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A new approach to calculate the vibrational distribution function of molecules in a medium providing energy for vibrational excitation is proposed and demonstrated. The approach is an improvement of solution methods based on the…

Chemical Physics · Physics 2018-09-11 Paola Diomede , Mauritius C. M. van de Sanden , Savino Longo

Vibrational spectroscopy is a key technique to elucidate microscopic structure and dynamics. Without the aid of theoretical approaches, it is however, often difficult to understand such spectra at a microscopic level. Ab initio molecular…

Chemical Physics · Physics 2023-03-14 Philipp Schienbein

We propose a Fokker-Planck equation (FPE) theory to describe stochastic fluctuation and relaxation processes of lattice vibration at a wide range of conditions, including those beyond the phonon gas (PG) limit. Using the time-dependent,…

Statistical Mechanics · Physics 2019-01-30 Yi Zeng , Jianjun Dong

Accurate free-energy estimation is essential in molecular simulation, yet the periodic boundary conditions (PBC) commonly used in computer simulations have rarely been explicitly exploited. Equilibrium methods such as umbrella sampling,…

Statistical Mechanics · Physics 2025-11-03 Daniel Nagel , Tristan Bereau

We develop a highly efficient method to numerically simulate thermal fluctuations and correlations in non-relativistic continuous bosonic one-dimensional systems. We start by noticing the equivalence of their description through the…

Quantum Gases · Physics 2020-04-20 Stefan Beck , Igor E. Mazets , Thomas Schweigler

We study nonlinear vibrational modes of oscillations for tetrahedral configurations of particles. In the case of tetraphosphorus, the interaction of atoms is given by bond stretching and van der Waals forces. Using equivariant gradient…

Dynamical Systems · Mathematics 2018-04-30 Irina Berezovik , Carlos García-Azpeitia , Wieslaw Krawcewicz

Solving the stationary nonlinear Fokker-Planck equations is important in applications and examples include the Poisson-Boltzmann equation and the two layer neural networks. Making use of the connection between the interacting particle…

Numerical Analysis · Mathematics 2023-10-03 Lei Li , Yijia Tang , Jingtong Zhang

Vibronic spectra of molecules are typically described within the Franck-Condon model. Here, we show that highly resolved vibronic spectra of large organic molecules on a single layer of MoS$_{2}$ on Au(111) show spatial variations in their…

Mesoscale and Nanoscale Physics · Physics 2020-03-24 Gaël Reecht , Nils Krane , Christian Lotze , Lei Zhang , Alejandro L. Briseno , Katharina J. Franke

The accurate modeling of mode hybridization and calculation of radiative relaxation rates have been crucial to the design and optimization of superconducting quantum devices. In this work, we introduce a spectral theory for the…

Quantum Physics · Physics 2024-04-11 Dung N. Pham , Richard D. Li , Hakan E. Türeci

Active Brownian particles (ABPs) function as self-driving agents that display non-equilibrium behavior through their pairwise interactions which lead to phase separation and vortex patterns in both soft matter and living systems. A…

Soft Condensed Matter · Physics 2025-09-09 Sadra Saremi , Amirhossein Ahmadkhan Kordbacheh

The modeling of complex reaction-diffusion processes in, for instance, cellular biochemical networks or self-assembling soft matter can be tremendously sped up by employing a multiscale algorithm which combines the mesoscopic Green's…

Molecular Networks · Quantitative Biology 2017-04-05 Adithya Vijaykumar , Thomas E. Ouldridge , Pieter Rein ten Wolde , Peter G. Bolhuis

Microscopic thermal fluctuations are known to affect the macroscopic and spatio-temporal evolution of a host of physical phenomena central to the study of biological systems, turbulence, and reactive mixtures, among others. In…

Fluid Dynamics · Physics 2024-09-17 K. J. Petersen , J. R. Brinkerhoff

In the Ermak-McCammon algorithm for Brownian Dynamics, the hydrodynamic interactions (HI) between N spherical particles are described by a 3N x 3N diffusion tensor. This tensor has to be factorized at each timestep with a runtime of O(N^3),…

Soft Condensed Matter · Physics 2009-11-13 Tihamer Geyer , Uwe Winter

Particle acceleration by turbulence plays a role in many astrophysical environments. The non- linear evolution of the underlying cosmic-ray spectrum is complex and can be described by a Fokker-Planck equation, which in general has to be…

Cosmology and Nongalactic Astrophysics · Physics 2015-06-22 Julius Donnert , Gianfranco Brunetti

We consider an electromechanical system where a microwave cavity is coupled to a mechanical resonator, with a mechanical frequency twice the microwave frequency. In this regime, the effective photon-phonon interaction is equivalent to that…

Quantum Physics · Physics 2019-01-09 E. Jansen , J. D. P. Machado , Ya. M. Blanter

The transition between the gas-, supercritical-, and liquid-phase behaviour is a fascinating topic which still lacks molecular-level understanding. Recent ultrafast two-dimensional infrared spectroscopy experiments suggested that the…

Chemical Physics · Physics 2023-03-22 Kai Töpfer , Debasish Koner , Shyamsunder Erramilli , Lawrence D. Ziegler , Markus Meuwly

Studying the jamming transition of granular and colloidal systems, has lead to a proliferation of theoretical and numerical results formulated in the language of the eigenspectrum of the dynamical matrix for these disordered system. Only…

Soft Condensed Matter · Physics 2016-01-19 Silke Henkes , Carolina Brito , Olivier Dauchot

Modeling and direct numerical simulation of particle-laden flows have a tremendous variety of applications in science and engineering across a vast spectrum of scales from pollution dispersion in the atmosphere, to fluidization in the…

The computation of the nuclear quantum dynamics of molecules is challenging, requiring both accuracy and efficiency to be applicable to systems of interest. Recently, theories have been developed for employing time-dependent basis functions…

We formulate theoretical modeling approaches and develop practical computational simulation methods for investigating the non-equilibrium statistical mechanics of fluid interfaces with passive and active immersed particles. Our approaches…

Soft Condensed Matter · Physics 2024-10-03 Dev Jasuja , Paul J. Atzberger
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