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We use a group theoretical approach to enumerate the possible couplings between magnetism and ferroelectric polarisation in the parent $Pm\bar{3}m$ perovskite structure. We show that third order magnetoelectric coupling terms must always…

Materials Science · Physics 2018-05-18 Mark S. Senn , Nicholas C. Bristowe

We have performed a comprehensive, first-principles high-throughput study of the magnetic properties of halide double perovskites, $Cs_2BB^\prime Cl_6$, with magnetic ions occupying one or both B and B$^\prime$ sites. Our findings indicate…

Materials Science · Physics 2023-06-16 Utkarsh Singh , Johan Klarbring , Igor A. Abrikosov , Sergei I. Simak

Piezoelectrics play a critical role in various applications. The permanent dipole associated with the molecular cations in organometal-halide perovskites (OMHPs) may lead to spontaneous polarization and thus piezoelectricity. Here, we…

Materials Science · Physics 2015-12-17 Shi Liu , Fan Zheng , Ilya Grinberg , Andrew M. Rappe

We have investigated the magnetic and dielectric properties of orthorhombic Eu$_{1-y}$Y$_y$MnO$_3$ ($0\leq y\leq 0.6$) single crystals without the presence of the 4$f$ magnetic moments of the rare-earth ions. In $y\geq 0.2$, the…

Strongly Correlated Electrons · Physics 2015-05-28 Mitsuru Akaki , Masaaki Hitomi , Mizuaki Ehara , Daisuke Akahoshi , Hideki Kuwahara

We report the experimental determination of the structure and response to applied electric field of the lower-temperature nematic phase of the previously reported calamitic compound 4-[(4-nitrophenoxy)carbonyl]phenyl2,4-dimethoxybenzoate…

Here, the first-principles predictions on the structural stability, magnetic behavior and electronic structure of B-site ordered double perovskite Nd$_{2}$FeCrO$_{6}$ have been reported. Initially, the ground state of the parent single…

Materials Science · Physics 2022-01-10 M. D. I. Bhuyan , Rana Hossain , Ferdous Ara , M. A. Basith

We calculate the shift current response, which has been identified as the dominant mechanism for the bulk photovoltaic effect, for the polar compounds LiAsS$_\text{2}$, LiAsSe$_\text{2}$, and NaAsSe$_\text{2}$. We find that the magnitudes…

Materials Science · Physics 2014-12-04 John A. Brehm , Steve M. Young , Fan Zheng , Andrew M. Rappe

Layered ferromagnets are thrilling materials from both a fundamental and technological point of view. VI3 is an interesting example, with a complex magnetism that differentiates it from the first reported Cr based layered ferromagnets.…

The magnetic, thermodynamic, and pyroelectric properties of LiFeP$_2$O$_7$ single crystals are investigated with emphasis on the magnetoelectric interaction of the electrical polarization with the magnetic order parameter. The magnetic…

Strongly Correlated Electrons · Physics 2012-09-13 K. -C. Liang , W. Zhang , B. Lorenz , Y. Y. Sun , P. S. Halasyamani , C. W. Chu

We report magnetic, transport, neutron diffraction, and muon spin rotation data showing that Pb$_2$CoOsO$_6$, a newly synthesized metallic double-perovskite with a centrosymmetric space group at room temperature, exhibits a continuous…

Third-generation photovoltaic (PV) materials combine many advantageous properties, including a high optical absorption together with a large charge carrier mobility, facilitated by small effective masses. Halide perovskites (ABX3, where X…

Surface alignment of a recently discovered ferroelectric nematic liquid crystal (NF) is usually achieved by buffed polymer films, which produce a unidirectional polar alignment of the spontaneous electric polarization. We demonstrate that…

Type-II multiferroics, where spin interactions induce a ferroelectric polarization, are interesting for new device functionalities due to large magnetoelectric coupling. We report on a new type of multiferroicity in the quadruple-perovskite…

Despite the great technological and scientific importance, a well-controlled coupled behavior in magnetoelectric multiferroic materials at room temperature remains challenging. We demonstrate that the self-ordered A2BBO6 (e.g., A = La, B =…

Materials Science · Physics 2015-05-14 M. P. Singh , K. D. Truong , S. Jandl , P. Fournier

The structural, electronic, magnetic and ferroelectric properties of Pb free double perovskite multiferroic Bi2FeTiO6 are investigated using density functional theory within the general gradient approximation (GGA) method. Our structural…

Materials Science · Physics 2018-05-23 Lokanath Patra , P. Ravindran

We discuss the particle size driven tunability of the coexistence of ferromagnetism and ferroelectricity in Pr0.67Ca0.33MnO3(PCMO) with the help of x ray diffraction, magnetization, impedance spectroscopy, and remanent polarization…

Strongly Correlated Electrons · Physics 2014-12-25 Vinay Kumar Shukla , Soumik Mukhopadhyay , Kalipada Das , A. Sarma , I. Das

Pyroelectric current and magnetoelectric coupling measurements on polycrystalline samples of the quadruple perovskite (LaMn$_{3}$)Mn$_{4}$O$_{12}$ give evidence of ferroelectricity driven by the antiferromagnetic ordering of the $B$-site…

Bulk photovoltaic (BPV) effect, a second order nonlinear process that generates static current under light irradiation, requires centrosymmetric broken systems as its application platform. In order to realize measurable BPV photocurrent in…

Materials Science · Physics 2023-01-05 Xingchi Mu , Qianqian Xue , Yan Sun , Jian Zhou

We report coupling between magnetic and electric orders for antiferromagnetic polycrystalline FeVO4 in which magnetism-induced polarization has been recently found in noncollinear antiferromagnetic state below the second antiferromagnetic…

Materials Science · Physics 2009-11-17 Bohdan Kundys , Christine Martin , Charles Simon

The possibility that metals may support ferroelectricity is an open issue. Anderson and Blount showed that certain martensitic transitions involve inversion symmetry breaking and the formal existence of a polar axis, so 'metallic…

Materials Science · Physics 2016-04-08 Alessio Filippetti , Vincenzo Fiorentini , Francesco Ricci , Pietro Delugas , Jorge Íñiguez
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