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Circular Dichroism (CD) spectroscopy has evolved from a purely solution based method towards a powerful tool in the analysis of chiral thin films. Although a straightforward technique, the genuine CD signal is often accompanied by artifacts…

Electronic charge transfer at the atomic scale can reveal fundamental information about chemical bonding, but is far more challenging to directly image than the atomic structure. The charge density is dominated by the atomic nuclei, with…

Materials Science · Physics 2025-05-01 Christoph Hofer , Jacob Madsen , Toma Susi , Timothy J. Pennycook

Manipulating the orbital occupation of valence electrons via epitaxial strain in an effort to induce new functional properties requires considerations of how changes in the local bonding environment affect the band structure at the Fermi…

We investigate the retrieval of spatially resolved atomic displacements via the phases of the direct(real)-space image reconstructed from the strained crystal's coherent x-ray diffraction pattern. We demonstrate that limiting the spatial…

Materials Science · Physics 2014-07-16 A. A. Minkevich , M. Köhl , S. Escoubas , O. Thomas , T. Baumbach

We report experimental measurements of the dynamical polarizability of dysprosium, at a wavelength of 532 nm. We measure all three components (scalar, vector, tensor) of the anisotropic polarizability for the ground and the excited…

In quantum mechanics, each conserved quantity (e.g., energy, position, linear momentum and angular momentum) is associated with a Hermitian operator. Its expected value can then be determined by performing a measurement on the wavefunction.…

Modern X-ray spectroscopy has proven itself as a robust tool for probing the electronic structure of atoms in complex environments. Despite working on energy scales that are much larger than those corresponding to nuclear motions, taking…

Chemical Physics · Physics 2017-06-28 Sven Karsten , Sergey I. Bokarev , Saadullah G. Aziz , Sergei D. Ivanov , Oliver Kühn

We have performed x-ray linear and circular magnetic dichroism experiments at the Mn L2,3-edge of the La0.7Sr0.3MnO3 ultra thin films. Our measurements show that the antiferromagnetic (AF) insulating phase is stabilized by the interfacial…

Strongly Correlated Electrons · Physics 2009-07-29 C. Aruta , G. Ghiringhelli , V. Bisogni , L. Braicovich , N. B. Brookes , A. Tebano , G. Balestrino

Understanding the ramifications of reduced crystalline symmetry on magnetic behavior is a critical step in improving our understanding of nanoscale and interfacial magnetism. However, investigations of such effects are often controversial…

Trapping of single ultracold atoms is an important tool for applications ranging from quantum computation and communication to sensing. However, most experimental setups, while very precise and versatile, can only be operated in specialized…

Single strontium atoms held in optical tweezers have so far only been imaged using the broad $^{1\hspace{-0.3ex}}S_0$-$^{1\hspace{-0.3ex}}P_1$ transition. For Yb, use of the narrow (183 kHz-wide)…

Atomic Physics · Physics 2022-06-28 Alexander Urech , Ivo H. A. Knottnerus , Robert J. C. Spreeuw , Florian Schreck

Strong enhancement of molecular circular dichroism has the potential to enable efficient asymmetric photolysis, a method of chiral separation that has conventionally been impeded by insufficient yield and low enantiomeric excess. Here, we…

We study the origin of dichroic effects in elastic scattering of high energy electrons by hydrogen atoms in the presence of a two-color bicircular laser field of commensurate frequencies, in the domain of moderate intensities below 10…

Atomic Physics · Physics 2023-09-27 Gabriela Buica

We realize a scanning probe microscope using single trapped $^{87}$Rb atoms to measure optical fields with subwavelength spatial resolution. Our microscope operates by detecting fluorescence from a single atom driven by near-resonant light…

Atomic Physics · Physics 2022-03-02 Emma Deist , Justin A. Gerber , Yue-Hui Lu , Johannes Zeiher , Dan M. Stamper-Kurn

The propagation of high-energy electrons in crystals is in general a complicated multiple scattering problem. However, along high-symmetry zone axes the problem can be mapped to the time evolution of a two-dimensional (2D) molecular system.…

Materials Science · Physics 2012-12-07 Robert Hovden , Huolin L. Xin , David A. Muller

We report the implementation of energy dispersive X-ray spectroscopy for layered semiconductors in the form of atomically thin transition metal dichalcogenides. The technique is based on a scanning electron microscope equipped with a…

Mesoscale and Nanoscale Physics · Physics 2022-11-17 Anna Rupp , Jonas Göser , Zhijie Li , Philipp Altpeter , Ismail Bilgin , Alexander Högele

Electron ptychography provides highly sensitive, dose efficient phase images which can be corrected for aberrations after the data has been acquired. This is crucial when very precise quantification is required, such as with sensitivity to…

Materials Science · Physics 2023-07-27 Christoph Hofer , Timothy J. Pennycook

Digital images from crystals, as projected from the third spatial dimension and recorded in atomic resolution with any kind of real-world microscope, feature necessarily broken symmetries of the translation-periodicity-restricted Euclidean…

Materials Science · Physics 2025-11-25 Tyler Bortel , Peter Moeck

The use of differential phase contrast (DPC) in scanning transmission electron microscopy (STEM) has shown much promise for directly investigating the functional properties of a material system, leveraging the natural coupling between the…

Materials Science · Physics 2025-12-04 Rafael V. Ferreira , Sebastian Calderon V. , Paulo J. Ferreira

Doping impurity atoms is a strategy commonly used to tune the functionality of materials including catalysts, semiconductors, and quantum emitters. The location of dopants and their interaction with surrounding atoms could significantly…