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Achieving reliable and quantifiable performance in large-area surface-enhanced Raman spectroscopy (SERS) substrates has long been a formidable challenge. It requires substantial signal enhancement while maintaining a reproducible and…

Dense layers of overlapping three-dimensional (3D) gold nanodendrites characterized by high specific surfaces as well as by abundance of sharp edges and vertices creating high densities of SERS hotspots are promising substrates for…

Applied Physics · Physics 2019-08-19 Weijia Han , Elzbieta Stepula , Michael Philippi , Sebastian Schlücker , Martin Steinhart

The nature of the interface in lateral heterostructures of 2D monolayer semiconductors including its composition, size, and heterogeneity critically impacts the functionalities it engenders on the 2D system for next-generation…

Surface plasmon resonances of metallic nanostructures offer great opportunities to guide and manipulate light on the nanoscale. In the design of novel plasmonic devices, a central topic is to clarify the intricate relationship between the…

Optics · Physics 2019-09-11 Sanghyeon Yu , Habib Ammari

Revealing hidden non-radiative (dark) of resonant nanostructures using optical methods such as dark-field spectroscopy often becomes a sophisticated problem due to a weak coupling of these modes with a far-field radiation, whereas methods…

We investigate optical second-harmonic generation (SHG) from metasurfaces where noncentrosymmetric V-shaped gold nanoparticles are ordered into regular array configurations. In contrast to expectations, a substantial enhancement of the SHG…

Interaction between plasmonic nanostructures and molecules is modeled based on the concept of quantized optical cavity for surface enhanced Raman scattering process. We have found that the background emission from plasmonic nanostructures…

Optics · Physics 2017-03-22 Yuqing Cheng , Jingyi Zhao , Te Wen , Guantao Li , Jianning Xu , Qihuang Gong , Guowei Lu

The implementation of hyperbolic metamaterials as component in optical waveguides, semiconductor light emitters and solar cells has been limited by the inherent loss in the metallic layers. The features of a hyperbolic metamaterial arise by…

Applied Physics · Physics 2020-09-04 Michael A. Mastro

The hyperbolic dispersion relation of phonon-polaritons (PhPol) provides high-momentum states, highly directional propagation, subdiffractional confinement, large optical density of states, and enhanced light-matter interactions. In this…

Materials Science · Physics 2023-07-12 A. Bergeron , C. Gradziel , R. Leonelli , S. Francoeur

Plasmonic metamaterials support the localized surface plasmon resonance (LSPR), which is sensitive to the change in the dielectric environment and highly desirable for ultrasensitive biochemical sensing. In this work, a novel design of…

Optics · Physics 2017-11-15 Shuyuan Xiao , Tao Wang , Yuebo Liu , Xu Han , Xicheng Yan

Hotspots of surface-enhanced resonance Raman scattering (SERRS) are localized within 1 nm at gaps or crevices of plasmonic nanoparticle (NP) dimers. We demonstrate SERRS hotspots with volumes that are extended in one dimension tens of…

The spectral relationships between surface enhanced resonant Raman scattering (SERRS) and plasmon resonance observed in far field scattering cross are investigated using single silver nanoparticle dimers with focusing on the lowest energy…

Optics · Physics 2023-04-07 Tamitake Itoh , Yuko S. Yamamoto

This article reviews the new developments in Tip-enhanced Raman scattering (TERS). The fundamental mechanisms underlying the Raman enhancement are discussed, including the role of the plasmonic character of the metallic tips, the nature of…

Chemical Physics · Physics 2008-04-01 Catalin C. Neacsu , Samuel Berweger , Markus B. Raschke

The surface plasmon oscillations spectra in noble metal nanoparticles - rods and spheroids embedded in a host matrix is analyzed theoretically. The important role of - electrons in formation of surface plasmon resonances is shown. A simple…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Armen Melikyan , Hayk Minassian

We report a detailed study of the strong near-field Raman scattering enhancement which takes place in tip-enhanced Raman scattering (TERS) in indium nitride. In addition to the well-known first-order optical phonons of indium nitride,…

Optical imaging beyond the diffraction limit was one of the primary motivations for negative-index metamaterials, resulting in Pendry's perfect lens and the more attainable superlens. While these approaches offer sub-diffractional…

Regular arrays of metal nanoparticles on metal films have tuneable optical resonances that can be applied for surface enhanced Raman scattering or biosensing. With the aim of developing more surface selective geometries we investigate…

Mesoscale and Nanoscale Physics · Physics 2012-09-13 Andreas Hohenau , Joachim R. Krenn

Magneto-plasmonic nanostructures have emerged as promising candidates for advanced sensing applications. However, conventional fabrication methods, such as lithography and sputtering, often involve high costs and complex processes. This…

Raman spectroscopic investigations are carried out on one-dimensional nanostructures of InN,such as nanowires and nanobelts synthesized by chemical vapor deposition. In addition to the optical phonons allowed by symmetry; A1, E1 and…

Materials Science · Physics 2009-11-13 Satyaprakash Sahoo , M. S. Hu , C. W. Hsu , C. T. Wu , K. H. Chen , L. C. Chen , A. K. Arora , S. Dhara

The ability to engineer localized surface plasmon resonances at large scale usually relies on precise nanoscale patterning. Here, we demonstrate that mid-infrared plasmonic responses can instead emerge in unpatterned polysilicon films…

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