Related papers: Quantifying surfactant adsorption at fluid interfa…
Mass transfer of gaseous components from rising bubbles to the ambient liquid depends not only on the chemical potential difference of the transfer component but also on the interfacial free energy and composition. The latter is strongly…
We formulate theoretical modeling approaches and develop practical computational simulation methods for investigating the non-equilibrium statistical mechanics of fluid interfaces with passive and active immersed particles. Our approaches…
Emulsion Stability Simulations (ESS) of deformable droplets are used to study the influence of the time-dependent adsorption on the coalescence time of a 200-$\mu$m drop of soybean oil pressed by buoyancy against a planar water/oil…
The wetting of solid surfaces by fluids is a problem of great practical importance that has been extensively studied over the years. Most often, the experimental work has involved measurements of the contact angle made by a liquid on the…
In this work we report studies of nitrogen adsorption and desorption onto solid surfaces using computer simulations of the three dimensional Ising model, for systems with complex porous structures at the mesoscopic and microscopic levels. A…
We studied a system formed by a mixture of a thermoresponsive negatively charged graft copolymer (Alg-g-PNIPAAm) with a brush-type structure, and an oppositely charged surfactant (DTAB), in bulk and at the air-solution interface. We…
Equilibrium adsorption of disk-like particles on patterned adhesive surfaces is studied using Monte Carlo simulations. The surface is represented as a two-dimensional plane with circular adhesive domains arranged either regularly or…
The physical state of the intergalactic medium can be probed in great detail with the intervening absorption systems seen in quasar spectra. The properties of the Hydrogen absorbers depend on many cosmological parameters, such as the…
The efficiency of soft particles to stabilize emulsions is examined by measuring their desorption free energy, i.e., the mechanical work required to detach the particle from a fluid interface. Here, we consider rubber-like elastic as well…
We investigate the influence of surfactants on stabilizing the formation of interfaces in non-local anisotropic two-phase fluid at equilibrium. The analysis focuses on singularly perturbed non-local van der Waals-Cahn-Hillard-type energies,…
Surfactants can have a detrimental effect on the drag reduction in shear flow over superhydrophobic surfaces in Cassie state. While surfactant-free gas-liquid interfaces are often well approximated as shear-free, surfactants can impede the…
This project aims to study the sedimentation of a surfactant-laden drop in a liquid with particles. A 2D simulation is performed with MATLAB. The interface is captured by the front-tracking method. The local viscosity depends on the local…
Biomolecular condensates organize biochemical processes by spatially concentrating molecules while allowing for dynamic exchange with their surroundings. However, transport across their interface can be strongly attenuated, leading to…
Surfactants are critical in natural processes and engineering, but measuring their concentrations in non-equilibrium conditions and in the presence of flow is difficult. Therefore, computational methods are a key tool for improving our…
Vapor adsorption experiments are widely used to assess pore size distributions, but the large hysteresis sometimes observed between sorption and desorption isotherms remains difficult to interpret. Such hysteresis is influenced pore network…
A simple molecular thermodynamic approach is applied to the study of the adsorption of gases of chain molecules on solid surfaces. We use a model based on the Statistical Associating Fluid Theory for Variable Range (SAFT-VR) potentials [A.…
Thin liquid films are central to everyday life. They are ubiquitous in modern technology (pharmaceuticals, coatings), consumer products (foams, emulsions) and also serve vital biological functions (tear film of the eye, pulmonary…
By means of density, dielectric spectroscopy and sound velocity measurements we perform a systematic study on the polyoxyethylene $C_{12}E_{6}$ nonionic surfactant solutions as a function of temperature and concentration. Both density and…
We describe a method that uses total internal reflection at the water-air interface inside a large, transparent tank, to measure the interface's deflections. Using this configuration, we obtain an optical set-up where the liquid surface…
Galaxy formation depends critically on the physical state of gas in the circumgalactic medium (CGM) and its interface with the intergalactic medium (IGM), determined by the complex interplay between inflows from the IGM and outflows from…