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Related papers: Resolving the Structural Duality of Graphene Grain…

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Topological defects in graphene, dislocations and grain boundaries, are still not well understood despites the considerable number of experimental observations. We introduce a general approach for constructing dislocations in graphene…

Mesoscale and Nanoscale Physics · Physics 2010-05-21 Oleg V. Yazyev , Steven G. Louie

The effect of grain boundaries and wrinkles on the electrical properties of polycrystalline graphene is pronounced. Here we investigate the stitching between grains of polycrystalline graphene, specifically, overlapping of layers at the…

Materials Science · Physics 2014-06-09 Rahul Rao , Neal Pierce , Avetik R. Harutyunyan

Grain boundaries (GBs) can critically influence the microstructural evolution and various materials properties. However, a fundamental understanding of GBs in high-entropy alloys (HEAs) is lacking because of the complex couplings of the…

Materials Science · Physics 2021-04-13 Chongze Hu , Jian Luo

Grain boundaries (GBs) often control the processing and properties of polycrystalline materials. Here, a potentially transformative research is represented by constructing GB property diagrams as functions of temperature and bulk…

Materials Science · Physics 2020-02-26 Chongze Hu , Yunxing Zuo , Chi Chen , Shyue Ping Ong , Jian Luo

In this work we have investigated the mechanical properties and fracture patterns of some graphene nanowiggles (GNWs). Graphene nanoribbons are finite graphene segments with a large aspect ratio, while GNWs are nonaligned periodic…

Mesoscale and Nanoscale Physics · Physics 2019-06-05 R. A. Bizao , T. Botari , D. S. Galvao

The grain boundary (GB) energy is a quantity of fundamental importance for understanding several key properties of graphene. Here we present a comprehensive theoretical and numerical study of the entire space of symmetric and asymmetric…

Materials Science · Physics 2016-11-22 Ashivni Shekhawat , Colin Ophus , Robert O. Ritchie

Microscopic models of the interaction between grain boundaries (GBs) and both dislocations and cracks are of importance in understanding the role of microstructure in altering the mechanical properties of a material. A recently developed…

Materials Science · Physics 2009-10-30 V. B. Shenoy , R. Miller , E. B. Tadmor , R. Phillips , M. Ortiz

The electronic properties of graphene nano-flakes (GNFs) with different edge passivation is investigated by using density functional theory. Passivation with F and H atoms are considered: C$_{N_c}$ X$_{N_x}$ (X=F or H). We studied GNFs with…

Materials Science · Physics 2014-03-05 Sandeep Kumar Singh , M. Neek-Amal , F. M. Peeters

The physical processes occurring in the presence of disorder: point defects, grain boundaries, etc. may have detrimental effects on the electronic properties of graphene. Here we present an approach to reveal the grain structure of graphene…

With the help of the recently developed SIESTA-PEXSI method [J. Phys.: Condens. Matter \textbf{26}, 305503 (2014)], we perform Kohn-Sham density functional theory (DFT) calculations to study the stability and electronic structure of…

Materials Science · Physics 2014-12-03 Wei Hu , Lin Lin , Chao Yang , Jinlong Yang

Grain boundaries (GBs) are ubiquitous in polycrystalline graphene materials obtained by various growth methods. It has been shown previously that considerable electrical transport gap can be opened by grain boundaries. On the other hand,…

Mesoscale and Nanoscale Physics · Physics 2012-08-31 S. Bala Kumar , Jing Guo

The correlation between structural distortion and emergence of magnetism in graphene containing a single vacancy was investigated using first-principles calculations based on density functional theory (DFT). Our results have shown that a…

Mesoscale and Nanoscale Physics · Physics 2015-06-12 Wendel S. Paz , Wanderlã L. Scopel , Jair C. C. Freitas

Chemical vapor deposition (CVD) on Cu foil is one of the most promising methods to produce graphene samples despite of introducing numerous grain boundaries into the perfect graphene lattice. A rich variety of GB structures can be realized…

Mesoscale and Nanoscale Physics · Physics 2013-10-28 Péter Vancsó , Géza I. Márk , Philippe Lambin , Alexandre Mayer , Chanyong Hwang , László P. Biró

Grain boundaries in epitaxial graphene on the SiC(000$\bar{1}$) substrate are studied using scanning tunneling microscopy and spectroscopy. All investigated small-angle grain boundaries show pronounced out-of-plane buckling induced by the…

Grain-boundary (GB) dynamics control the stability, mechanical, and functional response of nanocrystalline materials, but direct experimental access to their slow non-equilibrium motion has been limited. Here we establish X-ray photon…

The strong interest in graphene has motivated the scalable production of high quality graphene and graphene devices. Since large-scale graphene films synthesized to date are typically polycrystalline, it is important to characterize and…

A central question in the field of graphene-related research is how graphene behaves when it is patterned at the nanometer scale with different edge geometries. Perhaps the most fundamental shape relevant to this question is the graphene…

The mechanical, electrical and chemical properties of chemically modified graphene (CMG) are intrinsically linked to its structure. Here we report on our study of the topographic structure of free-standing CMG using atomic force microscopy…

Mesoscale and Nanoscale Physics · Physics 2011-04-12 N R Wilson , P A Pandey , R Beanland , J P Rourke , U Lupo , G Rowlands , R A Römer

Graphite occurs in a range of metastable stacking orders characterized by both the number and direction of shifts between adjacent layers by the length of a single carbon-carbon bond. At the extremes are Bernal (or ``ABAB...'') stacking,…

Graphene has attracted significant interest both for exploring fundamental science and for a wide range of technological applications. Chemical vapor deposition (CVD) is currently the only working approach to grow graphene at wafer scale,…