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High-accuracy calculations of electric dipole polarizabilities and quadrupole moments ($\Theta$) of the clock states of the singly charged calcium (Ca$^+$), strontium (Sr$^+$) and barium (Ba$^+$) alkaline-earth ions are estimated by…

Atomic Physics · Physics 2026-01-28 A. Chakraborty , Vaibhav Katyal , B. K. Sahoo

$^{229}$Th is a promising candidate for developing a nuclear optical clock and searching the new physics beyond the standard model. Accurate knowledge of the nuclear properties of $^{229}$Th is very important. In this work, we calculate…

Atomic Physics · Physics 2022-01-05 Fei-Chen Li , Hao-Xue Qiao , Yong-Bo Tang , Ting-Yun Shi

The thorium nucleus with mass number $A=229$ has attracted much interest because its extremely low lying first excited isomeric state at about $8$eV opens the possibility for the development of a nuclear clock. However, neither the exact…

The isotope $^{229}$Th is unique in that it possesses an isomeric state of only a few eV above the ground state, suitable for nuclear laser excitation. An optical clock based on this transition is expected to be a very sensitive probe for…

Determination of nuclear moments for many nuclei relies on the computation of hyperfine constants, with theoretical uncertainties directly affecting the resulting uncertainties of the nuclear moments. In this work we improve the precision…

Atomic Physics · Physics 2022-01-05 S. G. Porsev , M. S. Safronova , M. G. Kozlov

Accurate calculations of electric dipole polarizabilities ($\alpha_d$), quadrupole moments ($\Theta$), and quadrupole polarizabilities ($\alpha_q$) for the clock states of the singly charged calcium (Ca$^+$) and ytterbium (Yb$^+$) ions are…

Atomic Physics · Physics 2025-02-11 YanMei Yu , B. K. Sahoo

Contemplating to register signature of a new vector boson unambiguously from the measured non-linear isotope shift (IS) effects in three recent experiments [Phys. Rev. X {\bf 12}, 021033 (2022); Phys. Rev. Lett. {\bf 128}, 163201 (2022) and…

Atomic Physics · Physics 2025-04-03 B. K. Sahoo

We use advanced computational techniques to study the electronic structure of the Hf$^{12+}$ ion, with the goal of assessing its potential for use in highly accurate atomic optical clocks and search for new physics. Such clocks should…

Atomic Physics · Physics 2025-11-04 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

The isotope $^{229}$Th is the only nucleus known to possess an excited state $^{229m}$Th in the energy range of a few electron volts, a transition energy typical for electrons in the valence shell of atoms, but about four orders of…

Motivated by recent experimental advances, including the ongoing development of an optical atomic clock in singly ionised radium, we perform a detailed theoretical characterisation of Ra+ and its lighter analogue, Ba+. Both ions are of…

Atomic Physics · Physics 2025-09-30 Robin B. Cserveny , Benjamin M. Roberts

The $^{229}\text{Th}$ isotope is a promising candidate for nuclear clocks, with its transition frequency influenced by electron-induced nuclear frequency shifts. This effect is comparatively small and requires high-precision theoretical…

Atomic Physics · Physics 2025-05-09 Ran Si , Chaofan Shi , Nan Xue , Xiangjin Kong , Chongyang Chen , Bingsheng Tu , Yu-Gang Ma

A systematic study of Ca+ atomic properties is carried out using high-precision relativistic all-order method where all single, double, and partial triple excitations of the Dirac-Fock wave functions are included to all orders of…

Atomic Physics · Physics 2015-05-20 M. S. Safronova , U. I. Safronova

By combining our theoretical calculation and recently measured electric quadrupole hyperfine structure constant of the $3d ^2D_{5/2}$ state in the singly ionized $^{43}$Ca, we determine its nuclear quadrupole moment to one percent accuracy.…

Atomic Physics · Physics 2015-05-13 B. K. Sahoo

We have investigated energies, magnetic dipole hyperfine structure constants ($A_{hyf}$) and electric dipole (E1) matrix elements of a number of low-lying states of the triply ionized tin (Sn$^{3+}$) by employing relativistic…

Atomic Physics · Physics 2020-04-22 Mandeep Kaur , Rishabh Nakra , Bindiya Arora , Cheng-Bin Li , B. K. Sahoo

Atomic properties of the 24 low-lying ns, np, nd, nf, and ng states in Th IV ion are calculated using the high-precision relativistic all-order method where all single, double, and partial triple excitations of the Dirac-Fock wave functions…

Atomic Physics · Physics 2015-06-15 M. S. Safronova , U. I. Safronova

We evaluate the electric quadrupole moments of the ${^1}\!S_0$ and ${^3}\!P_0$ clock states of $^{27}$Al$^+$ and $^{115}$In$^+$. To capture all dominant contributions, our analysis extends through third order of perturbation theory and…

Atomic Physics · Physics 2017-04-11 K. Beloy , D. R. Leibrandt , W. M. Itano

In heavy atoms and ions, nuclear structure effects are significantly enhanced due to the overlap of the electron wave functions with the nucleus. This overlap rapidly increases with the nuclear charge $Z$. We study the energy level shifts…

Atomic Physics · Physics 2021-03-17 V. V. Flambaum , I. B. Samsonov , H. B. Tran Tan , A. V. Viatkina

We use the nuclear density functional theory to determine nuclear electric quadrupole and magnetic dipole moments in all one-particle and one-hole neighbours of eight doubly magic nuclei. We align angular momenta along the intrinsic…

Nuclear Theory · Physics 2022-10-06 P. L. Sassarini , J. Dobaczewski , J. Bonnard , R. F. Garcia Ruiz

We report the results of theoretical investigation of electronic structure of ThF$^+$ cation which is one of the most interesting systems to search for the electron electric dipole moment (eEDM) [H. Loh, K.C. Cossel, M.C. Grau, K.-K. Ni,…

Atomic Physics · Physics 2015-05-01 L. V. Skripnikov , A. V. Titov

Divalent atoms and ions with a singlet $S$ ground state and triplet $P$ excited state form the basis of many high-precision optical atomic clocks. Along with the metastable $^{3}\mathrm{P}_{0}$ clock state, these atomic systems also have a…

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