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The most advanced techniques using fault-tolerant quantum computers to estimate the ground-state energy of a chemical Hamiltonian involve compression of the Coulomb operator through tensor factorizations, enabling efficient block-encodings…

H\"uckel molecular orbital (HMO) theory provides a semi-empirical treatment of the electronic structure in conjugated {\pi}-electronic systems. A scalable system-agnostic execution of HMO theory on a quantum computer is reported here based…

Quantum Physics · Physics 2024-05-22 Harshdeep Singh , Sonjoy Majumder , Sabyashachi Mishra

Quantum chemistry provides a target for quantum simulation of considerable scientific interest and industrial importance. The majority of algorithms to date have been based on a second-quantized representation of the electronic structure…

Quantum Physics · Physics 2013-12-17 Borzu Toloui , Peter J. Love

Owing to the computational complexity of electronic structure algorithms running on classical digital computers, the range of molecular systems amenable to simulation remains tightly circumscribed even after many decades of work. Quantum…

Quantum Physics · Physics 2022-05-18 Alexis Ralli , Michael I. Williams , Peter V. Coveney

We analyze the modification of entanglement dynamics in the Grover algorithm when the qubits are subjected to single-qubit amplitude-damping or phase-flip noise. We compare quantum trajectories with full density-matrix simulations,…

Quantum Physics · Physics 2026-02-20 Raphaël Menu , Johannes Schachenmayer

In recent work [arXiv:2003.06939v2] a novel fermion to qubit mapping -- called the compact encoding -- was introduced which outperforms all previous local mappings in both the qubit to mode ratio, and the locality of mapped operators. There…

Quantum Physics · Physics 2021-01-27 Charles Derby , Joel Klassen

Many-body fermionic quantum calculations performed on analog quantum computers are restricted by the presence of k-local terms, which represent interactions among more than two qubits. These originate from the fermion-to-qubit mapping…

Recent development of mixed-state encoding (MSE) allows pure-state logical information to be encoded by a bosonic (continuous-variable) system in mixed physical state. Despite interest due to its counter-intuitiveness, the utility of the…

Quantum Physics · Physics 2019-04-03 Kevin Marshall , Daniel F. V. James , Alexandru Paler , Hoi-Kwan Lau

Quantum computers potentially have an exponential advantage over classical computers for the quantum simulation of many-fermion quantum systems. Nonetheless, fermions are more expensive to simulate than bosons due to the fermionic encoding…

Quantum Physics · Physics 2022-06-29 Scott E. Smart , David A. Mazziotti

Quantum computer emulators model the behavior and error rates of specific quantum processors. Without accurate noise models in these emulators, it is challenging for users to optimize and debug executable quantum programs prior to running…

Quantum Physics · Physics 2026-05-20 Matthew Ho , Jun Yong Khoo , Adrian M. Mak , Stefano Carrazza

We introduce a general method based on the operators of the Dyson-Masleev transformation to map the Hamiltonian of an arbitrary model system into the Hamiltonian of a circuit Quantum Electrodynamics (cQED) processor. Furthermore, we…

Quantum computational chemistry holds great promise for simulating molecular systems more efficiently than classical methods by leveraging quantum bits to represent molecular wavefunctions. However, current implementations face significant…

Quantum Physics · Physics 2025-09-10 Weitang Li , Shi-Xin Zhang , Zirui Sheng , Cunxi Gong , Jianpeng Chen , Zhigang Shuai

We introduce novel algorithms for the quantum simulation of molecular systems which are asymptotically more efficient than those based on the Trotter-Suzuki decomposition. We present the first application of a recently developed technique…

Solid-state spin qubits have emerged as promising platforms for quantum information. Despite extensive efforts in controlling noise in spin qubit quantum applications, one important but less controlled noise source is near-field…

Quantum Physics · Physics 2024-09-18 Wenbo Sun , Sathwik Bharadwaj , Runwei Zhou , Dan Jiao , Zubin Jacob

A promising route towards fault-tolerant quantum error correction is the concatenation of a Gottesman-Kitaev-Preskill (GKP) code with a qubit code. Development of such concatenated codes requires simulation tools which realistically model…

We explore how the fundamental problems in quantum molecular dynamics can be modelled using classical simulators (emulators) of quantum computers and the actual quantum hardware available to us today. The list of problems we tackle includes…

Quantum Physics · Physics 2025-07-29 Tamila Kuanysheva , Brian Kendrick , Lukasz Cincio , Dmitri Babikov

The variational quantum eigensolver (VQE) is one of the most appealing quantum algorithms to simulate electronic structure properties of molecules on near-term noisy intermediate-scale quantum devices. In this work, we generalize the VQE…

Quantum Physics · Physics 2022-06-09 Jie Liu , Lingyun Wan , Zhenyu Li , Jinlong Yang

Scalable characterization of quantum processors is crucial for mitigating noise and imperfections. While randomized measurement protocols enable efficient access to local observables, inferring a globally consistent description of…

Quantum Physics · Physics 2026-03-10 Zidu Liu , Dominik S. Wild

The required precision to perform quantum simulations beyond the capabilities of classical computers imposes major experimental and theoretical challenges. The key to solving these issues are precise means of characterizing analog quantum…

Quantum Physics · Physics 2024-11-11 Dominik Hangleiter , Ingo Roth , Jonas Fuksa , Jens Eisert , Pedram Roushan

Quantum algorithms offer a dramatic speedup for computational problems in machine learning, material science, and chemistry. However, any near-term realizations of these algorithms will need to be heavily optimized to fit within the finite…

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