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We study the electrical behavior of multiferroic BiFeO$_3$ by means of first-principles calculations. We do so by constraining a specific component of the electric displacement field along a variety of structural paths, and by monitoring…

Materials Science · Physics 2016-01-20 Massimiliano Stengel , Jorge Íñiguez

We present an approach to parameterize DFT+$U$+$V$ from hybrid-functional calculations using Wannier-function projections. The method constructs a common localized Wannier basis for both semilocal DFT and hybrid-functional calculations,…

Strongly Correlated Electrons · Physics 2026-02-25 Dmitry M. Korotin , Anna A. Anisimova , Vladimir I. Anisimov

Streamlined prediction of the electronic properties of photoactive materials warrants a Density Functional Theory (DFT) based approach that (i) yields reliable bandgaps, (ii) is free of empirically tuned parameters, and (iii) exhibits low…

Materials Science · Physics 2025-12-17 Andrew C. Burgess , Lórien MacEnulty , Ethan D'Arcy , David Gavin , David D. O'Regan

We present a DFT+U-type functional for strong correlation, derived from multiconfigurational wavefunction theory. The reference system experiences electron-electron interactions only in DFT+U-type atomic states, yielding a block-localized…

Chemical Physics · Physics 2023-07-25 Benjamin G. Janesko

The consequences of dynamical screening of Coulomb interaction among correlated electrons in realistic materials have not been widely considered before. In this letter we try to incorporate a frequency dependent Coulomb interaction into the…

Strongly Correlated Electrons · Physics 2014-12-04 Li Huang , Yilin Wang

Various methods going beyond density-functional theory (DFT), such as DFT+U, hybrid functionals, meta-GGAs, GW, and DFT-embedded dynamical mean field theory (eDMFT), have been developed to describe the electronic structure of correlated…

Strongly Correlated Electrons · Physics 2020-07-16 Subhasish Mandal , Kristjan Haule , Karin M. Rabe , David Vanderbilt

The existence of band gaps in Mott insulators such as perovskite oxides with partially filled 3d shells has been traditionally explained in terms of strong, dynamic inter-electronic repulsion codified by the on-site repulsion energy U in…

Materials Science · Physics 2019-07-24 Julien Varignon , Manuel Bibes , Alex Zunger

We give a summary of recent progress in the field of electronic structure calculations for materials with strong electronic Coulomb correlations. The discussion focuses on developments beyond the by now well established combination of…

Strongly Correlated Electrons · Physics 2014-12-30 Silke Biermann

A fully self-consistent density-functional theory (DFT) with improved functionals is used to provide a comprehensive account of structural, electronic, and optical properties of C$_{3}$N$_{4}$ polymorphs. Using our recently developed van…

By performing accurate ab-initio density functional theory calculations, we study the role of $4f$ electrons in stabilizing the magnetic-field-induced ferroelectric state of DyFeO$_{3}$. We confirm that the ferroelectric polarization is…

Materials Science · Physics 2015-05-14 Alessandro Stroppa , Martijn Marsman , Georg Kresse , Silvia Picozzi

Recent density functional theory (DFT) calculations for KFe2As2 have shown to be insufficient to satisfactorily describe angle-resolved photoemission (ARPES) measurements as well as observed de Haas van Alphen (dHvA) frequencies. In the…

Strongly Correlated Electrons · Physics 2014-08-21 Steffen Backes , Daniel Guterding , Harald O. Jeschke , Roser Valenti

Double perovskite Bi$_2$FeCrO$_6$, related with BiFeO$_3$, is very interesting because strong ferroelectricity and high magnetic Curie temperature beyond room temperature are observed in it. However, existing density-functional-theory (DFT)…

Materials Science · Physics 2014-03-18 Zhe-Wen Song , Bang-Gui Liu

We employ dynamical mean-field theory (DMFT) combined with density functional theory (DFT) and the non-equilibrium Green's function technique to investigate the steady-state transport properties of an Fe/MgO/Fe magnetic tunnel junction…

Strongly Correlated Electrons · Physics 2024-10-11 Declan Nell , Stefano Sanvito , Ivan Rungger , Andrea Droghetti

Charge self-consistent DFT+DMFT quantitatively captures dynamical electronic correlations in real materials, but its cost precludes the large-scale thermodynamic sampling required for phase boundaries and equations of state. Here, we…

Materials Science · Physics 2026-05-20 Rishi Rao , Li Zhu

The thermodynamics of the antiferromagnetic ordering transition in NiO and the photoelectron spectra in the antiferromagnetic phase are studied by the Variational Cluster Approximation. Using realistic Racah parameters to describe the…

Strongly Correlated Electrons · Physics 2015-04-01 R. Eder

We shed light on the interplay between structure and many-body effects relevant for itinerant ferromagnetism in LaAlO$_3$/SrTiO$_3$ heterostructures. The realistic correlated electronic structure is studied by means of the (spin-polarized)…

Materials Science · Physics 2014-08-27 Frank Lechermann , Lewin Boehnke , Daniel Grieger , Christoph Piefke

We study the role of electron correlations in the presumed type II Weyl semimetallic candidate $\gamma$-MoTe$_2$ by employing density functional theory (DFT) where the on-site Coulomb repulsion (Hubbard U) for the Mo 4$d$ states is included…

Strongly Correlated Electrons · Physics 2019-01-16 Niraj Aryal , Efstratios Manousakis

Rare-earth trihydrides ($R$H$_3$) exhibit intriguing coupled electronic and structural properties as a function of doping, hydrogen vacancies, and thermodynamic conditions. Theoretical studies of these materials typically rely on density…

Strongly Correlated Electrons · Physics 2024-10-07 Adam Denchfield , Hyeondeok Shin , Panchapakesan Ganesh , Russell J Hemley , Hyowon Park

A continuum approach to study magnetoelectric multiferroic $\mathrm{BiFeO}_3$ (BFO) is proposed. Our modeling effort marries the ferroelectric (FE) phase field method and micromagnetic simulations in order to describe the entire…

Materials Science · Physics 2024-03-25 John Mangeri , Davi Rodrigues , Sudipta Biswas , Monica Graf , Olle Heinonen , Jorge Íñiguez

The probability density function (PDF) and cumulative density function (CDF) of bulk BiFeO3, nanostructured BiFeO$_3$, and thick film of BiFeO$_{2.85}$ were studied in detail based on their experimental absorption data. The goal of this…

Materials Science · Physics 2025-10-21 Ramachandran Balakrishnan