Related papers: Thermodynamic response functions in a cell fluid m…
Thermodynamic response functions, namely the isothermal compressibility, the thermal pressure coefficient, and the thermal expansion coefficient, are calculated for a many-particle system interacting through a modified Morse potential.…
The object of this study is a cell model with Curie-Weiss interaction potential. We have already proved the possibility of a mathematically rigorous transition from a continuous system of interacting particles to such a model and made an…
The analytic method for deriving the equation of state of a cell fluid model in the region above the critical temperature ($T \geqslant T_\text{c}$) is elaborated using the renormalization group transformation in the collective variables…
A microscopic description is given for the behavior of the fluid system in an immediate vicinity of its critical point, where theoretical and experimental researches are difficult to carry out. For the temperatures $T<T_c$, the regions of…
Entropy of the cell fluid model with Curie-Weiss interaction is obtained in analytical form as a function of temperature and chemical potential. A parametric equation is derived representing the entropy as a function of density. Features of…
The previously proposed approach for the microscopic description of the critical behavior of Morse liquids based on the cell fluid model is applied to the case where the parameters of the Morse interaction potential correspond to alkali…
In this paper, we study the thermodynamics of short-range central potentials, namely, the Lee-Wick potential, and the Plasma potential. In the first part of the paper we obtain the numerical solution for the orbits equation for these…
In this paper we present results for the pair distribution function for the cell fluid model with Curie-Weiss interaction. As a supplementary result, one- and two-particle densities are calculated.
We study a cell fluid model of a many-particle system with Curie-Weiss-type interaction potential. It is considered as an open system in a fixed volume partitioned into a large number of congruent cubic cells. The interaction potential…
We solve the Schr\"odinger wave equation for the generalized Morse and Cusp molecular potential models. In the limit of high temperature, at first, we need to calculate the canonical partition function which is basically used to study the…
We propose a method of describing a phase transition in a cell fluid model with pair interaction potential that includes repulsive and attractive parts. An exact representation of the grand partition function of this model is obtained in…
We study the partition function and free energy of the Curie-Weiss model with complex temperature, and partially describe its phase transitions. As a consequence, we obtain information on the locations of zeros of the partition function.
A single-sort continuum Curie-Weiss system of interacting particles is studied. The particles are placed in the space $\mathbb{R}^d$ divided into congruent cubic cells. For a region $V\subset \mathbb{R}^d$ consisting of $N\in \mathbb{N}$…
We study autocorrelation functions of energy, heat and entropy densities obtained by molecular dynamics simulations of supercritical Ar and compare them with the predictions of the hydrodynamic theory. It is shown that the predicted by the…
We show that for any liquid or solid with strong correlation between its $NVT$ virial and potential-energy equilibrium fluctuations, the temperature is a product of a function of excess entropy per particle and a function of density,…
The present manuscript gives a theoretical description of the first-order phase transition in a cell fluid model with a modified Morse potential and additional repulsive interaction. In the framework of the grand canonical ensemble, the…
The structural and thermodynamic properties of fluids whose molecules interact via potentials with a hard-core plus a square well, a square shoulder, and a second square well, are considered. Those properties are derived by using a…
We demonstrate that the mechanically-defined "isothermal" compressibility behaves as a thermodynamic-like response function for suspensions of active Brownian particles. The compressibility computed from the active pressure - a combination…
The properties of one-dimensional liquids are studied for several interaction potentials for which, under certain assumptions, the properties of the system admit an analytical solution. The studied potentials are the triangle-well and the…
With the use of thermodynamics and general equilibrium conditions only, we study the entropy of a fluid in the vicinity of the critical point of the liquid-vapor phase transition. By assuming a general form for the coexistence curve in the…