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Dynamic nuclear polarization (DNP) is an NMR hyperpolarization technique that mediates polarization transfer from highly polarized unpaired electrons to NMR-active nuclei via microwave (mw) irradiation. The ability to generate arbitrarily…

Dynamic nuclear polarization (DNP) is used in nuclear magnetic resonance (NMR) to transfer polarization from electron spins to nuclear spins. The resulting nuclear polarization enhancement can, in theory, be two or three orders of magnitude…

Quantum Physics · Physics 2015-10-14 Sarah Sheldon , David G. Cory

Dynamic nuclear polarization (DNP) enhances the intensity of NMR signals by transferring polarization from electron spins to nuclei via microwave irradiation. Pulsed DNP methods offer more control on the spin dynamics than conventional…

Chemical Physics · Physics 2026-01-07 Lorenzo Niccoli , Gian-Marco Camenisch , Matías Chávez , Matthias Ernst

In pulsed dynamic nuclear polarization (DNP), enhancement of the polarization of bulk nuclei requires the repeated application of a microwave pulse sequence. So far, analysis of a one-time transfer of electron spin polarization to a…

Chemical Physics · Physics 2025-07-24 Shebha Anandhi Jegadeesan , Yujie Zhao , Graham M. Smith , Ilya Kuprov , Guinevere Mathies

Dynamic nuclear polarisation (DNP) refers to a class of techniques used to increase the signal in nuclear magnetic resonance measurements by transferring spin polarisation from ensembles of highly polarised electrons to target nuclear…

Quantum Physics · Physics 2020-12-24 L. T. Hall , D. A. Broadway , A. Stacey , D. A. Simpson , J-P. Tetienne , L. C. L. Hollenberg

Dynamical nuclear polarisation (DNP) is an important technique that uses polarisation transfer from electron to nuclear spins to achieve nuclear hyperpolarisation. As the electron spin of the nitrogen vacancy (NV) centres in diamond can be…

Polarization transfers are crucial building blocks in magnetic resonance experiments, i.e., they can be used to polarize insensitive nuclei and correlate nuclear spins in multidimensional NMR spectroscopy. The polarization can be…

Chemical Physics · Physics 2022-08-24 Zhenfeng Pang , Sheetal Jain , Chen Yang , Xueqian Kong , Kong Ooi Tan

Nuclear spin hyperpolarization techniques, such as dynamic nuclear polarization (DNP) and parahydrogen-induced polarization (PHIP), have revolutionized nuclear magnetic resonance and magnetic resonance imaging. In these methods, a readily…

Dynamic Nuclear Polarization (DNP) has revolutionized the field of solid-state NMR spectroscopy by significantly enhancing the sensitivity of nuclear magnetic resonance experiments. Conventionally, cross effect DNP relies on biradicals to…

Chemical Physics · Physics 2023-09-28 Amaria Javed , Asif Equbal

Many applications of magnetic resonance are limited by rapid loss of spin coherence caused by large transverse relaxation rates. In nuclear magnetic resonance (NMR) of large proteins, increased relaxation losses lead to poor sensitivity of…

Quantum Physics · Physics 2007-05-23 N. Khaneja , J. S. Li , C. Kehlet , B. Luy , S. J. Glaser

Dynamic nuclear polarization (DNP) is a promising strategy for generating a significantly increased non-thermal spin polarization in nuclear magnetic resonance (NMR) applications thereby circumventing the need for strong magnetic fields.…

Quantum Physics · Physics 2015-07-15 Alexander Karabanov , Daniel Wisniewski , Igor Lesanovsky , Walter Köckenberger

Pulsed Dynamic Nuclear Polarization (DNP) is currently receiving substantial interest as a means to enhance the sensitivity of nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) by orders of magnitude. It has also…

We present constrained random walk (cRW) and figure of merit (FOM) based non-linear optimization procedures for systematic design and fundamental understanding of magnetic resonance experiments dressing bilinear and linear effective…

Dynamic nuclear polarization transfers spin polarization from electrons to nuclei. We have achieved this by a new method, simultaneously exciting transitions of electronic and nuclear spins. The efficiency of this technique improves with…

Quantum Physics · Physics 2008-09-11 G. W. Morley , K. Porfyrakis , A. Ardavan , J. van Tol

Dynamic Nuclear Polarization (DNP) presently stands as the preferred strategy to enhance the sensitivity of nuclear magnetic resonance measurements, but its application relies on the use of high-frequency microwave to manipulate electron…

Mesoscale and Nanoscale Physics · Physics 2022-02-02 Carlos A. Meriles , Pablo R. Zangara

It is demonstrated that the time evolution of the electron-nuclear polarization transfer process during pulsed dynamic nuclear polarization (DNP) can be reversed on a microsecond timescale, leading to the observation of DNP echoes. The DNP…

Chemical Physics · Physics 2024-06-28 Nino Wili , Anders B. Nielsen , José P. Carvalho , Niels Chr. Nielsen

Dynamic nuclear polarization (DNP) of molecules in a solution at room temperature has potential to revolutionize nuclear magnetic resonance spectroscopy and imaging. The prevalent methods for achieving DNP in solutions are typically most…

Chemical Physics · Physics 2016-03-02 Qiong Chen , Ilai Schwarz , Fedor Jelezko , Alex Retzker , Martin B Plenio

Dynamic nuclear polarization (DNP) has revolutionized the field of NMR spectroscopy, expanding its reach and capabilities to investigate diverse materials, biomolecules, and complex dynamic processes. Bringing high-efficiency DNP to the…

Mesoscale and Nanoscale Physics · Physics 2024-02-27 Sahand Tabatabaei , Pritam Priyadarsi , Namanish Singh , Pardis Sahafi , Daniel Tay , Andrew Jordan , Raffi Budakian

A sensitivity increase of two orders of magnitude in proton (1H) and carbon (13C) spins via dynamic nuclear polarization (DNP) has been accomplished recently using a compact benchtop DNP polarizer operating at 1 T and 77 K. However the DNP…

The non-reciprocal and dynamic nature of polarization mode dispersion (PMD) in optical fibers can be a problem for accurate time and frequency transfer. Here a simple, passive solution is put forward that is based on transmitting optical…

Optics · Physics 2022-04-13 Thomas Fordell
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