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The Bragg-Williams free energy is used to incorporate nearest-neighbor interactions into the lattice gas model of a solvent-free ionic liquid near a planar electrode. We calculate the differential capacitance from solutions of the…

Chemical Physics · Physics 2018-12-04 Rachel Downing , Bjorn K. Berntson , Guilherme V. Bossa , Sylvio May

Wave-particle duality and the superposition of quantum mechanical states furnish quantum mechanics with unique features which distinguishes it from classical mechanics and give it the apparently counter-intuition interpretation. The two…

Quantum Physics · Physics 2020-06-15 Abanoub Mikhail

Electrical conductance through various nanocontacts between gold electrodes is studied by using the density functional theory, scalar-relativistic pseudopotentials, generalized gradient approximation for the exchange-correlation energy and…

Materials Science · Physics 2009-11-13 O. Lopez-Acevedo , D. Koudela , H. Häkkinen

It has been shown that the presence of a metal plate near a double quantum well with spatially separated electron and hole layers may lead to a drastic reconstruction of the system state with the formation of stable charged complexes of…

Condensed Matter · Physics 2009-10-28 V. I. Yudson

We calculate the thermal conductivity of interacting electrons in disordered metals. In our analysis we point out that the interaction affects thermal transport through two distinct mechanims, associated with quantum interference…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Roberto Raimondi , Giorgio Savona , Peter Schwab , Thomas Lueck

Quantum criticality is the intriguing possibility offered by the laws of quantum mechanics when the wave function of a many-particle physical system is forced to evolve continuously between two distinct, competing ground states. This…

Mesoscale and Nanoscale Physics · Physics 2008-09-18 Nicolas Roch , Serge Florens , Vincent Bouchiat , Wolfgang Wernsdorfer , Franck Balestro

We study quantum interference effects due to electron motion on a three-dimensional cubic lattice in a continuously-tunable magnetic field of arbitrary orientation and magnitude. These effects arise from the interference between magnetic…

Mesoscale and Nanoscale Physics · Physics 2009-10-28 Yeong-Lieh Lin , Franco Nori

Quantum proton tunneling (QPT) in the two representative multi-electron/-proton transfer electrode processes, i.e. hydrogen evolution reaction (HER) and oxygen reduction reaction (ORR), was investigated by using polycrystalline platinum…

Chemical Physics · Physics 2019-07-02 Ken Sakaushi

Reliable first-principles calculations of electrochemical processes require accurate prediction of the interfacial capacitance, a challenge for current computationally-efficient continuum solvation methodologies. We develop a model for the…

Chemical Physics · Physics 2018-04-12 Ravishankar Sundararaman , Kendra Letchworth-Weaver , Kathleen Schwarz

We study theoretically the quantum optical properties of hybrid molecules composed of an individual quantum dot and a metallic nanoparticle. We calculate the resonance fluorescence of this hybrid system. Its incoherent part, the one arising…

Quantum Physics · Physics 2010-04-12 A. Ridolfo , O. Di Stefano , N. Fina , R. Saija , S. Savasta

Electrode surface roughness significantly impacts the structure of electric double layer on a molecular scale. We derive analytical solutions for differential capacitance (DC) of electric double layer near rough electrode surface, comparing…

Chemical Physics · Physics 2023-03-07 Aleksey Khlyupin , Irina Nesterova , Kirill Gerke

The quantum tunneling effects between two metallic plates are studied using the time dependent density functional theory. Results show that the tunneling is mainly dependent on the separation and the initial local field of the interstice…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Li Mao , Zhipeng Li , Biao Wu , Hongxing Xu

Quantum dots (QDs), embedded in supercapacitors (S-C) cells exhibited capacitance amplification that peaked at certain QD concentration. More than 2.5 peak amplification was demonstrated with cyclic voltammetry (C-V) at a scan rate of 0.1…

Chemical Physics · Physics 2025-08-25 H. Grebel

We calculate the charge susceptibility and the linear and differential conductances of a double quantum dot coupled to two metallic reservoirs both at equilibrium and when the system is driven away from equilibrium. This work is motivated…

Mesoscale and Nanoscale Physics · Physics 2018-10-16 V. Talbo , M. Lavagna , T. Q. Duong , A. Crépieux

Electron tunneling experiments are used to probe Coulomb correlation effects in the single-particle density-of-states (DOS) of boron-doped silicon crystals near the critical density of the metal-insulator transition (MIT). At low energies,…

Disordered Systems and Neural Networks · Physics 2014-11-20 Mark Lee , J. G. Massey , V. L. Nguyen , B. I. Shklovskii

We theoretically study electron interference in a ballistic electronic interferometer capacitively coupled to a quantum dot. The visibility of the interference is reduced when the dot has degenerate ground states with different excess…

Mesoscale and Nanoscale Physics · Physics 2009-10-30 Seok-Chan Youn , Hyun-Woo Lee , H. -S. Sim

The puzzling behavior of the transition phase through a quantum dot can be understood in a natural way via a formation of the electron molecule in the quantum dot. In this case the resonance tunneling takes place through the…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 S. A. Gurvitz

The thermoelectric voltage developed across an atomic metal junction (i.e., a nanostructure in which one or a few atoms connect two metal electrodes) in response to a temperature difference between the electrodes, results from the quantum…

The quantum interference effect on the quasiparticle density of states (DOS) is studied with the diagrammatic technique in two-dimensional d-wave superconductors with dilute nonmagnetic impurities both near the Born and near the unitary…

Superconductivity · Physics 2007-05-23 Y. H. Yang , Y. G. Wang , M. Liu , D. Y. Xing

We investigate two equivalent, capacitively coupled semiconducting quantum dots, each coupled to its own lead, in a regime where there are two electrons on the double dot. With increasing interdot coupling a rich range of behavior is…

Strongly Correlated Electrons · Physics 2007-05-23 Martin R. Galpin , David E. Logan , H. R. Krishnamurthy