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The coupled dynamics of entangled polymers which span a broad time and length scales govern the unique viscoelastic properties of polymers. To follow chain mobility by numerical simulations from the intermediate Rouse and reptation regimes…

Soft Condensed Matter · Physics 2016-11-03 Gary S. Grest

The depletion interaction mediated by non-adsorbing polymers promotes condensation and assembly of repulsive colloidal particles into diverse higher-order structures and materials. One example, with particularly rich emergent behaviors, is…

Soft Condensed Matter · Physics 2016-02-23 Louis Kang , Thomas Gibaud , Zvonimir Dogic , T. C. Lubensky

The size of rings (also called cyclic polymers) in bidisperse blends of chemically identical rings is analyzed by computer simulations. Data of entangled ring blends and blends of interpenetrating rings are compared and it is shown that the…

Soft Condensed Matter · Physics 2021-03-31 Michael Lang

Ring polymers are characterized by topology-specific entanglements called threadings. In the limit of large rings, it is conjectured that a "topological glass" should emerge due to the proliferation of threadings. In this study, we used…

Soft Condensed Matter · Physics 2024-11-19 Shota Goto , Takenobu Nakamura , Davide Michieletto , Kang Kim , Nobuyuki Matubayasi

The mechanism and driving forces of chromosome segregation in the bacterial cell cycle of E. coli is one of the least understood events in its life cycle. Using principles of entropic repulsion between polymer loops confined in a cylinder,…

Soft Condensed Matter · Physics 2021-12-24 Debarshi Mitra , Shreerang Pande , Apratim Chatterji

We report molecular dynamics simulations of the segregation of two overlapping chains in cylindrical confinement. We find that the entropic repulsion between the chains can be sufficiently strong to cause segregation on a time scale that is…

Soft Condensed Matter · Physics 2011-11-09 Axel Arnold , Suckjoon Jun

Polymer-related materials exhibit rich glassy behaviors at different length scales due to their various molecular structures and topological constraints. Recent studies have identified transient interpenetration of the long-chain rings…

Soft Condensed Matter · Physics 2024-07-08 Jian Li , Bokai Zhang , Yushan Li

Topological constraints (TCs) between polymers determine the behaviour of complex fluids such as creams, oils and plastics. Most of the polymer solutions used every day life employ linear chains; their behaviour is accurately captured by…

Soft Condensed Matter · Physics 2020-10-07 Fabio Landuzzi , Takenobu Nakamura , Davide Michieletto , Takahiro Sakaue

Loop formation between monomers in the interior of semiflexible chains describes elementary events in biomolecular folding and DNA bending. We calculate analytically the interior distance distribution function for semiflexible chains using…

Soft Condensed Matter · Physics 2009-11-11 Changbong Hyeon , D. Thirumalai

We investigate, using numerical simulations, the conformations of isolated active ring polymers. We find that the their behaviour depends crucially on their size: short rings ($N \lesssim$ 100) are swelled whereas longer rings ($N \gtrsim$…

Soft Condensed Matter · Physics 2021-03-03 Emanuele Locatelli , Valentino Bianco , Paolo Malgaretti

The statistical theory of polymers tethered around the inner surface of a cylindrical channel has traditionally employed the assumption that the equilibrium density of the polymers is independent of the azimuthal coordinate. However,…

Soft Condensed Matter · Physics 2015-01-30 D. Osmanovic , M. Kerr-Winter , R. C. Eccleston , B. W. Hoogenboom , I. J. Ford

Understanding how topological constraints affect the dynamics of polymers in solution is at the basis of any polymer theory and it is particularly needed for melts of rings. These polymers fold as crumpled and space-filling objects and,…

Soft Condensed Matter · Physics 2017-11-15 D. Michieletto , N. Nahali , A. Rosa

The statistical mechanics of polymer loops entangled in the two-dimensional array of randomly distributed obstacles of infinite length is discussed. The area of the loop projected to the plane perpendicular to the obstacles is used as a…

Condensed Matter · Physics 2009-10-28 Matthias Otto , Thomas A. Vilgis

In the presented work we study, by means of numerical simulations, the behaviour of a suspension of active ring polymers in the bulk and under lateral confinement. When changing the separation between the confining planes and the polymers'…

Soft Condensed Matter · Physics 2023-07-31 Juan Pablo Miranda-López , Emanuele Locatelli , Chantal Valeriani

We examine the dynamics of entanglement entropy of all parts in an open system consisting of a two-level dimer interacting with an environment of oscillators. The dimer-environment interaction is almost energy conserving. We find the…

Quantum Physics · Physics 2018-05-09 M. Merkli , G. P. Berman , R. T. Sayre , X. Wang , A. I. Nesterov

Equilibrium states of a closed semiflexible polymer binding to a cylinder are described. This may be either by confinement or by constriction. Closed completely bound states are labeled by two integers: the number of oscillations, $n$, and…

Soft Condensed Matter · Physics 2017-11-17 Pablo Vázquez-Montejo , Zachary McDargh , Markus Deserno , Jemal Guven

Circuit topology refers to the arrangement of interactions between objects belonging to a linearly ordered object set. Linearly ordered set of objects are common in nature and occur in a wide range of applications in economics, computer…

Disordered Systems and Neural Networks · Physics 2015-09-02 Alireza Mashaghi , Abolfazl Ramezanpour

We study the rotational dynamics of a flexible polymer initially wrapped around a rigid rod and unwinding from it. This dynamics is of interest in several problems in biology and constitutes a fundamental instance of polymer relaxation from…

Soft Condensed Matter · Physics 2014-07-29 Jean-Charles Walter , Marco Baiesi , Enrico Carlon , Helmut Schiessel

Entangled networks of stiff biopolymers exhibit complex dynamic response, emerging from the topological constraints that neighboring filaments impose upon each other. We propose a class of reference models for entanglement dynamics of stiff…

Soft Condensed Matter · Physics 2008-06-23 Felix Höfling , Tobias Munk , Erwin Frey , Thomas Franosch

By using the blob theory and computer simulations, we investigate the properties of a linear polymer performing a stationary rotational motion around a long impenetrable rod. In particular, in the simulations the rotation is induced by a…