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For many real physico-chemical complex systems detailed mechanism includes both reversible and irreversible reactions. Such systems are typical in homogeneous combustion and heterogeneous catalytic oxidation. Most complex enzyme reactions…
We construct the free Lagrangian of the magnetic sector of Carrollian electrodynamics. The construction relies on Helmholtz integrability condition for differential equations in a self consistent algorithm, working hand in hand with…
We introduce the idea of weakly coherent collisional models, where the elements of an environment interacting with a system of interest are prepared in states that are approximately thermal, but have an amount of coherence proportional to a…
We prove the existence of large-data global-in-time weak solutions to an evolutionary PDE system describing flows of incompressible \emph{heat-conducting} viscoelastic rate-type fluids with stress-diffusion, subject to a stick-slip boundary…
The emergence of irreversibility in physical processes, despite the fundamentally reversible nature of quantum mechanics, remains an open question in physics. This thesis explores the intricate relationship between quantum mechanics and…
The equations of Lagrangian, ideal, one-dimensional (1D), compressible gas dynamics are written in a multi-symplectic form using the Lagrangian mass coordinate $m$ and time $t$ as independent variables, and in which the Eulerian position of…
The available enthalpy is an early form of the modern thermodynamic concept of exergy, which is the generic name for the amount of work obtainable when some matter is brought to a state of equilibrium with its surroundings by means of…
For classical discrete systems under constant composition typically refferred to substitutional alloys, we propose calculation method of Helmholtz free energy based on a set of special microscopic states. The advantage of the method is that…
By examining the deterministic limit of a general $\epsilon$-dependent generator for Markovian dynamics, which includes the continuous Fokker-Planck equations and discrete chemical master equations as two special cases, the intrinsic…
We show that the energy of a perturbed system can be fully recovered from the unperturbed system's electron density. We derive an alchemical integral transform by parametrizing space in terms of transmutations, the chain rule and…
It is shown that a heat energy can be transformed in an electric energy of direct current by the use of an inhomogeneous superconducting ring. This trasformation is possible both at an iterative change of temperature and at an unaltered…
Relativistic irreversible thermodynamics is reformulated following the conventional approach proposed by Meixner in the non-relativistic case. Clear separation between mechanical and non-mechanical energy fluxes is made. The resulting…
The equations of motion for electromechanical systems are traced back to the fundamental Lagrangian of particles and electromagnetic fields, via the Darwin Lagrangian. When dissipative forces can be neglected the systems are conservative…
Landauer's principle, often regarded as the foundation of the thermodynamics of information processing, holds that any logically irreversible manipulation of information, such as the erasure of a bit or the merging of two computation paths,…
We derive a bound on generalized currents for Langevin systems in terms of the total entropy production in the system and its environment. For overdamped dynamics, any generalized current is bounded by the total rate of entropy production.…
Landauer's Principle relates entropy decrease and heat dissipation during logically irreversible processes. Most theoretical justifications of Landauer's Principle either use thermodynamic reasoning or rely on specific models based on…
Through an Hamiltonian action we write down the system of equations of motions for a mixture of thermocapillary fluids under the assumption that the internal energy is a function not only of the gradient of the densities but also of the…
According to the Landauer principle, any logically irreversible process accompanies entropy production, which results in heat dissipation in the environment. Erasing of information, one of the primary logically irreversible processes, has a…
On the basis of the balance equations for energy-momentum, spin, particle and entropy density, an approach is considered which represents a comparatively general framework for special- and general-relativistic continuum thermodynamics. In…
Nonequilibrium thermodynamics of a general second-order stochastic system is investigated. We prove that at steady state, under inversion of velocities, the condition of time-reversibility over the phase space is equivalent to the…