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With controlled ionic current rectification (ICR) achieved through a strategically designed non-uniform surface charge distribution, short unipolar nanopores exhibit promising applications in nanofluidic sensors, ionic circuits, and ion…

Chemical Physics · Physics 2025-12-08 Hongwen Zhang , Long Ma , Di Liu , Tianyi Sui , Zuzanna S. Siwy , Yinghua Qiu

Bipolar nanopores, with asymmetric charge distributions, can induce significant ionic current rectification (ICR) at ultra-short lengths, finding potential applications in nanofluidic devices, energy conversion, and other related fields.…

Chemical Physics · Physics 2024-10-29 Hongwen Zhang , Long Ma , Chao Zhang , Yinghua Qiu

Single nanopores have attracted much scientific interest due to their versatile applications. The majority of experiments have been performed with nanopores being in contact with the same electrolyte on both sides of the membrane, while…

Chemical Physics · Physics 2018-12-11 Yinghua Qiu , Zuzanna S. Siwy , Meni Wanunu

Nanopores that exhibit ionic current rectification (ICR) behave like diodes, such that they transport ions more efficiently in one direction than the other. Conical nanopores have been shown to rectify ionic current, but only those with at…

Chemical Physics · Physics 2022-06-08 Long Ma , Zhongwu Li , Zhishan Yuan , Chuanzhen Huang , Zuzanna S. Siwy , Yinghua Qiu

Ionic current rectification (ICR) of charged conical nanopores has various applications in fields including nanofluidics, bio-sensing, and energy conversion, whose function is closely related to the dynamic response of nanopores. The…

Chemical Physics · Physics 2024-10-29 Zhe Liu , Long Ma , Hongwen Zhang , Jiakun Zhuang , Jia Man , Zuzanna S. Siwy , Yinghua Qiu

Recent experimental work has suggested that electroosmotic flows (EOF) through conical nanopores exhibit rectification in the opposite sense to the well-studied effect of ionic current rectification. A positive bias voltage generates large…

Fluid Dynamics · Physics 2015-06-02 Nadanai Laohakunakorn , Ulrich F. Keyser

Fluidic devices exhibiting ion current rectification (ICR), or ionic diodes, are of broad interest for applications including desalination, energy harvesting, and sensing, amongst others. For such applications a large conductance is…

Soft Condensed Matter · Physics 2022-10-11 Mark Aarts , Willem Boon , Blaise Cuénod , M. Dijkstra , René van Roij , Esther Alarcon-Llado

Ionic Current Rectification (ICR) can appear in nanopores, causing a diode-like behavior that originates from different efficiency of ion transport through the pore channel with respect to the applied voltage bias polarity. This effect is…

Continuum simulations become an important tool to uncover the mysteries in nanofluidic experiments. However, fluid flow in simulation models is usually unconsidered. Here, systematical simulations are conducted to provide a quantitative…

Chemical Physics · Physics 2024-02-08 Yinghua Qiu , Long Ma

Recent experiments with electrolytes driven through conical nanopores give evidence of strong rectified current response. In such devices, the asymmetry in the confinement is responsible of the non-Ohmic response, suggesting that the…

Mesoscale and Nanoscale Physics · Physics 2019-09-04 Sara Dal Cengio , Ignacio Pagonabarraga

In charged nanopores, ionic diffusion current reflects the ionic selectivity and ionic permeability of nanopores which determines the performance of osmotic energy conversion, i.e. the output power and efficiency. Here, theoretical…

Chemical Physics · Physics 2023-09-15 Long Ma , Zihao Gao , Jia Man , Jianyong Li , Guanghua Du , Yinghua Qiu

We have investigated ion current rectification properties of a recently prepared bipolar nanofluidic diode. This device is based on a single conically shaped nanopore in a polymer film whose pore walls contain a sharp boundary between…

Other Condensed Matter · Physics 2009-11-13 D. Constantin , Z. S. Siwy

Electroosmotic flow (EOF) through nanoporous membranes has broad applications in micro- and nanofluidic systems, particularly in biomedical diagnostics and chemical analysis. The use of short nanopores enables high fluid flux, and the…

Chemical Physics · Physics 2025-12-08 Chao Zhang , Xiaomei Zhang , Hongwen Zhang , Zekun Gong , Xiuhua Ren , Mengnan Guo , Yinghua Qiu

Nanopores in solid state membranes are a tool able to probe nanofluidic phenomena or can act as a single molecular sensor. They also have diverse applications in filtration, desalination or osmotic power generation. Many of these…

Soft Condensed Matter · Physics 2020-12-02 Sebastian J. Davis , Michal Macha , Andrey Chernev , David M. Huang , Aleksandra Radenovic , Sanjin Marion

The microchannel corner is a common inherent component of most planar microfluidic systems and thus its influence on the channel flow is of significant interest. Application of an alternating current electric field enables quantification of…

Fluid Dynamics · Physics 2014-12-08 Matan Zehavi , Alicia Boymelgreen , Gilad Yossifon

The venerable theory of electrokinetic phenomena rests on the hypothesis of a dilute solution of point-like ions near a weakly charged surface, whose potential relative to the bulk is of order the thermal voltage ($kT/e \approx 25$ mV at…

Fluid Dynamics · Physics 2009-09-29 Martin Z. Bazant , Mustafa Sabri Kilic , Brian D. Storey , Armand Ajdari

This theoretical study investigates the nonlinear ionic current-voltage characteristics of nano-channels that have weakly overlapping electrical double layers. Numerical simulations as well as a 1-D mathematical model are developed to…

Chemical Physics · Physics 2017-01-10 Yang Liu , Lingzi Guo , Xin Zhu , Qiushi Ran , Robert Dutton

Short nanopores have various applications in biosensing, desalination, and energy conversion. Here, the modulation of charged exterior surfaces on ionic transport is investigated through simulations with sub-200 nm long nanopores under…

Soft Condensed Matter · Physics 2024-02-08 Long Ma , Zhe Liu , Jia Man , Jianyong Li , Zuzanna S. Siwy , Yinghua Qiu

Nanopore membranes are a versatile platform for a wide range of applications ranging from medical sensing to filtration and clean energy generation. To attain high-flux rectifying ionic flow, it is required to produce short channels…

Mesoscale and Nanoscale Physics · Physics 2023-05-12 Alexander Kiy , Shankar Dutt , Christian Notthoff , Maria E. Toimil-Molares , Nigel Kirby , Patrick Kluth

High-performance osmotic energy conversion requires both large ionic throughput and high ionic selectivity, which can be significantly promoted by exterior surface charges simultaneously, especially for short nanopores. Here, we investigate…

Chemical Physics · Physics 2022-06-08 Long Ma , Xuan An , Fenhong Song , Yinghua Qiu
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