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The microscopic mechanisms involved in the formation/dissociation of methane hydrate confined at the nanometer scale are unraveled using advanced molecular modeling techniques combined with a mesoscale thermodynamic approach. By means of…

Chemical Physics · Physics 2021-04-28 Dongliang Jin , Benoit Coasne

Surface nanobubbles are stable gaseous phases in liquids that form on solid substrates. While their existence has been confirmed, there are many open questions related to their formation and dissolution processes along with their structures…

Fluid Dynamics · Physics 2022-04-20 Zhizhao Che , Panagiotis E. Theodorakis

Bubble formation in electrochemical system often hinders reaction efficiency by reducing active surface area and obstructing mass transfer, yet the mechanisms governing their nanoscale nucleation dynamics and impact remains unclear. In this…

Soft Condensed Matter · Physics 2025-09-26 Zhenlei Wanga , Yaxi Yua , Mengkai Qin , Hao Jiang , Zhenjiang Guo , Lu Bai , Limin Wang , Xiaochun Zhang , Xiangping Zhang , Yawei Liu

Formation, evolution, and vanishing of bubbles are common phenomena in our nature, which can be easily observed in boiling or falling waters, carbonated drinks, gas-forming electrochemical reactions, etc. However, the morphology and the…

The compartmentalization of chemical reactions within droplets has advantages in low costs, reduced consumption of reagents and increased throughput. Reactions in small droplets have also been shown to greatly accelerate the rate of many…

Soft Condensed Matter · Physics 2020-07-27 Brendan P. Dyett , Xuehua Zhang

Experimental investigations of hydrophobic/water interfaces often return controversial results, possibly due to the unknown role of gas accumulation at the interfaces. Here, during advanced atomic force microscopy of the initial evolution…

Mesoscale and Nanoscale Physics · Physics 2015-12-29 Ing-Shouh Hwang , Chung-Kai Fang , Hsien-Chen Ko , Chih-Wen Yang , Yi-Hsien Lu

We have designed and constructed an experimental system to study gas bubble growth in slightly supersatu- rated liquids. This is achieved by working with carbon dioxide dissolved in water, pressurized at a maximum of 1 MPa and applying a…

Electrogenerated gas nanobubbles strongly influence the performance of electrochemical energy-conversion systems, yet their nucleation and early evolution remain poorly understood due to limitations of existing experimental and…

Soft Condensed Matter · Physics 2026-01-19 Nima Shakourifar , Nana Ofori-Opoku , Benzhong Zhao

It has been recently shown that nanobubbles exhibit a remarkable and unexpected stability. The lifetime of nanobubbles, formed either within liquids or on hydrophobic surfaces, can exceed by more than 10 orders of magnitude the theoretical…

Soft Condensed Matter · Physics 2019-05-14 Caroline Desgranges , Jerome Delhommelle

The paper is dedicated to the mechanics of the methane bubbles in the gas hydrate stability zone of the basin. Transformation of deep-water methane bubbles into solid hydrate was investigated in Lake Baikal in situ. Released from the bottom…

Fluid Dynamics · Physics 2013-06-25 Alexander V. Egorov , Robert I. Nigmatulin , Aleksey N. Rozhkov

Clathrate hydrates are vital in energy research and environmental applications. Understanding their stability is crucial for harnessing their potential. In this work, we employ direct coexistence simulations to study finite-size effects in…

Soft Condensed Matter · Physics 2024-08-06 S. Blazquez , J. Algaba , J. M. Míguez , C. Vega , F. J. Blas , M. M. Conde

Under continuous laser irradiation, noble metal nanoparticles immersed in water can quickly heat up, leading to the nucleation of so-called plasmonic bubbles. In this work, we want to further understand the bubble nucleation and growth…

Fluid phase equilibria involving nano-dispersed phases, where at least one of the coexisting phases is confined to a small volume, are investigated by molecular dynamics simulation. Complementing previous studies on nanoscopic droplets,…

Mesoscale and Nanoscale Physics · Physics 2013-07-23 Martin Horsch , Hans Hasse

Bubble nucleation in liquid confined in nanochannel is studied using molecular dynamics simulations and compared against nucleation in the liquid over smooth (i.e. without confinement). Nucleation is achieved by heating part of a surface to…

Fluid Dynamics · Physics 2022-01-24 Manish Gupta , Shalabh C. Maroo

Nanobubbles in liquids are mysterious gaseous objects having exceptional stability. They promise a wide range of applications but their production is not well controlled and localized. Alternating polarity electrolysis of water is a tool…

Soft Condensed Matter · Physics 2017-12-27 Alexander V. Postnikov , Ilia V. Uvarov , Nikita V. Penkov , Vitaly B. Svetovoy

The formation and decomposition of methane hydrates, particularly in porous media such as subsea sediments, have attracted significant research interest due to their implications for energy production, storage, and safety in deep-sea…

Applied Physics · Physics 2024-10-01 Yuze Wang , Jianyu Yang , Pengfei Wang , Jinlong Zhu , Yongshun John Chen

We present the results of dynamic in-situ 3D X-ray imaging of methane hydrates microstructure during methane hydrate formation and decomposition in sand samples. Short scanning times and high resolution provided by synchrotron X-rays…

Surface nanobubbles are complex micro- and nanoscale fluid systems. While thermodynamics is believed to dominate nanobubble dynamics, the precise mechanism by which nanobubble evolution is driven by thermodynamics remains unclear. It is…

Soft Condensed Matter · Physics 2025-02-06 Lili Lan , Yongcai Pan , Liang Zhao , Binghai Wen

Nanobubble-related technologies have been confirmed to be useful in various fields such as climate change and the environment as well as water-based industries such as water purification, crops, horticulture, medical care, bio, and…

Fluid Dynamics · Physics 2023-10-26 Taekeun Yoo , Young-Ho Yoo , Suk-Joo Byun , A-Ram You , Chang-Hee Park , Dae-Hyun Choi , Eun-Hee Jun

Gas hydrates grown at gas-ice interfaces are examined by electron microscopy and found to have a submicron porous texture. Permeability of the intervening hydrate layers provides the connection between the two counterparts (gas and water…

Chemical Physics · Physics 2015-11-03 Andrey N Salamatin , Werner F Kuhs
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