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Inactive lithium (Li) formation is the immediate cause of capacity loss and catastrophic failure of Li metal batteries. However, the chemical component and the atomic level structure of inactive Li have rarely been studied due to the lack…

Lithium-sulfur (Li-S) batteries offer substantial theoretical energy density gains over Li-ion bat-teries, a crucial factor for transportation electrification. In addition, sulfur is an earth-abundant, inexpensive material obtainable from…

Materials Science · Physics 2025-01-22 Praveen Balaji T , Soumyadip Choudhury , Ernesto E. Marinero

All-solid-state batteries are currently developed at high pace and show a strong potential for market introduction within the next years. Though their performance has improved considerably over the last years, investigation of their…

Polymer electrolytes are intensely investigated for use as solid electrolytes in next generation lithium-ion and lithium-metal batteries. However, little is known about the structural and dynamical properties of polymer electrolytes close…

Soft Condensed Matter · Physics 2021-12-02 Andreas Thum , Diddo Diddens , Andreas Heuer

This work revisits the classical concept of electric energy and suggests that the common definition is likely to generate large errors when dealing with nanostructures. For instance, deriving the electrostatic energy in semiconductors using…

Classical Physics · Physics 2016-06-06 Jean-Michel Sallese

Wearable electronic devices and gadgets raise the need for flexible, thin and lightweight batteries. In this article we present for the first time, a unique, single-step method for the preparation of a membrane-electrode assembly for…

Lithium thiophosphates (LPS) with the composition (Li$_2$S)$_x$(P$_2$S$_5$)$_{1-x}$ are among the most promising prospective electrolyte materials for solid-state batteries (SSBs), owing to their superionic conductivity at room temperature…

Materials Science · Physics 2022-01-28 Haoyue Guo , Qian Wang , Alexander Urban , Nongnuch Artrith

Dendrite formation during electrodeposition while charging lithium metal batteries compromises their safety. While high shear modulus solid-ion conductors (SICs) have been prioritized to resolve pressure-driven instabilities that lead to…

The development of novel electrolytes and electrodes for supercapacitors is hindered by a gap of several orders of magnitude between experimentally measured and theoretically predicted charging timescales. Here, we propose an electrode…

Chemical Physics · Physics 2020-02-26 Cheng Lian , Mathijs Janssen , Honglai Liu , René van Roij

Solid-state electrolytes (SSE) with high ion conductivity are pivotal for the development and large-scale adoption of green-energy conversion and storage technologies such as fuel cells, electrocatalysts and solid-state batteries. Yet, SSE…

Materials Science · Physics 2022-11-30 Cibrán López , Agustí Emperador , Edgardo Saucedo , Riccardo Rurali , Claudio Cazorla

Supercapacitors or ultracapacitors are promising for efficient energy storage applications, owing to their high power density, high charge-discharge rates, and long cycle life performance. To achieve this goal, a large specific surface…

Materials Science · Physics 2019-10-10 Qingqing Ke , Cao Guan , Xiao Zhang , Minrui Zheng , Yong-Wei Zhang , Yongqing Cai , Hua Zhang , John Wang

Engineered nanoparticles made from noble metals, rare-earth oxides or semiconductors are emerging as the central constituents of future nanotech developments. In this review, a survey of the complexing strategies between nanoparticles and…

Materials Science · Physics 2011-08-25 J. -P. Chapel , J. -F. Berret

Non-destructive characterization of lithium-ion batteries provides critical insights for optimizing performance and lifespan while preserving structural integrity. Optimizing electrolyte design in commercial LIBs requires consideration of…

Energy efficient, safe and reliable Li-ion batteries (LIBs) are required for a wide range of applications. Charging capabilities of thick electrodes still holding their stored high-energy is a most desirable characteristic in future…

At photoelectrosynthetic interfaces, an electrochemical reaction is driven by excited charge-carriers from a semiconducting photoabsorber. Structure and composition of this interface determine both the electronic and electrochemical…

Chemical Physics · Physics 2022-05-30 Matthias M. May , Wolfram Jaegermann

Electrolyte is a very important part of rechargeable batteries such as lithium batteries. However, the electrolyte innovation is facing grand challenges due to the complicated solution chemistry and infinite molecular space (>1060 for small…

Materials Science · Physics 2024-12-03 Xiang Chen , Mingkang Liu , Shiqiu Yin , Yu-Chen Gao , Nan Yao , Qiang Zhang

The control of the dielectric and conductive properties of device-level systems is important for increasing the efficiency of energy- and information-related technologies. In some cases, such as neuromorphic computing, it is desirable to…

Mesoscale and Nanoscale Physics · Physics 2020-07-28 Dimitrios Fraggedakis , Mohammad Mirzadeh , Tingtao Zhou , Martin Z. Bazant

Solid-state electrolytes, by enabling lithium metal anodes, may significantly increase the energy density of current lithium-ion batteries. However, similar to their liquid counterparts, these hard and stiff electrolytes can still be…

Chemical Physics · Physics 2024-10-04 Rajeev Gopal , Longan Wu , Youngju Lee , Jinzhao Guo , Peng Bai

The renewable energy sector critically needs low-cost and environmentally neutral energy storage solutions throughout the entire device life cycle. However, the limited performance of standard water-based electrochemical systems prevents…

Supercapacitors are promising electrochemical energy storage devices due to their prominent performance in rapid charging/discharging rates, long cycle life, stability, etc. Experimental measurement and theoretical prediction on charging…

Numerical Analysis · Mathematics 2023-05-31 Lijie Ji , Zhenli Xu , Shenggao Zhou