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We report on two fold increase in superconducting transition temperature of La3Co4Sn13 by substituting indium at the tin site. The transition temperature of this skutterudite is observed to increase from 2.5 K to 5.1 K for 10 % indium…

Superconductivity · Physics 2015-09-17 P. Neha , P. Srivastava , R. Jha , Shruti , V. P. S. Awana , S. Patnaik

Here we report targeted high-pressure synthesis of two novel high-$T_C$ hydride superconductors, $P6_3/mmc$-$ThH_9$ and $Fm\bar{3}m$-$ThH_{10}$, with the experimental critical temperatures ($T_C$) of 146 K and 159-161 K and upper critical…

Inspired by the synthesis of the high-pressure Fm-3m LaH10 superconducting superhydride, systematic density functional theory (DFT) calculations are performed to study ternaries that could be derived from it by replacing two of the hydrogen…

Superconductivity · Physics 2024-01-02 Nisha Geng , Katerina P. Hilleke , Francesco Belli , Pratik Kumar Das , Eva Zurek

Searching for superconductivity with Tc near room temperature is of great interest both for fundamental science & many potential applications. Here we report the experimental discovery of superconductivity with maximum critical temperature…

Organic superconductors are unique materials with a crystal structure made primarily of a complex carbon based network, an element associated directly with life, which were postulated to have a high critical temperature, $T_{C}$, even above…

The semimetal antimony (Sb) element doped into hydrogen has been performed theoretically to explored high-pressure crystal structure and superconductivity of antimony hydrides. The unexpected stoichiometry $\textrm{SbH}_\textrm{4}$ with…

Superconductivity · Physics 2015-06-24 Yanbin Ma , Defang Duan , Da Li , Yunxian Liu , Fubo Tian , Xiaoli Huang , Zhonglong Zhao , Hongyu Yu , Bingbing Liu , Tian Cui

New stable thorium decahydride $Fm\bar{3}m$-$ThH_{10}$, a record high-temperature superconductor with $T_C$ up to 241 K ($-32^{\circ}C$), critical field $H_C$ up to 71T and superconducting gap ${\Delta_0}$ = 52 meV at 80-100 GPa was…

High pressure structures, phase diagram and superconductivity of polonium hydrides have been systematically investigated through the first-principles calculations based on the density functional theory. With the increasing pressure, several…

The rapid variation of the superconductivity Tc in hydride sulfur (H3S) under high pressure [A. Drozdov et al, Nature 525, 73 (2015); M. Einaga et al, arXiv: 1509.03156] in a vicinity Pcr=123GPa is interpreted in terms of the 1st order…

Superconductivity · Physics 2016-01-01 Lev P. Gor'kov , V. Z. Kresin

Motivated by the recent claim of hot superconductivity with critical temperatures up to 550 K in La + x hydrides (arXiv:2006.03004), we investigate the high-pressure phase diagram of possible compounds that may have formed in the…

Superconductivity · Physics 2021-06-15 Simone Di Cataldo , Wolfgang von der Linden , Lilia Boeri

In the last six years (2015-2021), many superconducting hydrides with critical temperatures $\textit{T}$$_C$ of up to 253 K, a record for today, have been discovered. Now, a special field of hydride superconductivity at ultrahigh pressures…

Superconductivity · Physics 2023-07-26 Dmitrii Semenok

We present the effect of yttrium substitution on superconductivity in the La$_{1-\textit{x}}$Y$_{\textit{x}}$O$_{0.5}$F$_{0.5}$BiS$_{2}$ system. Polycrystalline samples with nominal Y concentrations up to 40% were synthesized and…

Superconductivity · Physics 2014-10-02 I. Jeon , D. Yazici , B. D. White , A. J. Friedman , M. B. Maple

Recently, the thorium hydride ThH9 possessing an H-rich clathrate structure has been experimentally synthesized to exhibit a superconducting transition temperature Tc of 146 K at 170-175 GPa, while the more H-rich clathrate thorium hydride…

Superconductivity · Physics 2023-02-15 Shichang Yao , Chongze Wang , Hyunsoo Jeon , Liangliang Liu , Jin Mo Bok , Yunkyu Bang , Yu Jia , Jun-Hyung Cho

Discovery of high-temperature superconductivity in hydrogen-rich compounds has fuelled the enthusiasm for finding materials with more promising superconducting properties among hydrides. However, the ultrahigh pressure needed to synthesize…

Superconductivity · Physics 2021-09-22 Miao Gao , Xun-Wang Yan , Zhong-Yi Lu , Tao Xiang

We report the electric transport and thermodynamic properties of the skutterudite-related La$_3$Co$_4$Sn$_{13}$ and La$_3$Rh$_4$Sn$_{13}$ superconductors. Applying an external pressure to La$_3$Rh$_4$Sn$_{13}$, the resistive superconducting…

Superconductivity · Physics 2014-03-25 A. Slebarski , M. Fijalkowski , M. M. Maska , M. Mierzejewski , B. D. White , M. B. Maple

The discovery of a superconducting phase in sulfur hydride under high pressure with a critical temperature above 200 K has provided a new impetus to the search for even higher $T_c$. Theory predicted and experiment confirmed that the phase…

Search for stable high-pressure compounds in the Ti--H system reveals the existence of titanium hydrides with new stoichiometries, including Ibam-Ti$_2$H$_5$, I4/m-Ti$_5$H$_{13}$, I$\bar{4}$-Ti$_5$H$_{14}$, Fddd-TiH$_4$,…

Materials Science · Physics 2020-05-20 Jin Zhang , Jeffrey M. McMahon , Artem R. Oganov , Xinfeng Li , Xiao Dong , Huafeng Dong , Shengnan Wang

Recently superconductivity has been discovered at around 200~K in a hydrogen sulfide system and around 260~K in a lanthanum hydride system, both under pressures of about 200 GPa. These record-breaking transition temperatures bring within…

Superconductivity · Physics 2020-07-15 Sabri Elatresh , T. Timusk , E. J. Nicol

Results of phase formation, resistivity (r), and thermo-electric power (S), are reported on Y1-xCaxBa2Cu2.7Co0.3O7 compounds with x = 0.1 and 0.2. Pristine compound i.e. without Co or Ca substitution crystallizes in orthorhombic structure…

While hydrogen-rich materials have been demonstrated to exhibit high T$_c$ superconductivity at high pressures, there is an ongoing search for ternary and quaternary hydrides that achieve such high critical temperatures at much lower…

Superconductivity · Physics 2024-07-25 Adam Denchfield , Hyowon Park , Russell J Hemley
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