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A multiscale QM/classical approach is presented, that is able to model the optical properties of complex nanostructures composed of a molecular system adsorbed on metal nanoparticles. The latter are described by a combined…

Chemical Physics · Physics 2024-10-29 Pablo Grobas Illobre , Piero Lafiosca , Luca Bonatti , Tommaso Giovannini , Chiara Cappelli

In this work we study the strong confinement effects on the electromagnetic response of metallic nanoparticles. We calculate the field enhancement factor for nanospheres of various radii by using optical constants obtained from both…

Mesoscale and Nanoscale Physics · Physics 2018-02-20 Mario Zapata-Herrera , Jefferson Flórez , Angela Camacho , Hanz Y. Ramirez

We study the plasmonic properties of arrays of atomic chains which comprise noble (Cu, Ag, and Au) and transition (Pd, Pt) metal atoms using time-dependent density-functional theory. We show that the response to the electromagnetic…

Mesoscale and Nanoscale Physics · Physics 2018-10-02 Kevin Conley , Neha Nayyar , Tuomas P. Rossi , Mikael Kuisma , Volodymyr Turkowski , Martti Puska , Talat S. Rahman

Localized-surface plasmon resonance is of importance in both fundamental and applied physics for the subwavelength confinement of optical field, but realization of quantum coherent processes is confronted with challenges due to strong…

Quantum Physics · Physics 2017-12-13 Pai Peng , Yong-Chun Liu , Da Xu , Qi-Tao Cao , Qihuang Gong , Yun-Feng Xiao

We develop a perturbative approach for calculating, within the quasistatic approximation, the shift of surface resonances in response to a deformation of a dielectric volume. Our strategy is based on the conversion of the homogeneous system…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 Daniel Grieser , Hannes Uecker , Svend-Age Biehs , Oliver Huth , Felix Rüting , Martin Holthaus

From a structural point of view, plasmonic nanoparticles are always at least two-layer structures with a dielectric layer of stabilizing, targeting, fluorescent, Raman, or other functional molecules. To optimize the optical properties of…

Optics · Physics 2025-05-13 Nikolai G. Khlebtsov , Sergey V. Zarkov

Surface plasmons on metals can concentrate light into sub-nanometric volumes and on these near atomic length scales the electronic response at the metal interface is smeared out over a Thomas-Fermi screening length. This nonlocality is a…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Yu Luo , A. I. Fernandez-Dominguez , Aeneas Wiener , S. A. Maier , J. B. Pendry

In this work, we present a fully quantum theory of the plasmonic nanolaser, based on the maser model. Theory can be applied both to the microlasers with high Q-factor cavities and plasmonic nanolasers. We show that the latter is essentially…

Mesoscale and Nanoscale Physics · Physics 2013-04-01 I. Fyodorov , A. Sarychev

Optical properties of metallic nanoparticles are most often considered in terms of plasmons, the coupled states of light and quasi-free electrons. Here we predict that confinement of electrons inside the nanostructure leads to another, very…

We investigate the dynamics of a plasmonic oscillation over a metal nanoparticle when it is strongly coupled to a quantum emitter (e.g. quantum dot, molecule). We simulate the density matrix evolution for a simple model; coupled…

Optics · Physics 2013-08-27 Mehmet Emre Tasgin

Plasmonic phenomena are exhibited in light-matter interaction involving materials whose real parts of permittivity functions attain negative values at operating wavelengths. However, such materials usually suffer from dissipative losses,…

Materials Science · Physics 2016-06-22 Cristian Della Giovampaola , Nader Engheta

The polarizability of a nanostructure is an important parameter that determines the optical properties. An exact semi-analytical solution of the electrostatic polarizability of a general geometry consisting of two segments forming a…

Optics · Physics 2015-06-04 Jesper Jung , Thomas G. Pedersen

We study the electromagnetic behaviour of dense, spherical clusters made of hundreds of plasmonic nanoparticules under illumination by a plane wave. Using high-precision T-matrix numerical calculations, we compute the multipolar response of…

Plasmonic resonances in metallic nanoparticles are exploited to create efficient optical filtering functions. A Finite Element Method is used to model metallic nanoparticles gratings. The accuracy of this method is shown by comparing…

Quasi-crystals are intriguing as they exhibit rotational symmetry and long range ordering but lack translational symmetry. 2-dimensional metal-dielectric patterns are interesting to make use of surface plasmon polariton (SPP) mediated local…

We report theoretical evidence that bulk nonlinear materials weakly interacting with highly localized plasmonic modes in ultra-sub-wavelength metallic nanostructures can lead to nonlinear effects at the single plasmon level in the visible…

Mesoscale and Nanoscale Physics · Physics 2017-04-27 Filippo Alpeggiani , Stefania D'Agostino , Daniele Sanvitto , Dario Gerace

The electrostatic interaction between metal spheres is an influential component in the assembly of many nanoscale materials in chemistry. Here we derive a method to calculate the energy and polarizations of metal spheres in arbitrary…

Mesoscale and Nanoscale Physics · Physics 2010-10-15 Alexander Moore

Nanostructured metamaterials, especially arrays of metallic nanoparticles which sustain the excitation of localized plasmon polaritons, provide excellent opportunities to mold the flow of light in the linear regime. We suggest a…

Optics · Physics 2009-11-13 C. Rockstuhl , C. R. Simovski , S. A. Tretyakov , F. Lederer

Quantum effects play a significant role in nanometric plasmonic devices, such as small metal clusters and metallic nanoshells. For structures containing a large number of electrons, ab-initio methods such as the time-dependent density…

Mesoscale and Nanoscale Physics · Physics 2018-09-27 Giovanni Manfredi , Paul-Antoine Hervieux , Fatema Tanjia

We study the interaction of focused radially-polarized light with metal nanospheres. By expanding the electromagnetic field in terms of multipoles, we gain insight on the excitation of localized surface plasmon-polariton resonances in the…

Optics · Physics 2009-11-13 Nassiredin M. Mojarad , Mario Agio