ph} coupling constants (matrix elements), i.e., we allow that the…

Disordered Systems and Neural Networks · Physics 2009-11-11 Mika Prunnila

We present a method to efficiently combine the computation of electron-electron and electron-phonon self-energies, which enables the evaluation of electron-phonon coupling at the $G_0W_0$ level of theory for systems with hundreds of atoms.…

Materials Science · Physics 2021-12-14 Han Yang , Marco Govoni , Arpan Kundu , Giulia Galli

The harmonic approximation of ionic fluctuations and the linear coupling between phonons and electrons provide the standard framework to compute, from first principles, the contribution of nuclear dynamics and its interaction with electrons…

Materials Science · Physics 2026-03-04 Raffaello Bianco , Ion Errea

We describe an approach for calculations of phonon contributions to the electron spectral function, including both quasiparticle properties and satellites. The method is based on a cumulant expansion for the retarded one-electron Green's…

Materials Science · Physics 2015-06-22 S. M. Story , J. J. Kas , F. D. Vila , M. J. Verstraete , J. J. Rehr

We have recently employed periodic Anderson model with electron-phonon interactions to describe Cerium volume collapse ($\gamma \rightarrow \alpha$ transition) under pressure. To describe the volume collapse transition in Cerium, we have…

Strongly Correlated Electrons · Physics 2019-08-20 Enzhi Li

In recent years, there has been a push to go beyond Born-Oppenheimer theory and build electronic states from a phase space perspective, i.e. parameterize electronic states by both nuclear position(R) and nuclear momentum(P). Previous…

Chemical Physics · Physics 2025-06-11 Xinchun Wu , Xuezhi Bian , Jonathan Rawlinson , Robert G. Littlejohn , Joseph E. Subotnik

We present a universal expression for the electronic friction as felt by a set of classical nuclear degrees of freedom (DoF's) coupled to a manifold of quantum electronic DoF's; no assumptions are made regarding the nature of the electronic…

Materials Science · Physics 2017-08-02 Wenjie Dou , Gaohan Miao , Joseph E. Subotnik

Molecular motion at metallic surfaces is affected by nonadiabatic effects and electron-phonon coupling. The ensuing energy dissipation and dynamical steering effects are not captured by classical molecular dynamics simulations, but can be…

Materials Science · Physics 2021-12-02 Connor L. Box , Wojciech G. Stark , Reinhard J. Maurer

Structural phase transitions are accompanied by a movement of one nucleus (or a few) in the crystallographic unit cell. If the nucleus movement is continuous, a second order phase transition without latent heat results, whereas an abrupt…

Statistical Mechanics · Physics 2024-09-04 Mario Graml , Kurt Hingerl

Describing the dynamics of nuclei in molecules requires a potential energy surface, which is traditionally provided by the Born-Oppenheimer or adiabatic approximation. However, we also need to assign masses to the nuclei. There, the…

It is argued that the nonintegrably singular energy density of the electron's electromagnetic field (in both the classical point-charge model and quantum electrodynamics) must entail very strong self-gravitational effects, which, via black…

High Energy Physics - Theory · Physics 2009-09-25 S. K. Kauffmann

Microscopic processes giving the energy gain and loss of a two-dimensional electron system in long-range potential fluctuations are studied theoretically at the breakdown of the quantum Hall effect in the case of even-integer filling…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Hiroshi Akera

The renormalization of electronic eigenenergies due to electron-phonon interactions (temperature dependence and zero-point motion effect) is important in many materials. We address it in the adiabatic harmonic approximation, based on first…

In this paper, we investigate the electron self-energy and effective mass in a single heterostructure using Green-function method. Numerical calculations of the electron self-energy and effective mass for GaAs/AlAs heterostructure are…

Materials Science · Physics 2009-11-07 Xiu-Kun Hua , Yin-Zhong Wu , Zhen-Ya Li