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Surface Enhanced Infrared Absorption (SEIRA) is an experimental method where trace amount of a compound can be detected with high sensibility. This high detection sensibility is the result of the interaction of the molecules with a…

Waveguide-integrated plasmonics is a growing field with many innovative concepts and demonstrated devices in the visible and near-infrared. Here, we extend this body of work to the mid-infrared for the application of surface-enhanced…

Optics · Physics 2018-12-05 Daniel A. Mohr , Daehan Yoo , Che Chen , Mo Li , Sang-Hyun Oh

A multiscale QM/classical approach is presented, that is able to model the optical properties of complex nanostructures composed of a molecular system adsorbed on metal nanoparticles. The latter are described by a combined…

Chemical Physics · Physics 2024-10-29 Pablo Grobas Illobre , Piero Lafiosca , Luca Bonatti , Tommaso Giovannini , Chiara Cappelli

Detecting trace molecules remains a significant challenge. Surface-enhanced infrared absorption (SEIRA) based on plasmonic nanostructures, particularly graphene, has emerged as a promising approach to enhance sensing sensitivity. While…

Mid-infrared (mid-IR) spectroscopy offers unparalleled opportunities in sensing through chemically specific detection of molecular absorption fingerprints. Yet, its practical applications are limited by the weak light-matter interaction in…

We investigate local heat generation by molecules at the apex of polymer-embedded vertical antennas excited at resonant mid-infrared wavelengths, exploiting the surface enhanced infrared absorption (SEIRA) effect. The embedding of vertical…

Surface-enhanced infrared absorption (SEIRA) spectroscopy exploits the field enhancement near nanophotonic structures for highly sensitive characterization of (bio)molecules. The vibrational signature observed in SEIRA spectra is typically…

Mid-infrared spectroscopy offers powerful label-free molecular analysis capabilities but faces significant challenges when analyzing complex biological samples. Here, we present a transformative surface-enhanced infrared absorption…

The absorption and emission spectrum arising from the vibrational motion of a molecule is mostly in the infrared region. These fingerprint absorptions of polar bonds enable us to acquire bond-specific chemical information from specimens.…

Optics · Physics 2024-11-15 Govind Dayal , Dheeraj Pratap

We have combined atomic layer lithography and template stripping to produce a new class of substrates for surface-enhanced infrared absorption (SEIRA) spectroscopy. Our structure consists of a buried and U-shaped metal-insulator-metal…

Optics · Physics 2022-04-19 Xiaoshu Chen , Cristian Ciracì , David R. Smith , Sang-Hyun Oh

Capabilities of highly sensitive surface-enhanced infrared absorption (SEIRA) spectroscopy are demonstrated by exploiting large-area templates ($cm^2$) based on self-organized (SO) nanorod antennas. We engineered highly dense arrays of gold…

The paper presents main aspects of the Dipole-Quadrupole theory of Surface Enhanced Infrared Absorption (SEIRA). It is pointed out the possibility of appearance of the lines, caused by totally symmetric vibrations transforming after the…

Optics · Physics 2015-06-04 A. M. Polubotko

Surface-enhanced spectroscopy techniques are the method-of-choice to characterize adsorbed intermediates occurring during electrochemical reactions, which are crucial in realizing a green sustainable future. Characterizing species with low…

Mesoscale and Nanoscale Physics · Physics 2023-07-21 Malo Duportal , Luca M. Berger , Stefan A. Maier , Andreas Tittl , Katharina Krischer

The monolayer form of CVD graphene is imposing crucial challenges in characterization of the targeted covalent functionalization due to the low amount of grafting moieties on the surface, which in turn hampers drawing conclusions about…

Materials Science · Physics 2021-07-20 Irena Matulková , Petr Kovaříček , Miroslav Šlouf , Ivan Němec , Martin Kalbáč

This study examines the Raman scattering and charge transfer properties of molecules adsorbed on the surface of a tetrahedral Au$_{120}$ nanoparticle based on the time-dependent density functional tight-binding (TD-DFTB) method. We study…

Chemical Physics · Physics 2024-09-18 Sajal Kumar Giri , George C. Schatz

The Cu nanowires were electrodeposited in polycarbonate track-etched (PCT) membrane. SEM, TEM and XPS techniques were used to characterize the morphology, structure and size of nanowires as well as chemical Composition. The absorption…

Mesoscale and Nanoscale Physics · Physics 2012-07-17 A. Azariana , F. Babaei

Nitrogen vacancy (NV) centers in diamond have emerged as a leading quantum sensor platform, combining exceptional sensitivity with nanoscale spatial resolution by optically detected magnetic resonance (ODMR). Because fluorescence-based ODMR…

Quantum Physics · Physics 2020-11-24 Laura Kim , Hyeongrak Choi , Matthew Trusheim , Dirk Englund

This study introduces a dual-band plasmonic absorber designed for simultaneous sensing applications in the near-infrared (NIR) and mid-infrared (MIR) regions. The absorber, composed of silver nanostructures on a metal plate with a…

Optics · Physics 2024-11-20 Ayon Sarker , Sajid Muhaimin Choudhury

Transient absorption and Raman scattering measurements on noble metal nanoparticles offer complimentary information on their vibrational modes and mechanical interactions with their surroundings. We have developed a comprehensive modeling…

Mesoscale and Nanoscale Physics · Physics 2024-10-29 Rachel Gelfand , Matthew Pelton

The plasmonic optical absorption of the silica glasses containing copper selenide nanoparticles is simulated on the basis of Drude theory. The plasmonic resonance absorption is studied in dependence on plasmonic frequency, damping factor…

Optics · Physics 2025-06-23 Valerij Gurin
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