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Many sub-Neptune exoplanets have been believed to be composed of a thick hydrogen-dominated atmosphere and a high-temperature heavier-element-dominant core. From an assumption that there is no chemical reaction between hydrogen and…
Recent claims of biosignature gases in sub-Neptune atmospheres have renewed interest in water-rich sub-Neptunes with surface oceans, often referred to as Hycean planets. These planets are hypothesized to form beyond the snow line, accreting…
Sub-Neptune exoplanets are commonly hypothesized to consist of a silicate-rich magma ocean topped by a hydrogen-rich atmosphere. Previous work studying the outgassing of silicate material has demonstrated that such atmosphere-interior…
Hydrogen, helium, silicates, and iron are key building blocks of rocky and gas-rich planets, yet their chemical interactions remain poorly constrained. Using first-principles molecular dynamics and thermodynamic integration, we quantify…
The evolution and structure of sub-Neptunes may be strongly influenced by interactions between the outer gaseous envelope of the planet and a surface magma ocean. However, given the wide variety of permissible interior structures of these…
We investigate the consequences of non-ideal chemical interaction between silicate and overlying hydrogen-rich envelopes for rocky planets using basic tenets of phase equilibria. Based on our current understanding of the temperature and…
Many planets in the solar system and across the galaxy have hydrogen-rich atmospheres overlying more heavy element-rich interiors with which they interact for billions of years. Atmosphere-interior interactions are thus crucial to…
Models based on variable miscibility among hydrogen, molten silicate, and molten iron, coupled with atmospheric escape, can reproduce the observed occurrence density structure of sub-Neptunes and super-Earths in mass-radius space. The…
The most abundant type of planet discovered in the Galaxy has no analogue in our Solar System and is believed to consist of a rocky interior with an overlying thick H2 dominated envelope. Models have predicted that the reaction between the…
Small planets ($\sim$1--3.9 $\Rearth$) constitute more than half of the inventory of the 4000-plus exoplanets discovered so far. Smaller planets are sufficiently dense to be rocky, but those with radii larger than $\sim$1.6 $\Rearth$ are…
Silica, water and hydrogen are known to be the major components of celestial bodies, and have significant influence on the formation and evolution of giant planets, such as Uranus and Neptune. Thus, it is of fundamental importance to…
Sub-Neptune planets formed in the protoplanetary disk accreted hydrogen-helium (H,He) envelopes. Planet formation models of sub-Neptunes formed by pebble accretion result in small rocky cores surrounded by polluted H,He envelopes where most…
We investigate equilibrium chemistry between molten metal and silicate, and a hydrogen-rich envelope using 18 independent reactions among 25 phase components for sub-Neptune-like exoplanets. Both reactive metal and unreactive metal…
Sub-Neptunes occupy an intriguing region of planetary mass-radius space, where theoretical models of interior structure predict that they could be water-rich, where water is in steam and supercritical state. Such planets are expected to…
The nature of sub-Neptunes remains unknown due to degeneracies in interior structure solutions. However, a statistical set of small planets with measured masses and radii can be used to test the planet formation theory prediction of large…
Rocky planet atmospheres form and evolve through interactions between the planet's surface and interior. If a growing rocky planet acquires enough mass prior to the dissipation of the nebular gas disk, it can gravitationally capture a…
Earth's water, intrinsic oxidation state, and metal core density are fundamental chemical features of our planet. Studies of exoplanets provide a useful context for elucidating the source of these chemical traits. Planet formation and…
The interaction between a magma ocean and a primordial atmosphere is increasingly recognized as a key process in shaping planetary envelope compositions. This coupling should strongly influence gas accretion, yet its role during the…
The population of small, close-in exoplanets is bifurcated into super-Earths and sub-Neptunes. We calculate physically motivated mass-radius relations for sub-Neptunes, with rocky cores and H/He dominated atmospheres, accounting for their…
In the pebble accretion scenario, the pebbles that form planets drift inward from the outer disk regions, carrying water ice with them. At the water ice line, the water ice on the inward drifting pebbles evaporates and is released into the…