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The high performance of hybrid perovskite based devices is attributed to its excellent bulk-transport properties. However, carrier dynamics, especially at the metal-perovskite interface, and its influence on device operation are not widely…

Materials Science · Physics 2022-02-25 N. Ganesh , A. Z. Ashar , Sumukh Purohit , K. L. Narasimhan , K. S. Narayan

Strong coupling between lead halide perovskite materials and optical resonators enables both the polaritonic control of the photophysical properties of these emerging semiconductors and the observation of novel fundamental physical…

Electron-positron momentum distributions measured by the coincidence Doppler broadening method can be used in the chemical analysis of the annihilation environment, typically a vacancy-impurity complex in a solid. In the present work, we…

Materials Science · Physics 2007-05-23 P. Folegati , I. Makkonen , R. Ferragut , M. J. Puska

The competition between corner, edge and face-sharing octahedral networks is a cause of phase inhomogeneity in metal halide perovskite thin-films. Here we probe the charged iodine vacancy distribution and transport at the junction between…

Materials Science · Physics 2022-11-03 Young Won Woo , Zhenzhu Li , Young-Kwang Jung , Ji-Sang Park , Aron Walsh

Inorganic-organic perovskites semiconductors are becoming increasingly interesting due to their remarkable optical properties, such as a high photoluminescence quantum yield and the possibility to show optical gain in a broad range of…

Optics · Physics 2021-03-30 Michele Bellingeri , Francesco Scotognella

Stability is one of the key issues in mixed-halide perovskite alloys which are promising in emergent optoelectronics. Previous density-functional-theory (DFT) and machine learning studies indicate that the formation-energy convex hulls of…

Materials Science · Physics 2024-03-01 Fang Pan , Junni Zhai , Jinyu Chen , Lin Yang , Hua Dong , Fang Yuan , Zhuangde Jiang , Wei Ren , Zuo-Guang Ye , Guo-Xu Zhang , Jingrui Li

In recent years, metal halide perovskites have generated tremendous interest for optoelectronic applications and their underlying fundamental properties. Due to the large electron-phonon coupling characteristic of soft lattices,…

The assignment of an exact space group to the tetragonal CH$_3$NH$_3$PbI$_3$ perovskite structure is experimentally challenging and controversial in the literature. Average orientation of the methylammonium ion that gives symmetry to the…

Materials Science · Physics 2023-01-27 Kuntal Talit , David A. Strubbe

Metal halide perovskites (MHPs) are nowadays one of the most studied semiconductors due to their exceptional performance as active layers in solar cells. Although MHPs are excellent solid-state semiconductors, they are also ionic compounds,…

Organic-inorganic hybrid perovskites (OIHPs) have recently emerged as groundbreaking semiconductor materials owing to their remarkable properties. Transmission electron microscopy (TEM), as a very powerful characterization tool, has been…

Materials Science · Physics 2024-02-05 Yu-Hao Deng

Lead halide perovskites (MAPbX3) are known to have high refractive index and controllable bandgap, making them attractive for all-dielectric and tunable metasurfaces. Till now, perovskite metasurfaces have only been used in structural…

Applied Physics · Physics 2019-04-03 Chen Zhang , Yuhan Wang , Yisheng Gao , Yubin Fan , Can Huang , Nan Zhang , Wenhong Yang , Qinghai Song , Shumin Xiao

Migration of halogen vacancies is one of the primary sources of phase segregation and material degradation in lead-halide perovskites. Here we use first principles density functional theory to compare migration energy barriers and paths of…

Materials Science · Physics 2021-07-07 Raisa-Ioana Biega , Linn Leppert

We use path integral Monte Carlo to study the energetics of excitons in layered, hybrid organic-inorganic perovskites in order to elucidate the relative contributions of dielectric confinement and electron-phonon coupling. While the…

Materials Science · Physics 2025-03-26 Rohit Rana , David T. Limmer

The long charge carrier lifetime of the hybrid organic-inorganic perovskites (HOIPs) is the key for their remarkable performance as a solar cell material. The microscopic mechanism for the long lifetime is still in debate. Here, by using…

Materials Science · Physics 2022-04-05 A. Koda , H. Okabe , M. Hiraishi , R. Kadono , K. A. Dagnall , J. J. Choi , S. -H. Lee

Band structure of inorganic lead halide perovskites is substantially different from the band structure of group IV, III-V and II-VI semiconductors. However, the standard empirical tight-binding model with sp3d5s* basis gives nearly perfect…

Mesoscale and Nanoscale Physics · Physics 2023-09-12 M. O. Nestoklon

Lead halide perovskites (LHPs) are promising materials for opto-electronics and photovoltaics, thanks to favorable characteristics and low manufacturing costs enabled by solution processing. In light of this, it is crucial to assess the…

Materials Science · Physics 2021-10-01 Giovanni Procida , Richard Schier , Ana M. Valencia , Caterina Cocchi

Lead-halide perovskites (LHPs) have shot to prominence as efficient energy conversion materials that can be processed using cost-effective fabrication methods. A widely-quoted reason for their exceptional performance is their ability to…

Materials Science · Physics 2024-08-30 Irea Mosquera-Lois , Yi-Teng Huang , Hugh Lohan , Junzhi Ye , Aron Walsh , Robert L. Z. Hoye

Purpose: Measuring the ortho-positronium (oPs) lifetime in human tissue bears the potential of adding clinically relevant information about the tissue microenvironment to conventional positron emission tomography (PET). Through phantom…