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We present the results of models of the chemistry, including deuterium, in the inner regions of protostellar disks. We find good agreement with recent gas phase observations of several (non--deuterated) species. We also compare our results…

Solar and Stellar Astrophysics · Physics 2015-05-13 K. Willacy , P. Woods

Many complex organic molecules (COMs) in star-forming regions are believed to form on dust grains. We thus expect both the reduced metallicity and dust-to-gas ratio in the outer Galaxy to have an impact on the chemical composition of these…

Astrophysics of Galaxies · Physics 2026-05-15 Youxin Wang , Arnaud Belloche , Robin T. Garrod

(Abridged) Exoplanet atmospheres are thought be built up from accretion of gas as well as pebbles and planetesimals in the midplanes of planet-forming disks. The chemical composition of this material is usually assumed to be unchanged…

Earth and Planetary Astrophysics · Physics 2018-05-23 Christian Eistrup , Catherine Walsh , Ewine F van Dishoeck

The atmospheric chemical composition of a hot Jupiter can lead to insights into where in its natal protoplanetary disk it formed and its subsequent migration pathway. We use a 1-D chemical kinetics code to compute a suite of models across a…

Earth and Planetary Astrophysics · Physics 2022-08-17 Richard Hobbs , Oliver Shorttle , Nikku Madhusudhan

We propose a scenario that explains the apparent nitrogen deficiency in comets in a way consistent with the fact that the surfaces of Pluto and Triton are dominated by nitrogen-rich ice. We use a statistical thermodynamic model to…

The discovery of the first two interstellar objects implies that, on average, every star contributes a substantial amount of material to the galactic population by ejecting such bodies from the host system. Since scattering is a chaotic…

Earth and Planetary Astrophysics · Physics 2022-07-06 Darryl Z. Seligman , Juliette Becker , Fred C. Adams , Adina D. Feinstein , Leslie A. Rogers

Most stars, including the Sun, are born in rich stellar clusters containing massive stars. Therefore, the study of the chemical reservoir of massive star-forming regions is crucial to understand the basic chemical ingredients available at…

As comets journey into the inner solar system, they deliver particulates and volatile gases into their comae that reveal the most primitive materials in the solar system. Cometary dust particles provide crucial information for assessing the…

Earth and Planetary Astrophysics · Physics 2023-09-28 David E. Harker , Diane H. Wooden , Michael S. P. Kelley , Charles E. Woodward

Context. Time dependent gas-grain chemistry can help us understand the layered structure of species deposited onto the surface of grains during the lifetime of a protoplanetary disk. The history of trapping important quantities of carbon-…

Solar and Stellar Astrophysics · Physics 2016-11-25 Germán Chaparro Molano , Inga Kamp

We present new models of the deuterium chemistry in protoplanetary disks, including, for the first time, multiply deuterated species. We use these models to explore whether observations in combination with models can give us clues as to…

Astrophysics · Physics 2011-02-11 K. Willacy

We study the influence of the turbulent transport on ice chemistry in protoplanetary disks, focusing on carbon and nitrogen bearing molecules. Chemical rate equations are solved with the diffusion term, mimicking the turbulent mixing in the…

Earth and Planetary Astrophysics · Physics 2015-06-22 Kenji Furuya , Yuri Aikawa

Elements in the interstellar medium (ISM) exist in the form of gas or dust. The interstellar extinction and elemental abundances provide crucial constraints on the composition, size and quantity of interstellar dust. Most of the extinction…

Astrophysics of Galaxies · Physics 2021-03-17 W. B. Zuo , Aigen Li , Gang Zhao

Context: Solar-like protostars are known to be chemically rich, but it is not yet clear how much their chemical composition can vary and why. So far, two chemically distinct types of Solar-like protostars have been identified: hot corinos,…

Astrophysics of Galaxies · Physics 2020-04-08 M. Bouvier , A. López-Sepulcre , C. Ceccarelli , C. Kahane , M. Imai , N. Sakai , S. Yamamoto , P. J. Dagdigian

The imprints of stellar nucleosynthesis and chemical evolution of the galaxy can be seen in different stellar populations, with older generation stars showing higher $\alpha$-element abundances while the later generations becoming enriched…

Earth and Planetary Astrophysics · Physics 2022-07-27 C. Swastik , Ravinder K. Banyal , Mayank Narang , P. Manoj , T. Sivarani , S. P. Rajaguru , Athira Unni , Bihan Banerjee

The elemental composition of the gas and dust in a protoplanetary disk influences the compositions of the planets that form in it. We use the Molecules with ALMA at Planet-forming Scales (MAPS) data to constrain the elemental composition of…

Recent observations of the long period comet C/2016 R2 (PanSTARRS) indicate an unusually high N2/CO abundance ratio, typically larger than 0.05, and at least 2-3 times higher than the one measured in 67P/Churyumov-Gerasimenko. Another…

Comets provide a unique insight into the molecular composition and complexity of the material in the primordial solar nebula. Recent results from the Rosetta mission, currently monitoring comet 67P/Churyumov-Gerasimenko in situ, and ALMA…

Earth and Planetary Astrophysics · Physics 2016-05-27 Catherine Walsh

Molecular oxygen has been detected in the coma of comet 67P/Churyumov--Gerasimenko with a mean abundance of 3.80 $\pm$ 0.85\% by the ROSINA mass spectrometer on board the Rosetta spacecraft. To account for the presence of this species in…

Earth and Planetary Astrophysics · Physics 2018-06-06 O. Mousis , T. Ronnet , J. I. Lunine , R. Maggiolo , P. Wurz , G. Danger , A. Bouquet

(Abridged) The birth environment of the Sun will have influenced the conditions in the pre-solar nebula, including the attainable chemical complexity, important for prebiotic chemistry. The formation and distribution of complex organic…

Earth and Planetary Astrophysics · Physics 2014-06-04 Catherine Walsh , Eric Herbst , Hideko Nomura , T. J. Millar , Susanna Widicus Weaver

The deuterium fractionation of gas-phase molecules in hot cores is believed to reflect the composition of interstellar ices. The deuteration of methanol is a major puzzle, however, because the isotopologue ratio [CH2DOH]/[CH3OD], which is…

Solar and Stellar Astrophysics · Physics 2015-12-02 A. Faure , M. Faure , P. Theulé , E. Quirico , B. Schmitt