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In this article, we propose a generalized model for nonequilibrium vibrational energy distribution functions. The model can be used, in place of equilibrium (Boltzmann) distribution functions, when deriving reaction rate constants for…

Chemical Physics · Physics 2020-07-15 Narendra Singh , Thomas Schwartzentruber

Despite well over a century of effort, the proper expression for the classical entropy in statistical mechanics remains a subject of debate. The Boltzmann entropy (calculated from a surface in phase space) has been criticized as not being…

Statistical Mechanics · Physics 2017-09-12 Robert H. Swendsen

We investigate the behavior in $N$ of the $N$--particle entropy functional for Kac's stochastic model of Boltzmann dynamics, and its relation to the entropy function for solutions of Kac's one dimensional nonlinear model Boltzmann equation.…

Probability · Mathematics 2008-08-26 E. A. Carlen , M. C. Carvalho , J. Le Roux , M. Loss , C. Villani

In this communication, the derivation of the Boltzmann-Gibbs and the Maxwellian distributions is presented from a geometrical point of view under the hypothesis of equiprobability. It is shown that both distributions can be obtained by…

Chaotic Dynamics · Physics 2010-01-20 Ricardo Lopez-Ruiz , Jaime Sanudo , Xavier Calbet

Statistical entropies of a general relativistic ideal gas obeying Maxwell-Boltzmann, Bose-Einstein and Fermi-Dirac statistics are calculated in a general axisymmetry space-time of arbitrary dimension. This general formation can be used to…

General Relativity and Quantum Cosmology · Physics 2007-05-23 S. Q. Wu , X. Cai

In the setting of the principle of local equilibrium which asserts that the temperature is a function of the energy levels of the system, we exhibit plenty of steady states describing the condensation of free Bosons which are not in thermal…

Mathematical Physics · Physics 2016-06-22 Luigi Accardi , Francesco Fidaleo

We show through a nonlinear Fokker-Planck formalism, and confirm by molecular dynamics simulations, that the overdamped motion of interacting particles at T=0, where T is the temperature of a thermal bath connected to the system, can be…

Statistical Mechanics · Physics 2011-02-08 J. S. Andrade , G. F. T. da Silva , A. A. Moreira , F. D. Nobre , E. M. F. Curado

A way to construct Boltzmann entropy, i.e., the entropy as a function of a microscopic pure state, for quantum field systems is proposed. Operators that shift the field in wavevector space are used in the construction. By employing an…

Statistical Mechanics · Physics 2020-03-25 Kyo Yoshida

The Renyi entropy with a free Renyi parameter $q$ is the most justified form of information entropy, and the Tsallis entropy may be regarded as a linear approximation to the Renyi entropy when $q\simeq 1$. When $q\to 1$, both entropies go…

Statistical Mechanics · Physics 2007-05-23 Andrei G. Bashkirov

Based on the q-exponential distribution which has been observed in more and more physical systems, the varentropy method is used to derive the uncertainty measure of such an abnormal distribution function. The uncertainty measure obtained…

Mathematical Physics · Physics 2010-09-07 Congjie Ou , Aziz El Kaabouchi , Qiuping A. Wang , Jincan Chen

As early as 1902, Gibbs pointed out that systems whose partition function diverges, e.g. gravitation, lie outside the validity of the Boltzmann-Gibbs (BG) theory. Consistently, since the pioneering Bekenstein-Hawking results, physically…

Statistical Mechanics · Physics 2013-07-08 Constantino Tsallis , Leonardo J. L. Cirto

A two parameter generalization of Boltzmann-Gibbs-Shannon entropy based on natural logarithm is introduced. The generalization of the Shannon-Kinchinn axioms corresponding to the two parameter entropy is proposed and verified. We present…

Statistical Mechanics · Physics 2013-03-08 R. Chandrashekar , C. Ravikumar , J. Segar

We examine the effect of non-equilibrium processes modeled by the introduction of a generalized Boltzmann factor on the thermal and magnetic properties of an array of two-dimensional GaAs quantum dots in the presence of an external uniform…

Materials Science · Physics 2020-05-20 Jorge David Castaño-Yepes , D. A. Amor-Quiroz

A central problem in computational statistics is to convert a procedure for sampling combinatorial from an objects into a procedure for counting those objects, and vice versa. Weconsider sampling problems coming from *Gibbs distributions*,…

Probability · Mathematics 2023-08-21 David G. Harris , Vladimir Kolmogorov

We discuss the energy distribution of free-electron Fermi-gas, a problem with a textbook solution of Gaussian energy fluctuations in the limit of a large system. We find that for a small system, characterized solely by its heat capacity…

Mesoscale and Nanoscale Physics · Physics 2016-09-21 Jukka P. Pekola , Paolo Muratore-Ginanneschi , Antti Kupiainen , Yuri M. Galperin

In this study, the theoretical maximum efficiency $\eta_{max}$ and the Boltzmann-type factor giving the concentration ratio of excited-to-ground state pigment-molecules for photosynthetic systems under irradiation with arbitrary photon flux…

Statistical Mechanics · Physics 2025-12-17 Tetsuo Yabuki

We develop a method using a coarse graining of the energy fluctuations of an equilibrium quantum system which produces simple parameterizations for the behaviour of the system. As an application, we use these methods to gain more…

Statistical Mechanics · Physics 2007-05-23 Jani Lukkarinen

We develop new modified cosmological scenarios by applying the first law of thermodynamics at the Universe horizon, utilizing a new entropic functional that generalizes the standard Boltzmann-Gibbs-Shannon entropy. In particular, starting…

General Relativity and Quantum Cosmology · Physics 2026-02-24 G. G. Luciano , E. N. Saridakis

We introduce a general, variational scheme applied to Kohn-Sham density functional theory that allows for partitioning of the ground-state density matrix into distinct spectral domains, each of which spanned by an independent diagonal…

Plasma Physics · Physics 2023-08-29 Babak Sadigh , Daniel Aberg , John Pask

A variety of astronomical phenomena appear to not satisfy the ergodic hypothesis in the relevant stationary state, if any. As such, there is no reason for expecting the applicability of Boltzmann-Gibbs (BG) statistical mechanics. Some of…

Statistical Mechanics · Physics 2011-07-19 Constantino Tsallis , Domingo Prato , Angel R. Plastino