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The excess free energy functional of classical density functional theory depends upon the type of fluid model, specifically on the choice of (pair) potential, is unknown in general, and is approximated reliably only in special cases. We…

Soft Condensed Matter · Physics 2025-03-12 Stefanie M. Kampa , Florian Sammüller , Matthias Schmidt , Robert Evans

Inspired by previous extensive numerical studies of a cell fluid model with Curie-Weiss interactions, we concentrate on some analytically tractable special cases in its description. The key ingredient of the model is a competition between…

Statistical Mechanics · Physics 2026-05-22 O. A. Dobush , M. P. Kozlovskii , I. V. Pylyuk , R. V. Romanik , M. A. Shpot

The primary goal of this paper is to characterize solutions to coupled reaction-diffusion systems. Indeed, we use operators theory to show that under suitable assumptions, then the solutions to the reaction-diffusion equations exist. As…

Analysis of PDEs · Mathematics 2007-05-23 Toka Diagana

The strongly attractive Fermi gas in the BCS-BEC crossover is efficiently described in terms of coupled fermions and fermion pairs, or molecules. We compute the spectral functions of both fermions and pairs in the normal state near the…

Quantum Gases · Physics 2024-03-01 Tilman Enss

We investigate how varying two microscopic parameters - cell volume and the ratio between repulsion and attraction intensities - affect the phase behavior of a cell model with a Curie-Weiss-type interaction. The analysis is based on an…

Statistical Mechanics · Physics 2025-05-30 O. A. Dobush , M. P. Kozlovskii , I. V. Pylyuk , Yu. O. Plevachuk

We present a new method for studying equilibrium properties of interacting fluids in an arbitrary external field. The fluid is composed of monodisperse spherical particles with hard-core repulsion and additional interactions of arbitrary…

Soft Condensed Matter · Physics 2021-03-09 Benaoumeur Bakhti , Gerhard Müller

A new one-dimensional fluid model for ions in weakly-ionized plasma is proposed. The model differs from the existing ones in two aspects. First, a more accurate approximation of the collision terms in the fluid equations is suggested. For…

Plasma Physics · Physics 2017-04-20 I. L. Semenov

We introduce and test via molecular simulation a simple model for predicting the manner in which interparticle interactions and thermodynamic conditions impact the single-particle free-volume distributions of equilibrium fluids. The model…

Soft Condensed Matter · Physics 2007-05-23 William P. Krekelberg , Venkat Ganesan , Thomas M. Truskett

Liquid-state theory, computer simulation, and numerical optimization are used to investigate the extent to which positional correlations of a hard-sphere fluid--as characterized by the radial distribution function and the two-particle…

Soft Condensed Matter · Physics 2016-03-23 Ryan B. Jadrich , Beth A. Lindquist , Jonathan A. Bollinger , Thomas M. Truskett

We extract a pair correlation function (PCF) from probability distributions of the spin-overlap parameter q. The distributions come from Monte Carlo simulations. A measure, w, of the thermal fluctuations of magnetic patterns follows from…

Disordered Systems and Neural Networks · Physics 2012-10-11 J. F. Fernández , J. J. Alonso

A new approach to thermodynamics of simple fluids is presented. The partition function is first expressed in the reciprocal space, it is argued that the links (p,q) between 2 molecules can reasonably in the thermodynamical limit be…

General Physics · Physics 2020-03-03 Richard Bonneville

The exact interaction energy of a many-electron system is determined by the electron pair density, which is not well-approximated in standard Kohn-Sham density functional models. Here we study the (complicated but well-defined) exact…

Chemical Physics · Physics 2015-08-07 Huajie Chen , Gero Friesecke

We use a mapping of the quasi-2D electron liquid to a classical fluid and use the hypernetted-chain equation inclusive of bridge corrections, i.e., CHNC, to calculate the electron pair-distribution functions and exchange-correlation…

Strongly Correlated Electrons · Physics 2009-11-11 M. W. C. Dharma-wardana

In this work we examine thermodynamics of fluid with "molecules" represented by two fused hard spheres, decorated by the attractive square-well sites. Interactions between these sites are of short-range and cause association between the…

Soft Condensed Matter · Physics 2016-03-24 M. Kastelic , Yu. V. Kalyuzhnyi , V. Vlachy

We present a density functional scheme for calculating the pair density (PD) by means of the correlated wave function. This scheme is free from both of problems related to PD functional theory, i.e., (a) the need to constrain the…

Strongly Correlated Electrons · Physics 2015-06-25 Masahiko Higuchi , Katsuhiko Higuchi

Particle pair-correlations are broadly used to describe particle distributions in chemistry, physics, and material science. Many theoretical methods require the pair-correlation to predict material properties such as fluid flow, thermal…

Soft Condensed Matter · Physics 2024-05-31 Aris Karnezis , Art L. Gower

Two basic correlation functions are calculated for a model of $N$ harmonically interacting identical particles in a parabolic potential well. The density and the pair correlation function of the model are investigated for the boson case.…

Statistical Mechanics · Physics 2009-10-30 F. Brosens , J. T. Devreese , L. F. Lemmens

The pair distribution function (PDF) is a key quantity for the analysis of correlation effects of a quantum system both in equilibrium and far from equilibrium. We derive an expression for the PDF in terms of the single-particle Green's…

Strongly Correlated Electrons · Physics 2013-09-19 M. Bonitz , S. Hermanns , K. Kobusch , K. Balzer

The macroscopic behavior of the solution of a coupled system of partial differential equations arising in the modeling of reaction-diffusion processes in periodic porous media is analyzed. Our mathematical model can be used for studying…

Analysis of PDEs · Mathematics 2019-06-19 G. Cardone , C. Perugia , C. Timofte

Pair densities and associated correlation functions provide a critical tool for introducing many-body correlations into a wide-range of effective theories. Ab initio calculations show that two-nucleon pair-densities exhibit strong spin and…