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Numerous few-electron atomic systems are considered which can be used effectively for observing a potential variation of the fine-structure constant $\alpha$ and the electron-proton mass ratio $m_e/m_p$. We examine optical magnetic dipole…

Recently it was pointed out that transition frequencies in certain diatomic molecules have an enhanced sensitivity to variations in the fine-structure constant $\alpha$ and the proton-to-electron mass ratio $m_p/m_e$ due to a near…

Atomic Physics · Physics 2010-08-31 K. Beloy , A. Borschevsky , P. Schwerdtfeger , V. V. Flambaum

It has been proposed that the radio-frequency electric-dipole (E1) transition between two nearly degenerate opposite-parity states in atomic dysprosium should be highly sensitive to possible temporal variation of the fine structure constant…

Atomic Physics · Physics 2009-11-10 A. T. Nguyen , D. Budker , S. K. Lamoreaux , J. R. Torgerson

The search for variation of the fundamental constants such as the fine structure constant $\alpha$ ($\alpha=e^2/\hbar c$) and the ratios of fundamental masses (e.g., electron to proton mass ratio $\mu=m_e/m_p$) is reviewed. Strong emphasis…

Atomic Physics · Physics 2015-05-13 V. V. Flambaum , V. A. Dzuba

Dependence of transition frequencies on the fine structure constant $\alpha=e^2/\hbar c$ is calculated for several many-electron systems which are used or planned to be used in the laboratory search for the time variation of the fine…

Atomic Physics · Physics 2009-11-13 V. A. Dzuba , V. V. Flambaum

Molecular vibrational transitions are prime candidates for model-independent searches for variation of the proton-to-electron mass ratio. Searches for present-day variation achieve highest sensitivity with deep molecular potentials. We…

Atomic Physics · Physics 2016-11-15 D. Hanneke , R. A. Carollo , D. A. Lane

Microwave and submillimeter molecular transition frequencies between nearly degenerated rotational levels, tunneling transitions, and mixed tunneling-rotational transitions show an extremely high sensitivity to the values of the…

Atomic Physics · Physics 2016-10-26 M. G. Kozlov , S. A. Levshakov

We present a review of recent works devoted to the variation of the fine structure constant alpha, strong interaction and fundamental masses. There are some hints for the variation in quasar absorption spectra, Big Bang nucleosynthesis, and…

Atomic Physics · Physics 2009-08-18 V. V. Flambaum

Sensitivity to temporal variation of the fundamental constants may be strongly enhanced in transitions between narrow close levels of different nature. This enhancement may be realized in a large number of molecules due to cancelation…

Atomic Physics · Physics 2008-11-26 V. V. Flambaum , M. G. Kozlov

Ultracold molecules offer brand new opportunities to probe the variation of fundamental constants with unprecedented sensitivity. This paper summarizes theoretical background and current constraints on the variation of fine structure…

Other Condensed Matter · Physics 2009-05-15 Cheng Chin , V. V. Flambaum , M. G. Kozlov

Astrophysical molecular spectroscopy is an important method of searching for new physics through probing the variation of the proton-to-electron mass ratio, $\mu$, with existing constraints limiting variation to a fractional change of less…

Chemical Physics · Physics 2020-08-26 Anna-Maree Syme , Adam Mousley , Maria Cunningham , Laura K McKemmish

Peik and Tamm [Europhys. Lett. 61, 181 (2003)] proposed a nuclear clock based on the isomeric transition between the ground state and the first excited state of thorium-229. This transition was recognized as a potentially sensitive probe of…

Atomic Physics · Physics 2021-01-19 Pavel Fadeev , Julian C. Berengut , Victor V. Flambaum

Experiments aimed at searching for variations in the fine-structure constant $\alpha$ are based on spectroscopy of transitions in microscopic bound systems, such as atoms and ions, or resonances in optical cavities. The sensitivities of…

Atomic Physics · Physics 2023-05-22 Beata Zjawin , Marcin Bober , Roman Ciuryło , Daniel Lisak , Michał Zawada , Piotr Wcisło

We estimate sensitivity coefficients to variation of the fine-structure constant alpha and electron-to-proton mass ratio mu for microwave Lambda-type transitions in CH molecule and for inversion-rotational transitions in partly deuterated…

Cosmology and Nongalactic Astrophysics · Physics 2009-10-27 M. G. Kozlov , A. V. Lapinov , S. A. Levshakov

Theories unifying gravity and other interactions suggest the possibility of spatial and temporal variation of physical ``constants'' in the Universe. Detection of high-redshift absorption systems intersecting the sight lines towards distant…

Atomic Physics · Physics 2009-08-18 V. A. Dzuba , V. V. Flambaum , J. K. Webb.

Theories unifying gravity with other interactions suggest spatial and temporal variation of fundamental "constants" in the Universe. A change in the fine structure constant, alpha, could be detected via shifts in the frequencies of atomic…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-20 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , J. A. King , M. G. Kozlov , M. T. Murphy , J. K. Webb

We identify two metastable excited states in Sm$ ^{10+} $ highly charged ion as candidates for high accuracy optical clocks. Several atomic properties relevant to optical clock development are calculated using relativistic many-body…

High Energy Physics - Phenomenology · Physics 2024-09-04 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

In 2003 we have measured the absolute frequency of the $(1S, F=1, m_F=\pm 1) \leftrightarrow (2S, F'=1, m_F'=\pm 1)$ two-photon transition in atomic hydrogen. We observed a variation of $(-29\pm 57)$ Hz over a 44 months interval separating…

An electronically variational approach to the calculation of atomic hyperfine structure transition energies under the influence of static external electric fields is presented. The method avoids the calculation of intermediate atomic states…

Atomic Physics · Physics 2025-08-29 Timo Fleig

Radio-frequency electric-dipole transitions between nearly degenerate, opposite parity levels of atomic dysprosium (Dy) were monitored over an eight-month period to search for a variation in the fine-structure constant, $\alpha$. The data…

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