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We investigate the capacity of a flat partially reactive patch of arbitrary shape to trap independent particles that undergo steady-state diffusion in the three-dimensional space. We focus on the total flux of particles onto the patch that…

Chemical Physics · Physics 2026-02-02 Denis S. Grebenkov , Raphael Maurette

Finding accurate approximations for the effective reactivity of a structured spherical target with a circular absorbing patch of arbitrary size is a long-standing problem in chemical physics. In this Communication, we reveal limitations of…

Chemical Physics · Physics 2025-07-16 Denis S. Grebenkov

We consider the kinetics of the imperfect narrow escape problem, i.e. the time it takes for a particle diffusing in a confined medium of generic shape to reach and to be adsorbed by a small, imperfectly reactive patch embedded in the…

Statistical Mechanics · Physics 2023-05-11 T. Guérin , M. Dolgushev , O. Bénichou , R. Voituriez

A wide variety of physical, chemical, and biological processes involve diffusive particles interacting with surfaces containing reactive patches. The theory of boundary homogenization seeks to encapsulate the effective reactivity of such a…

Statistical Mechanics · Physics 2024-05-21 Claire E Plunkett , Sean D Lawley

In this paper we analyze the narrow capture problem for a single Brownian particle diffusing in a three-dimensional (3D) bounded domain containing a set of small, spherical traps. The boundary surface of each trap is taken to be a…

Statistical Mechanics · Physics 2022-11-23 Paul C Bressloff

A general topic of current interest is the analysis of diffusion problems in singularly perturbed domains with small interior targets or traps (the narrow capture problem). One major application is to intracellular diffusion, where the…

Statistical Mechanics · Physics 2022-04-13 Paul C. Bressloff

A popular approach to modeling bimolecular reactions between diffusing molecules is through the use of reactive boundary conditions. One common model is the Smoluchowski partial absorption condition, which uses a Robin boundary condition in…

Biological Physics · Physics 2015-11-17 S. Jonathan Chapman , Radek Erban , Samuel A. Isaacson

This chapter aims at emphasizing the crucial role of partial reactivity of a catalytic surface or a target molecule in diffusion-controlled reactions. We discuss various microscopic mechanisms that lead to imperfect reactions, the Robin…

Chemical Physics · Physics 2019-11-05 Denis S. Grebenkov

We consider steady-state diffusion in a three-dimensional bounded domain with a smooth reflecting boundary that is partially covered by small partially reactive patches. By using the method of matched asymptotic expansions, we investigate…

Analysis of PDEs · Mathematics 2025-10-01 Denis S. Grebenkov , Michael J. Ward

Consider a finite system of diffusing particles coupled through a reactive boundary. Each particle is reflected, but may react with the boundary according to a killing mechanism which depends on the current reactivity of the boundary and…

Probability · Mathematics 2026-05-20 Eliana Fausti , Andreas Sojmark

An active Brownian particle is a minimal model for a self-propelled colloid in a dissipative environment. Experiments and simulations show that, in the presence of boundaries and obstacles, active Brownian particle systems approach…

Soft Condensed Matter · Physics 2024-01-17 Caleb G. Wagner , Michael F. Hagan , Aparna Baskaran

We study the one-dimensional motion of a Brownian particle inside a confinement described by two reactive boundaries which can partially reflect or absorb the particle. Understanding the effects of such boundaries is important in physics,…

Statistical Mechanics · Physics 2021-03-30 Arnab Pal , Isaac Pérez Castillo , Anupam Kundu

Encounter-based models of diffusion provide a probabilistic framework for analyzing the effects of a partially absorbing reactive surface, in which the probability of absorption depends upon the amount of surface-particle contact time.…

Statistical Mechanics · Physics 2023-07-05 Paul C Bressloff

We derive the asymptotic behavior of hitting probability at small target of size $O(\epsilon)$ for reflected Brownian motion in domains with suitable smooth boundary conditions, where the boundary of domain contains both reflecting part,…

Probability · Mathematics 2024-10-29 Yuchen Fan

We introduce two probabilistic models for $N$ interacting Brownian motions moving in a trap in $\mathbb {R}^d$ under mutually repellent forces. The two models are defined in terms of transformed path measures on finite time intervals under…

Probability · Mathematics 2016-08-16 Stefan Adams , Jean-Bernard Bru , Wolfgang König

We present a novel simulation technique derived from Brownian cluster dynamics used so far to study the isotropic colloidal aggregation. It now implements the classical Kern-Frenkel potential to describe patchy interactions between…

Soft Condensed Matter · Physics 2015-06-19 Achutha Prabhu , Sujin B. Babu , Jorge S. Dolado , J. -C. Gimel

Active Brownian particles (ABPs) are termed out to be a successful way of modeling the moving microorganism on the substrate. In recent studies, it is shown that such organisms can sense the characteristics of the substrate. Motivated by…

Soft Condensed Matter · Physics 2023-10-31 Pawan Kumar Mishra , Ajeya Krishna , Shradha Mishra

To realise the goals of active matter at the micro- and nano-scale, the next generation of microrobots must be capable of autonomously sensing and responding to their environment to carry out pre-programmed tasks. Memory effects are…

Soft Condensed Matter · Physics 2024-04-03 Maximilian Bailey , Fabio Grillo , Lucio Isa

We study analytically how noninteracting weakly active particles, for which passive Brownian diffusion cannot be neglected and activity can be treated perturbatively, distribute and behave near boundaries in various geometries. In…

Soft Condensed Matter · Physics 2021-05-05 Michael Wang

We present an efficient method to solve the narrow capture and narrow escape problems for the sphere. The narrow capture problem models the equilibrium behavior of a Brownian particle in the exterior of a sphere whose surface is reflective,…

Numerical Analysis · Mathematics 2021-08-03 Jason Kaye , Leslie Greengard
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