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Many of the purported virtues of Multi-Principal Element Alloys (MPEAs), such as corrosion, high-temperature oxidation and irradiation resistance, are highly sensitive to vacancy diffusivity. Similarly, solute interdiffusion is governed by…

Materials Science · Physics 2020-03-18 Spencer L. Thomas , Srikanth Patala

Multi-principal element alloys (MPEAs) are exciting systems showing remarkable properties compared to conventional materials due to their exceedingly large compositional space and spatially varying chemical environment. However, predicting…

Materials Science · Physics 2022-09-12 Mauricio Ponga , Mohamed Hendy , Okan K. Orhan , Swarnava Ghosh

Multi-principal element alloys (MPEAs) continue to garner interest as structural and plasma-facing materials due to their structure stability and increased resistance to radiation damage. Despite sensitivity of mechanical behavior to…

Materials Science · Physics 2022-04-29 Ankit Roy , Prashant Singh , Ganesh Balasubramanian , Duane D. Johnson

Multi principal element alloys (MPEAs) comprise a unique class of metal alloys. MPEAs have been demonstrated to possess several exceptional properties, including, as most relevant to the present study, a high corrosion resistance. In the…

Multi-Principal Element Alloys (MPEAs) have emerged as an exciting area of research in materials science in the 2020s, owing to the vast potential for discovering alloys with unique and tailored properties enabled by the combinations of…

Materials Science · Physics 2024-08-15 Brent Vela , Trevor Hastings , Raymundo Arróyave

Finding Minimum Energy Configurations (MECs) is essential in fields such as physics, chemistry, and materials science, as they represent the most stable states of the systems. In particular, identifying such MECs in multi-component alloys…

Materials Science · Physics 2025-01-27 Md Rajib Khan Musa , Yichen Qian , Jie Peng , David Cereceda

Due to the vast compositional space of multi-principal element alloys (MPEAs), the rational design of MPEAs for optimized microstructures is difficult. Therefore, a high-throughput first-principles study of Mo-V-Nb-Ti-Zr, a refractory MPEA,…

Materials Science · Physics 2021-05-25 Zhidong Leong , Upadrasta Ramamurty , Teck Leong Tan

The equilibrium vacancy concentration in multi-principal element alloys remains a controversial and nontrivial subject, primarily because of chemical complexity and chemical short-range order (CSRO). Here we derive an exact expression that…

Materials Science · Physics 2025-12-30 Hao Tang , Hoje Chun , Rafael Gomez-Bombarelli , Yuri Mishin , Ju Li

Multi-principal element materials (MPEMs) have been attracting a rapidly growing interest due to their exceptional performance under extreme conditions, from cryogenic conditions to extreme-high temperatures and pressures. Despite the…

Materials Science · Physics 2022-11-28 Okan K. Orhan , Mewael Isiet , Mauricio Ponga , David D. O'Regan

Cluster expansions are commonly employed as surrogate models to link the electronic structure of an alloy to its finite-temperature properties. Using cluster expansions to model materials with several alloying elements is challenging due to…

Materials Science · Physics 2025-01-31 Yann L. Müller , Anirudh Raju Natarajan

Metallurgists have long been accustomed to a trade-off between yield strength and tensile ductility. Extending previously known strain-hardening mechanisms, the emerging multi-principal-element alloys (MPEAs) offer additional help in…

Materials Science · Physics 2024-02-13 Evan Ma , Chang Liu

Understanding atomic hydrogen (H) diffusion in multi-principal element alloys (MPEAs) is essential for advancing clean energy technologies such as H transport, storage, and nuclear fusion applications. However, the vast compositional space…

Materials Science · Physics 2025-05-14 Fei Shuang , Yucheng Ji , Zixiong Wei , Chaofang Dong , Wei Gao , Luca Laurenti , Poulumi Dey

Refractory multi-principal element alloys (MPEAs) have exceptional mechanical properties, including high strength-to-weight ratio and fracture toughness, at high temperatures. Here, we elucidate the complex interplay between segregation,…

Materials Science · Physics 2020-05-18 Xiang-Guo Li , Chi Chen , Hui Zheng , Yunxing Zuo , Shyue Ping Ong

The possibility of solid solution formation in high entropy alloys (HEAs) has been calculated for alloys with four to seven elements, using a rule previously reported. Thirty elements were included: transition elements of the fourth, fifth…

Materials Science · Physics 2021-05-03 Oscar Coreno Alonso , Juan Coreno Alonso

Recently, high-entropy alloys (HEAs) have attracted wide attention due to their extraordinary materials properties. A main challenge in identifying new HEAs is the lack of efficient approaches for exploring their huge compositional space.…

Materials Science · Physics 2019-05-07 Tatiana Kostiuchenko , Fritz Körmann , Jörg Neugebauer , Alexander Shapeev

Whilst multi-principal element alloys (MPEAs) remain a promising class of materials owing to several attractive mechanical properties, their corrosion performance is also unique. In this concise review, we present an emerging overview of…

While first-principles methods have been successfully applied to characterize individual properties of multi-principal element alloys (MPEA), their use to search for optimal trade-offs between competing properties is hampered by high…

Materials Science · Physics 2024-07-25 Franco Moitzi , Lorenz Romaner , Max Hodapp , Andrei V. Ruban , Oleg E. Peil

Multi-principal element alloys open large composition spaces for alloy development. The large compositional space necessitates rapid synthesis and characterization to identify promising materials, as well as predictive strategies for alloy…

Researchers attributed the orderly arranged nanoscale phases observed in many multi-principal element alloys (MPEAs) to spinodal/spinodal-mediated phase transformation pathways. However, spinodal decomposition is not well understood in…

Materials Science · Physics 2023-04-14 Kamalnath Kadirvel , Shalini Roy Koneru , Yunzhi Wang

High-entropy alloys (HEAs) refer to alloys composed of five or more elements in equal or near-equal amounts or in an atomic concentration range of 5 to 35 atomic percent (at%). Different elemental ratios will affect the microstructures of…

Materials Science · Physics 2025-02-25 Shiyi Chen , Xuesong Fan , Hugh Shortt , Baldur Steingrimsson , Weidong Li , Peter Liaw
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