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In this paper, we introduce a new scheme for the efficient numerical treatment of the electronic Schr\"odinger equation for molecules. It is based on the combination of a many-body expansion, which corresponds to the so-called bond order…

Numerical Analysis · Mathematics 2017-07-20 Sambasiva Rao Chinnamsetty , Michael Griebel , Jan Hamaekers

Efficient mixed-precision matrix multiply accumulate (MMA) operations are critical for accelerating deep learning workloads on GPGPUs. However, existing open-source dot product implementations for Tensor Cores rely on discrete arithmetic…

Hardware Architecture · Computer Science 2026-04-07 Nikhil Rout , Blaise Tine

Accurate vibrational spectra are essential for understanding how molecules behave, yet their computation remains challenging and benchmark data to reliably compare different methods are sparse. Here, we present high-accuracy eigenstate…

Chemical Physics · Physics 2025-04-16 Henrik R. Larsson

We present two new methods for performing ab initio calculations of excited states for closed-shell systems within the in-medium similarity renormalization group (IMSRG) framework. Both are based on combining the IMSRG with simple many-body…

Nuclear Theory · Physics 2017-05-10 N. M. Parzuchowski , T. D. Morris , S. K. Bogner

Transition metal complexes present significant challenges for electronic structure theory due to strong electron correlation arising from partially filled $d$-orbitals. We compare our recently developed Tensor Product Selected Configuration…

Chemical Physics · Physics 2025-08-19 Arnab Bachhar , Nicholas J. Mayhall

The density matrix renormalization group (DMRG) algorithm is a cornerstone computational method for studying quantum many-body systems, renowned for its accuracy and adaptability. Despite DMRG's broad applicability across fields such as…

Computational Physics · Physics 2026-03-24 Per Sehlstedt , Jan Brandejs , Paolo Bientinesi , Lars Karlsson

We discuss the development of an angular-momentum-conserving variant of the Density Matrix Renormalization Group (DMRG) method for use in large-scale shell-model calculations of atomic nuclei and report a first application of the method to…

Nuclear Theory · Physics 2009-02-09 B. Thakur , S. Pittel , N. Sandulescu

Tensor network methods, particularly those based on Matrix Product States (MPS), provide a powerful framework for simulating quantum many-body systems. A persistent computational challenge in these methods is the selection of the bond…

Emerging Technologies · Computer Science 2026-04-07 Harshni Kumaresan , Gayathri Muruganantham , Lakshmi Rajendran , Santhosh Sivasubramani

The numerical renormalization group (NRG) has been widely used as a magnetic impurity solver since the pioneering works by Wilson. Over the past decades, a significant attention has been focused on the application of symmetries in order to…

Strongly Correlated Electrons · Physics 2024-10-17 Aitor Calvo-Fernández , María Blanco-Rey , Asier Eiguren

Within the framework of many-body perturbation theory based on Green's functions, the $GW$ approximation has emerged as a pivotal method for computing quasiparticle energies and excitation spectra. However, its high computational cost and…

Chemical Physics · Physics 2025-12-25 Yueyang Zhang , Wei Wu , Peifeng Su

Understanding the intricate properties of one-dimensional quantum systems coupled to multiple reservoirs poses a challenge to both analytical approaches and simulation techniques. Fortunately, density matrix renormalization group-based…

Quantum Physics · Physics 2021-07-15 Heitor P. Casagrande , Dario Poletti , Gabriel T. Landi

Tensor network techniques are becoming increasingly popular tools to solve partial differential equations within the so-called quantics representation. Their popularity stems from the fact that their spatial resolution depends only…

Quantum Physics · Physics 2026-04-13 Jheng-Wei Li , Nicolas Jolly , Xavier Waintal

Dukelsky, Mart\'in-Delgado, Nishino and Sierra (Europhys. Lett., 43, 457 (1998) - hereafter referred to as DMNS) investigated the matrix product method (MPM), comparing it with the infinite-size density matrix renormalization group (DMRG).…

Strongly Correlated Electrons · Physics 2009-11-07 I. P. McCulloch , M. Gulacsi

Determining the exponentially scaled ground state wavefunction and the associated molecular properties remains one of the central challenges in quantum chemistry. Hybrid quantum-classical algorithms implemented on quantum computers offer a…

Quantum Physics · Physics 2026-04-22 Dibyendu Mondal , Ashish Kumar Patra , Rahul Maitra

We generalize the interpolative separable density fitting (ISDF) method, used for compressing the four-index electron repulsion integral (ERI) tensor, to incorporate adaptive real space grids for potentially highly localized single-particle…

Computational Physics · Physics 2026-02-17 Hai Zhu , Chia-Nan Yeh , Miguel A. Morales , Leslie Greengard , Shidong Jiang , Jason Kaye

We compare convergence of isogeometric analysis (IGA), a spline modification of finite element method (FEM), with FEM in the context of our real space code for ab-initio electronic structure calculations of non-periodic systems. The…

Computational Physics · Physics 2021-01-07 Robert Cimrman , Matyáš Novák , Radek Kolman , Miroslav Tůma , Jiří Vackář

The GMRES method is used to solve sparse, non-symmetric systems of linear equations arising from many scientific applications. The solver performance within a single node is memory bound, due to the low arithmetic intensity of its…

Numerical Analysis · Mathematics 2020-11-04 Neil Lindquist , Piotr Luszczek , Jack Dongarra

FPGA is appropriate for fix-point neural networks computing due to high power efficiency and configurability. However, its design must be intensively refined to achieve high performance using limited hardware resources. We present an…

Hardware Architecture · Computer Science 2022-01-03 Qingyang Yi , Heming Sun , Masahiro Fujita

We present an efficient stochastic algorithm for the recently introduced perturbative density matrix renormalization group (p-DMRG) method for large active spaces. The stochastic implementation bypasses the computational bottleneck involved…

Chemical Physics · Physics 2018-08-01 Sheng Guo , Zhendong Li , Garnet Kin-Lic Chan

Variational approaches for the calculation of vibrational wave functions and energies are a natural route to obtain highly accurate results with controllable errors. However, the unfavorable scaling and the resulting high computational cost…

Chemical Physics · Physics 2017-08-14 Alberto Baiardi , Christopher J. Stein , Vincenzo Barone , Markus Reiher