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We consider the adsorption kinetics of a regular block-copolymer of total length $N$ and block size $M$ at a selective liquid-liquid interface in the limit of strong localization. We propose a simple analytic theory based on scaling…

Soft Condensed Matter · Physics 2007-05-23 Andrea Corsi , Andrey Milchev , Vakhtang G. Rostiashvili , Thomas A. Vilgis

The structure of polymer coils near interfaces between coexisting phases of symmetrical polymer mixtures (AB) is discussed, as well as the structure of symmetric diblock copolymers of the same chain length N adsorbed at the interface. The…

Soft Condensed Matter · Physics 2015-06-25 K. Binder , M. Mueller , F. Schmid , A. Werner

An infinite hierarchy of layering transitions exists for model polymers in solution under poor solvent or low temperatures and near an attractive surface. A flat histogram stochastic growth algorithm known as FlatPERM has been used on a…

Statistical Mechanics · Physics 2009-11-10 J. Krawczyk , A. L. Owczarek , T. Prellberg , A. Rechnitzer

Using fluorescence microscopy we study the adsorption of single latex microparticles at a water/water interface between demixing aqueous solutions of polymers, generally known as a water-in-water emulsion. Similar microparticles at the…

Soft Condensed Matter · Physics 2018-05-23 Louis Keal , Carlos E. Colosqui , Hans Tromp , Cecile Monteux

Pore-network modeling is a widely used predictive tool for pore-scale studies in various applications that deal with multiphase flow in porous media. Despite recent improvements to enable pore-network modeling on simplified pore geometry…

Computational Physics · Physics 2020-04-06 Amir H. Kohanpur , Albert J. Valocchi

In this paper we present simulations of a surface-adsorbed polymer subject to an elongation force. The polymer is modelled by a self-avoiding walk on a regular lattice. It is confined to a half-space by an adsorbing surface with attractions…

Statistical Mechanics · Physics 2007-05-23 J. Krawczyk , T. Prellberg , A. Rechnitzer , A. L. Owczarek

Coagulation-flocculation, the physicochemical process widely used for purification a wastewater, is affected both by chemical details of involved polymers and by the statistics of their conformations on a large scale. The latter aspect is…

Soft Condensed Matter · Physics 2024-07-23 V. Blavatska , Ja. Ilnytskyi , E. Lähderanta

We investigated theoretically water evaporation from concentrated supramolecular mixtures, such as solutions of polymers or amphiphilic molecules, using numerical resolutions of a one dimensional model based on mass transport equations.…

Soft Condensed Matter · Physics 2017-10-25 Jean-Baptiste Salmon , Frédéric Doumenc , Béatrice Guerrier

Conformations of partially or fully adsorbed semiflexible polymer chains are studied varying both contour length $L$, chain stiffness, $\kappa$, and the strength of the adsorption potential over a wide range. Molecular Dynamics simulations…

Soft Condensed Matter · Physics 2019-10-02 Andrey Milchev , Kurt Binder

The adsorption of a single polymer to a flat surface in shear is investigated using Brownian hydrodynamics simulations and scaling arguments. Competing effects are disentangled: in the absence of hydrodynamic interactions, shear drag…

Soft Condensed Matter · Physics 2015-05-20 Andreas Serr , Christian Sendner , Florian Mueller , Thomas R. Einert , Roland R. Netz

We study analytically and by means of an off-lattice bead-spring dynamic Monte Carlo simulation model the adsorption kinetics of a single macromolecule on a structureless flat substrate in the regime of strong physisorption. The underlying…

Soft Condensed Matter · Physics 2008-06-27 S. Bhattacharya , A. Milchev , V. G. Rostiashvili , A. Y. Grosberg , T. A. Vilgis

We investigate the conformational properties of a multi-branched polymer structure with a dendrimer-like topology, known as a snowflake polymer. This polymer is characterized by two parameters: $f_s$, which represents the functionality of…

Soft Condensed Matter · Physics 2023-06-26 Khristine Haydukivska , Viktoria Blavatska , Jaroslaw Paturej

Sampling with the Generalised Atmospheric Rosenbluth Method (GARM) is a technique for estimating the distributions of lattice polymer models that has had some success in the study of linear polymers and lattice polygons. In this paper we…

Statistical Mechanics · Physics 2024-01-23 Tom Roberts , Thomas Prellberg

We study irreversible polymer adsorption from dilute solutions theoretically. Universal features of the resultant non-equilibrium layers are predicted. Two cases are considered, distinguished by the value of the local monomer-surface…

Soft Condensed Matter · Physics 2009-11-10 Ben O'Shaughnessy , Dimitrios Vavylonis

Using Monte Carlo simulations, we investigate the self-assembly of model nanoparticles inside a matrix of model equilibrium polymers (or matrix of Wormlike micelles) as a function of the polymeric matrix density and the excluded volume…

Soft Condensed Matter · Physics 2018-04-03 Sk. Mubeena , Apratim Chatterji

Using extensive Monte Carlo simulations, we investigate the surface adsorption of self-avoiding trails on the triangular lattice with two- and three-body on-site monomer-monomer interactions. In the parameter space of two-body, three-body,…

Statistical Mechanics · Physics 2020-01-01 Nathann T. Rodrigues , Tiago J. Oliveira , Thomas Prellberg , Aleksander L. Owczarek

We report on the complexation between charged-neutral block copolymers and oppositely charged surfactants studied by small-angle neutron scattering. Two block copolymers/surfactant systems are investigated, poly(acrylic…

Soft Condensed Matter · Physics 2007-05-23 Jean-Francois Berret

Advanced chain-growth computer simulation methodologies have been employed for a systematic statistical analysis of the critical behavior of a polymer adsorbing at a substrate. We use finitesize scaling techniques to investigate the…

Soft Condensed Matter · Physics 2017-05-09 J. A. Plascak , Paulo H. L. Martins , Michael Bachmann

Star polymer is a typical nonlinear macromolecule possessing special thermodynamic behaviors for the existence of a jointing point. The thermodynamic transitions of a single star polymer are systematically studied with bond fluctuation…

Soft Condensed Matter · Physics 2015-05-27 Zilu Wang , Xuehao He

Bottle brushes are polymeric macromolecules made of a linear polymeric backbone grafted with side chains. The choice of the grafting density {\sigma}g, the length ns the grafted side chains and their chemical nature fully determines the…

Soft Condensed Matter · Physics 2019-08-09 P. Corsi , E. Roma , T. Gasperi , F. Bruni , B. Capone
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