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We study a partially ionized hydrogen plasma by means of quantum molecular dynamics, which is based on wave packets. We introduce a new model which distinguishes between free and bound electrons. The free electrons are modelled as Gaussian…

Plasma Physics · Physics 2009-10-30 W. Ebeling , B. Militzer

We propose a novel method to describe realistically ionization processes with absorbing boundary conditions in basis expansion within the formalism of the so-called Non-Adiabatic Quantum Molecular Dynamics. This theory couples…

Quantum Physics · Physics 2015-06-26 Mathias Uhlmann , Thomas Kunert , Ruediger Schmidt

By performing an ensemble of molecular dynamics simulations, the model-dependent ionisation state is computed for strongly interacting systems self-consistently. This is accomplished through a free energy minimisation framework based on the…

Quantum gases of atoms and molecules in optical cavities offer a formidable laboratory for studying the out-of-equilibrium dynamics of open quantum systems with long-range interactions. Long-range interactions are here mediated by multiple…

Quantum Physics · Physics 2026-03-19 Tom Schmit , Catalin-Mihai Halati , Tobias Donner , Giovanna Morigi , Simon B. Jäger

The quantum dynamics of electron-nuclear systems is analyzed from the perspective of the exact factorization of the wavefunction, with the aim of defining gauge invariant equations of motion for both the nuclei and the electrons. For pure…

Chemical Physics · Physics 2023-10-16 Rocco Martinazzo , Irene Burghardt

A comprehensive comparison of quantum evolution between the quantum and classical mechanically motion of nuclei in a finite-dimensional quantum chemistry model is presented. A modified version of Tavis-Cummings-Hubbard model with two…

Quantum Physics · Physics 2024-06-10 Hui-hui Miao

This paper presents the inversion symmetry breaking observed in ion-pair formation from molecular hydrogen on electron impact. We explain these observations using quantum interference of two dissociation paths coherently accessed by…

Chemical Physics · Physics 2024-04-17 Akshay Kumar , Suvasis Swain , Vaibhav S. Prabhudesai

An approach to correlated dynamics of quantum nuclei and electrons both in dynamical interaction with external environments is presented. This stochastic quantum molecular dynamics rests on a theorem that establishes a one-to-one…

Materials Science · Physics 2012-12-27 Heiko Appel , Massimiliano Di Ventra

In this paper we apply quantum hydrodynamics (QHD) to study the quantum evolution of a system of spinning particles and particles that have the electric dipole moments EDM in the rotating reference frame. The method presented is based on…

Plasma Physics · Physics 2016-12-21 Mariya Iv. Trukhanova

The thermodynamics of quantum systems driven out of equilibrium has attracted increasing attention in last the decade, in connection with quantum information and statistical physics, and with a focus on non-classical signatures. While a…

Quantum Physics · Physics 2022-06-01 Gonzalo Manzano , Roberta Zambrini

The coupled quantum dynamics of electrons and protons is ubiquitous in many dynamical processes involving light-matter interaction, such as solar energy conversion in chemical systems and photosynthesis. A first-principles description of…

Chemical Physics · Physics 2023-11-07 Jianhang Xu , Ruiyi Zhou , Tao E. Li , Volker Blum , Sharon Hammes-Schiffer , Yosuke Kanai

The dynamics of a typical open quantum system, namely a quantum Brownian particle in a harmonic potential, is studied focussing on its non-Markovian regime. Both an analytic approach and a stochastic wave function approach are used to…

Quantum Physics · Physics 2009-11-10 S. Maniscalco , J. Piilo , F. Intravaia , F. Petruccione , A. Messina

The theoretical description of materials' properties driven out of equilibrium has important consequences in various fields such as semiconductor spintronics, nonlinear optics, continuous and discrete quantum information science and…

Materials Science · Physics 2025-09-18 Jacopo Simoni , Gabriele Riva , Yuan Ping

An $\mathit{ab\ initio}$ theory is devised for the quantum dynamics of molecules undergoing (multiple) ionization in ultrafast and intense light. Specifically, the intertwined problem of photoionization, radiative, and electronic…

Chemical Physics · Physics 2018-12-12 Christian Buth

We introduce a simple model for electromagnetically induced transparency in which all fields are treated quantum mechanically. We study a system of three separated atoms at fixed positions in a one-dimensional multimode optical cavity. The…

Quantum Physics · Physics 2018-05-09 Thomas Purdy , Martin Ligare

Quantum nuclear dynamics with wavepacket time-evolution is classically intractable and viewed as a promising avenue for quantum information processing. Here, we use an IonQ 11-qubit trapped-ion quantum computer, Harmony, to study the…

Quantum Physics · Physics 2024-12-05 Anurag Dwivedi , A. J. Rasmusson , Philip Richerme , Srinivasan S. Iyengar

We study quantum electrodynamics (QED) in the light-front dynamical form by using null-plane causal perturbation theory. We establish the equivalence with instant dynamics for the scattering processes, whose normalization allows to…

High Energy Physics - Theory · Physics 2022-08-17 O. A. Acevedo , B. M. Pimentel

By means of quantum mechanics and quantum electrodynamics applied to coupled harmonic Drude oscillators, we study the interaction between two neutral atoms or molecules subject to a uniform static electric field. Our focus is to understand…

Chemical Physics · Physics 2022-03-16 Mohammad Reza Karimpour , Dmitry V. Fedorov , Alexandre Tkatchenko

We investigate the effects of dissipation on the quantum dynamics of many-body systems at quantum transitions, especially considering those of the first order. This issue is studied within the paradigmatic one-dimensional quantum Ising…

Statistical Mechanics · Physics 2020-12-08 Giovanni Di Meglio , Davide Rossini , Ettore Vicari

We investigate how short and long electron trajectory contributions to high harmonic emission and their interferences give access to intra-molecular dynamics. In the case of unaligned molecules, we show experimental evidences that the long…

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