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The photogalvanic effect is the generation of a second-order direct current by illumination of a non-centrosymmetric material. In this work, we develop a first-principles real-time density matrix (FPDMD) formalism enabling the calculations…

The bulk photovoltaic effect (BPVE) -- generation of electric currents by light in noncentrosymmetric materials in the absence of electric fields and gradients -- has been intensively investigated in the end of the last century. The…

Mesoscale and Nanoscale Physics · Physics 2019-11-28 Boris Sturman

In photonics, twisted bi-layer systems have demonstrated unprecedented control over light-matter interactions, primarily through the modulation of photonic band structures and the formation of Moir\'e patterns. Meanwhile, magnetic photonic…

Optics · Physics 2025-10-10 You-Ming Liu , Shi-Kai Lin , Pei-Shi Li , Yi-Ran Hao , Biao Yang

A bulk material without inversion symmetry can generate a direct current under illumination. This interface-free current generation mechanism, referred to as the bulk photovoltaic effect (BPVE), does not rely on $p$-$n$ junctions. Here, we…

Materials Science · Physics 2023-05-01 Zhuang Qian , Jian Zhou , Hua Wang , Shi Liu

In a system of two-dimensional electrons, a combination of broken symmetry, interactions, and nontrivial topology can conspire to give rise to a nonlinear transport regime, where electric current density scales as the square of electric…

Second order optical nonlinear processes involve the coherent mixing of two electromagnetic waves to generate a new optical frequency, which plays a central role in a variety of applications, such as ultrafast laser systems, rectifiers,…

Mesoscale and Nanoscale Physics · Physics 2015-06-03 Sanfeng Wu , Li Mao , Aaron M. Jones , Wang Yao , Chuanwei Zhang , Xiaodong Xu

The interplay between crystal symmetry and its optical responses is at the heart of tremendous recent advances in light-matter interactions and applications. Nonlinear optical processes that produce electric currents, for example bulk…

Materials Science · Physics 2021-10-27 Yongliang Shi , Jian Zhou

Bulk photovoltaic effect, which arises from crystal symmetry-driven charge carrier separation, is an intriguing physical phenomenon that has attracted extensive interest in photovoltaic application due to its junction-free photovoltaic and…

Materials Science · Physics 2023-08-22 Xiaojuan Chen , Kang Xu , Tingxiao Qin , Yubin Wang , Yuzhong Chen , Haiyun Liu , Qihua Xiong

We elucidate light-induced orbital and spin current through nonlinear response theory, which generalizes the well-known bulk photovoltaic effect in centrosymmetric broken materials from charge to the spin and orbital degrees of freedom. We…

Materials Science · Physics 2021-08-30 Xingchi Mu , Jian Zhou

Moir\'e materials represent strongly interacting electron systems bridging topological and correlated physics. Despite significant advances, decoding wavefunction properties underlying the quantum geometry remains challenging. Here, we…

Solid systems with strong correlations and interactions under light illumination have the potential for exhibiting interesting bulk photovoltaic behavior in the non-perturbative regime, which has remained largely unexplored in the past…

Strongly Correlated Electrons · Physics 2022-04-06 Sangeeta Rajpurohit , C. Das Pemmaraju , Tadashi Ogitsu , Liang Z Tan

Shift current and ballistic current have been proposed to explain the bulk photovoltaic effect (BPVE), and there have been experiments designed to separate the two mechanisms. These experiments are based on the assumption that under…

Materials Science · Physics 2023-05-24 Zhenbang Dai , Andrew M. Rappe

Two-dimensional (2D) hexagonal materials have been intensively explored for multiple optoelectronic applications such as spin current generation, all-optical valleytronics, and topological electronics. In the realm of strong-field and…

Materials Science · Physics 2025-09-09 Anna Galler , Ofer Neufeld

Two-dimensional multi-layer materials with an induced moir\'e pattern, either due to strain or relative twist between layers, provide a versatile platform for exploring strongly correlated and topological electronic phenomena. While these…

Strongly Correlated Electrons · Physics 2025-05-27 Mohammed M. Al Ezzi , Albert Zhu , Daniel Bennett , Daniel T. Larson , Efthimios Kaxiras

In future solar cell technologies, the thermodynamic Shockley-Queisser limit for solar-to-current conversion in traditional p-n junctions could potentially be overcome with a bulk photovoltaic effect by creating an inversion broken symmetry…

The bulk photovoltaic effect (BPVE) refers to the direct current generation in a noncentrosymmetric material under illumination and can be applied to solar energy technology. BPVE includes injection and shift currents, led by the change of…

Mesoscale and Nanoscale Physics · Physics 2025-11-04 Bo-Xin Lin , Hsiu-Chuan Hsu

We report on the observation of terahertz radiation induced edge photogalvanic currents in graphene, which are nonlinear in intensity. The increase of the radiation intensities up to MW/cm$^2$ results in a complex nonlinear intensity…

Mesoscale and Nanoscale Physics · Physics 2021-10-13 S. Candussio , L. E. Golub , S. Bernreuter , T. Jötten , T. Rockinger , K. Watanabe , T. Taniguchi , J. Eroms , D. Weiss , S. D. Ganichev

The shift current photovoltaic effect is conventionally understood as the real-space displacement of a wave packet induced by photoexcitation. However, this interpretation becomes insufficient in flat-band systems, where quasiparticles are…

Materials Science · Physics 2025-02-25 Zhuocheng Lu , Zhihao Gong , Jingshan Qi , Hua Wang , Kai Chang

Transverse thermophotovoltaics has been conceptually proposed as a paradigm distinct from conventional junction-based photovoltaics, but has so far lacked a theoretical foundation. In this Letter, we establish a microscopic formalism of…

Mesoscale and Nanoscale Physics · Physics 2026-05-28 Dingwei He , Gaomin Tang

Nonlinear couplings between photons and electrons in new materials give rise to a wealth of interesting nonlinear phenomena. This includes frequency mixing, optical rectification or nonlinear current generation, which are of particular…