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The discovery of superconductivity in CaC6 with a critical temperature (Tc) of 11.5 K reignites much interest in exploring high-temperature superconductivity in graphite intercalation compounds (GICs). Here we identify a GIC NaC4,…

We report experimental results indicating possible high-temperature superconductivity in graphite intercalation compounds synthesized with lithium-based alloys. Temperature-dependent measurements of magnetization, trapped magnetic flux, and…

In this letter, we report the discovery of superconductivity in Li3Ca2C6. Several graphite intercalation compounds (GICs) with electron donors, are well known as superconductors. It is probably not astonishing, since it is generally…

On the basis of the model that was successfully applied to KC8, RbC8, and CsC8 in 1982, we have calculated the superconducting transition temperature Tc for CaC6 and YbC6 to find that the same model reproduces the observed Tc in those…

Superconductivity · Physics 2016-01-13 Yasutami Takada

A recent ab initio investigation of Na-C binary compounds under moderate pressures has uncovered a possible stable NaC$_4$ superconductor with an estimated critical temperature up to 41K. We revisit this promising binary system by…

Graphite intercalation compounds (GICs) have a variety of functions due to their rich material variations, and thus,innovative methods for their synthesis are desired for practical applications. We have discovered that Na has a catalytic…

Materials Science · Physics 2023-03-28 Akira Iyo , Hiraku Ogino , Shigeyuki Ishida , Hiroshi Eisaki

Search for new high-temperature superconductors and insight into their superconducting mechanism are of fundamental importance in condensed matter physics. The discovery of near-room temperature superconductivity at more than a million…

Although not an intrinsic superconductor, it has been long--known that, when intercalated with certain dopants, graphite is capable of exhibiting superconductivity. Of the family of graphite--based materials which are known to superconduct,…

Superconductivity · Physics 2016-08-16 Gabor Csányi , P. B. Littlewood , A. H. Nevidomskyy , Chris J. Pickard , B. D. Simons

Using density functional theory we investigate the occurrence of superconductivity in AC$_6$ with A=Mg,Ca,Sr,Ba. We predict that at zero pressure, Ba and Sr should be superconducting with critical temperatures (T$_c$) 0.2 K and 3.0 K,…

Superconductivity · Physics 2009-11-11 Matteo Calandra , Francesco Mauri

The pressure effect on the superconducting transition temperature ($T_c$) of the newly-discovered Ca-intercalated graphite compound CaC$_6$ has been investigated up to $\sim$ 16 kbar. $T_c$ is found to increase under pressure with a large…

Superconductivity · Physics 2015-06-25 J. S. Kim , L. Boeri , R. K. Kremer , F. S. Razavi

The deposition and intercalation of metal atoms can induce superconductivity in monolayer and bilayer graphenes. For example, it has been experimentally proved that Li-deposited graphene is a superconductor with critical temperature $T_{c}$…

Superconductivity · Physics 2024-05-07 Jin-Han Tan , Hao Wang , Ying-Jie Chen , Na Jiao , Meng-Meng Zheng , Hong-Yan Lu , Ping Zhang

We report the discovery of superconductivity below 1.65(6) K in Sr-intercalated graphite SrC6, by susceptibility and specific heat (Cp) measurements. In comparison with CaC6, we found that the anisotropy of the upper critical fields for…

Superconductivity · Physics 2009-11-13 J. S. Kim , L. Boeri , J. R. O'Brien , F. S. Razavi , R. K. Kremer

In this letter we report the discovery of superconductivity in the isostructural graphite intercalation compounds C6Yb and C6Ca, with transition temperatures of 6.5K and 11.5K respectively. A structural characterisation of these compounds…

Superconductivity · Physics 2015-06-25 Thomas E. Weller , Mark Ellerby , Siddharth S. Saxena , Robert P. Smith , Neal T. Skipper

The difficult intercalation of sodium (Na) into graphite is studied by systematic and long-time investigations (of up to 2 years) using highly oriented pyrolytic graphite (HOPG). By studying chemical insertion of solid, liquid and gaseous…

Graphene, a zero-gap semimetal, can be transformed into a metallic, semiconducting or insulating state by either physical or chemical modification. Superconductivity is conspicuously missing among these states despite considerable…

Superconductivity · Physics 2016-04-05 J. Chapman , Y. Su , C. A. Howard , D. Kundys , A. Grigorenko , F. Guinea , A. K. Geim , I. V. Grigorieva , R. R. Nair

Searching for superconductivity with Tc near room temperature is of great interest both for fundamental science & many potential applications. Here we report the experimental discovery of superconductivity with maximum critical temperature…

Sulfur intercalated graphite composites with diamagnetic transitions at 6.7 K and 37 K are prepared. The magnetization hysteresis loops (MHL), Xray diffraction patterns, and resistance were measured. From the MHL, a slight superconducting…

Superconductivity · Physics 2009-11-07 H. P. Yang , H. H. Wen , Z. W. Zhao , S. L. Li

The superconducting state of Ca-intercalated graphite CaC6 has been investigated by specific heat measurements. The characteristic anomaly at the superconducting transition (Tc = 11.4 K) indicates clearly the bulk nature of the…

Superconductivity · Physics 2009-11-11 J. S. Kim , R. K. Kremer , L. Boeri , F. S. Razavi

Room temperature superconductivity under normal conditions has been a major challenge of physics and material science since its very discovery. Here we report the global room-temperature superconductivity observed in cleaved highly oriented…

Superconductivity with transition temperature $T_c=1.7$ K has been reported in bilayer graphene [1,2]. The main factors, which may shed light on the mechanism of the formation of this superconductivity, are the following. Superconductivity…

Superconductivity · Physics 2018-06-22 G. E. Volovik
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