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We investigate the ${\rm H_3S}$ phase of sulphur hydride under high pressure $\simeq$ 200 GPa by means of {\it ab-initio} calculations within the framework of the density-functional theory (DFT) with the PBE0 hybrid exchange-correlation…

Superconductivity · Physics 2015-11-30 Matej Komelj , Henry Krakauer

Theory of superconductivity in two-band non-adiabatic systems with strong electron correlations in the linear approximation over non-adiabaticity is built in the article. Having assumed weak electron-phonon interaction analytical…

Superconductivity · Physics 2007-05-23 M. E. Palistrant , V. A. Ursu

The superconducting properties of uniformly hole-doped perovskite hydride KMgH$_3$ with varying doping concentration and lattice parameter corresponding to different pressures were investigated from first principles. The superconducting…

Superconductivity · Physics 2024-11-18 Shaocong Lu , Ryosuke Akashi , Mitsuaki Kawamura , Shinji Tsuneyuki

The rapid variation of the superconductivity Tc in hydride sulfur (H3S) under high pressure [A. Drozdov et al, Nature 525, 73 (2015); M. Einaga et al, arXiv: 1509.03156] in a vicinity Pcr=123GPa is interpreted in terms of the 1st order…

Superconductivity · Physics 2016-01-01 Lev P. Gor'kov , V. Z. Kresin

We present the first fully $ab\;initio$ microscopic description of cubic and tetragonal Nb$_3$Sn. We compute the anharmonic free energy surface, phonon spectra, and solve the full-bandwidth anisotropic Migdal-Eliashberg equations for the…

Superconductivity · Physics 2025-09-11 Alessio Cucciari , Lilia Boeri

The discovery of a superconducting phase in sulfur hydride under high pressure with a critical temperature above 200 K has provided a new impetus to the search for even higher $T_c$. Theory predicted and experiment confirmed that the phase…

We use first-principles calculations to study pressure effects on the vibrational and superconducting properties of H$_3$S in the cubic $Im\bar{3}m$ phase for the pressure range where the superconducting critical temperature (T$_c$) was…

Superconductivity · Physics 2019-11-07 J. A. Camargo-Martínez , G. I. González-Pedreros , R. Baquero

The discovery of high critical temperature T_{c} superconductivity in highly compressed H_{3}S has opened up the question of searching for strong electron-phonon coupling in the hydrides outside the transition metal series. The specific…

Superconductivity · Physics 2019-08-08 P. -H. Chang , S. Silayi , D. A. Papaconstantopoulos , M. J. Mehl

First-principles calculations were carried out to provide a chemical basis for proposed structures associated with the recently reported room-temperature superconductivity in a carbonaceous sulfur hydride material under pressure.…

Superconductivity · Physics 2022-04-28 Xiaoyu Wang , Tiange Bi , Katerina P. Hilleke , Anmol Lamichhane , Russell J. Hemley , Eva Zurek

We investigate three dimensional anharmonic phonons in tetrahedral symmetry and superconductivity mediated by these phonons. Three dimensional anharmonic phonon spectra are calculated directly by solving Schr\"odinger equation and the…

Superconductivity · Physics 2015-05-18 Kazumasa Hattori , Hirokazu Tsunetsugu

Ever since BCS theory was first formulated it was recognized that a large electronic density of states at the Fermi level was beneficial to enhancing $T_c$. The A15 compounds and the high temperature cuprate materials both have had an…

Superconductivity · Physics 2016-12-07 Thiago X. R. Souza , F. Marsiglio

The discovery of high-temperature superconductivity in compressed H3S by Drozdov and co-workers (A. Drozdov, et. al., Nature 525, 73 (2015)) heralded a new era in superconductivity. To date, the record transition temperature of Tc = 260 K…

Superconductivity · Physics 2019-06-05 E. F. Talantsev

We use first principles calculations to study structural, vibrational and superconducting properties of H$_2$S at pressures $P\ge 200$ GPa. The inclusion of zero point energy leads to two different possible dissociations of H$_2$S, namely…

The inclusion of nonadiabatic corrections to the electron-phonon interaction leads to a strong momentum dependence in the generalized Eliashberg equations beyond Migdal's limit. For a s-wave symmetry of the order parameter, this induced…

Superconductivity · Physics 2009-10-31 P. Paci , C. Grimaldi , L. Pietronero

The classical Bardeen-Cooper-Schrieffer and Eliashberg theories of the electron-phonon-mediated superconductivity are based on the Migdal theorem, which is an assumption that the energy of charge carriers, $k{_B}T{_F}$, significantly…

Superconductivity · Physics 2022-12-26 E. F. Talantsev

We report on a comparative study of the electronic structure, phonon spectra, and superconducting properties for recently discovered superconducting hydrides, H3S and H3P. While the electronic structures of these two materials are similar,…

Superconductivity · Physics 2016-07-05 Hyungju Oh , Sinisa Coh , Marvin L. Cohen

The adiabatic Born-Oppenheimer approximation is considered to be a robust approach that very rarely breaks down. Consequently, it is predominantly utilized to address various electron-phonon properties in condensed matter physics. By…

Superconductivity · Physics 2023-03-01 Nina Girotto , Dino Novko

Electrons on Kagome lattice exhibit a wealth of features including Dirac points, van Hove singularities and flatbands. When the Fermi level is placed at the van Hove saddle point, the Fermi surface is perfectly nested and a rich variety of…

Superconductivity · Physics 2025-04-17 Yuan Tian , Sergey Y. Savrasov

Hydrogen-rich compounds are extensively explored as candidates for a high-temperature superconductors. Currently, the measured critical temperature of $203$ K in hydrogen sulfide (H$_3$S) is among the highest over all-known superconductors.…

Superconductivity · Physics 2016-05-05 A. P. Durajski , R. Szczesniak , L. Pietronero

Strong nonlinear elastic effects arise due to the Lifshitz transition associated with a change in the Fermi surface topology. It is shown that an electronic contribution to the elastic characteristics of cuprates becomes important if the…

Condensed Matter · Physics 2007-05-23 V. Rzhevskii , G. Roepke