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Master equation could be applied to model various kinds of biochemical systems. A general theory for its time-dependent nonequilibrium thermodynamics is rigorously derived. We not only introduce a concept of general internal energy, but…

Statistical Mechanics · Physics 2009-04-16 Hao Ge

A nonequilibrium distribution function of microscopic thermal current is studied by a direct numerical simulation in a thermal conducting steady state of particle systems. Two characteristic temperatures of the thermal current are…

Statistical Mechanics · Physics 2009-04-01 Satoshi Yukawa , Takashi Shimada , Fumiko Ogushi , Nobuyasu Ito

Relevant and fundamental concepts of the statistical mechanical theory of classical liquids are ordinarily introduced in the context of the description of thermodynamic equilibrium states. This makes explicit reference to probability…

Statistical Mechanics · Physics 2024-01-30 O. Joaquín-Jaime , R. Peredo-Ortiz , M. Medina-Noyola , L. F. Elizondo-Aguilera

Macroscopic thermodynamics of equilibrium is constructed for systems obeying power-law canonical distributions. With this, the connection between macroscopic thermodynamics and microscopic statistical thermodynamics is generalized. This is…

Statistical Mechanics · Physics 2009-10-31 Sumiyoshi Abe , A. K. Rajagopal

We compare two approaches to nonequilibrium thermodynamics, the two-generator bracket formulation of time-evolution equations for averages and the macroscopic fluctuation theory, for an isothermal driven diffusive system under steady state…

Statistical Mechanics · Physics 2010-11-10 Hans Christian Ottinger

The reasons which restrict opportunities of classical mechanics at the description of nonequilibrium systems are discussed. The way of overcoming of the key restrictions is offered. This way is based on an opportunity of representation of…

General Physics · Physics 2012-05-14 V. M. Somsikov

How can we derive the evolution equations of dissipative systems? What is the relation between the different approaches? How much do we understand the fundamental aspects of a second law based framework? Is there a hierarchy of dissipative…

Statistical Mechanics · Physics 2021-03-17 P. Ván

Stochastic Thermodynamics (ST) extends the notions of classical thermodynamics to trajectories taken from a nonequilibrium ensemble. This extension yields a simple approach to fluctuation relations in small systems. Multiple time- and…

Statistical Mechanics · Physics 2012-10-19 Bernhard Altaner

To describe the nonequilibrium states of a system we introduce a new thermodynamic parameter - the lifetime of a system. The statistical distributions which can be obtained out of the mesoscopic description characterizing the behaviour of a…

Statistical Mechanics · Physics 2007-05-23 V. V. Ryazanov , S. G. Shpyrko

Classical thermodynamics describes physical systems in thermodynamic equilibrium, characterized in particular by the absence of macroscopic motion. Global non-equilibrium thermodynamics extends this framework to include physical systems in…

Interface equations are derived for both binary diffusive and binary fluid systems subjected to non-equilibrium conditions, starting from the coarse-grained (mesoscopic) models. The equations are used to describe thermo-capillary motion of…

Soft Condensed Matter · Physics 2015-06-25 Ravi Bhagavatula , David Jasnow , Takao Ohta

Nonequilibrium thermodynamics has shown its applicability in a wide variety of different situations pertaining to fields such as physics, chemistry, biology, and engineering. As successful as it is, however, its current formulation…

Condensed Matter · Physics 2009-11-07 J. M. G. Vilar , J. M. Rubi

Classical thermodynamics is built with the concept of equilibrium states. However, it is less clear how equilibrium thermodynamics emerges through the dynamics that follows the principle of quantum mechanics. In this paper, we develop a…

Quantum Physics · Physics 2018-12-18 Md. Manirul Ali , Wei-Ming Huang , Wei-Min Zhang

We address the problem of the dynamical foundation of non-canonical equilibrium. We consider, as a source of divergence from ordinary statistical mechanics, the breakdown of the condition of time scale separation between microscopic and…

Statistical Mechanics · Physics 2009-10-31 M. Annunziato , P. Grigolini , B. J. West

Previous work developed a space-time metric with two cosmological scales; one that conveniently describes the classical evolution of the dynamics, and the other describing a scale associated with macroscopic quantum aspects like vacuum…

General Relativity and Quantum Cosmology · Physics 2007-05-23 James Lindesay

This short paper presents a nontechnical introduction to the problem of nonequivalent microcanonical and canonical ensembles. Both the thermodynamic and the macrostate levels of definition of nonequivalent ensembles are introduced. The many…

Statistical Mechanics · Physics 2007-05-23 H. Touchette , R. S. Ellis , B. Turkington

A key feature of non-equilibrium thermodynamics is the Markovian, deterministic relaxation of coarse observables such as, for example, the temperature difference between two macroscopic objects which evolves independently of almost all…

Quantum Physics · Physics 2014-04-08 Hendrik Niemeyer , Kristel Michielsen , Hans de Raedt , Jochen Gemmer

Focusing on isolated macroscopic systems, described either in terms of a quantum mechanical or a classical model, our two key questions are: In how far does an initial ensemble (usually far from equilibrium and largely unknown in detail)…

Statistical Mechanics · Physics 2013-11-13 Peter Reimann , Mykhaylo Evstigneev

We investigate the thermodynamics of integrable classical field theories under the effect of a random initial configuration, motivated by the nonequilibrium evolution of quantum field theories. The approach to thermal equilibrium is…

Statistical Mechanics · Physics 2016-10-05 P. E. G. Assis

Open quantum systems are studied from the thermodynamical point of view unifying the principle of maximum informational entropy and the hypothesis of relaxation times hierarchy. The result of the unification is a non-Markovian and local in…

Quantum Physics · Physics 2014-11-24 Vitalii Semin , Francesco Petruccione