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In mixed-valence or heavy-fermion systems, the hybridization between local $f$ orbitals and conduction band states can cause the suppression of long-range magnetic order, which competes with strong spin fluctuations. Ce- and Yb-based…

Unusual phases and phase transitions are seen at the magnetic-nonmagnetic boundary in Ce, Eu and Yb-based compounds. EuNi$_2$P$_{2}$ is a very unusual valence fluctuating Eu system, because at low temperatures the Eu valence stays close to…

Strongly Correlated Electrons · Physics 2016-11-11 U. B. Paramanik , A. Bar , Debarchan Das , N. Caroca-Canales , R. Prasad , C. Geibel , Z. Hossain

Eu$_5$In$_2$Sb$_6$ is a member of a family of orthorhombic nonsymmorphic rare-earth intermetallics that combines large localized magnetic moments and itinerant exchange with a low carrier density and perpendicular glide planes. This may…

We have studied crystal structure, magnetism and electric transport properties of a europium fulleride Eu6C60 and its Sr-substituted compounds, Eu6-xSrxC60. They have a bcc structure, which is an isostructure of other M6C60 (M represents an…

Materials Science · Physics 2009-11-07 Kenji Ishii , Akihiko Fujiwara , Hiroyoshi Suematsu , Yoshihiro Kubozono

Valence transition could induce structural, insulator-metal, nonmagnetic-magnetic and superconducting transitions in rare-earth metals and compounds, while the underlying physics remains unclear due to the complex interaction of localized…

The ground-state magnetic structure of EuNi$_{2}$As$_{2}$ was investigated by single-crystal neutron diffraction. At base temperature, the Eu$^{2+}$ moments are found to form an incommensurate antiferromagnetic spiral-like structure with a…

Strongly Correlated Electrons · Physics 2019-01-30 W. T. Jin , N. Qureshi , Z. Bukowski , Y. Xiao , S. Nandi , M. Babij , Z. Fu , Y. Su , Th. Brückel

We report the magnetic properties of two Eu based compounds, single crystalline EuIrGe$_3$ and EuRhGe$_3$, inferred from magnetisation, electrical transport, heat capacity and $^{151}$Eu M\"{o}ssbauer spectroscopy. These previously known…

Strongly Correlated Electrons · Physics 2015-12-09 Arvind Maurya , P. Bonville , R. Kulkarni , A. Thamizhavel , S. K. Dhar

We report the design, synthesis, crystal structure, and physical properties of a layered intergrowth compound, Eu$_2$CuMn$_2$P$_3$. The structure of Eu$_2$CuMn$_2$P$_3$ features an alternating arrangement of hexagonal EuCuP block layers and…

Materials Science · Physics 2025-06-03 Xiyu Chen , Ziwen Wang , Wuzhang Yang , Jia-Yi Lu , Zhiyu Zhou , Zhi Ren , Guang-Han Cao , Shuai Dong , Zhi-Cheng Wang

Element-specific x-ray resonant magnetic scattering investigations were performed to determine the magnetic structure of Eu in EuRh2As2. In the temperature range from 46 K down to 6 K, an incommensurate antiferromagnetic (ICM)structure with…

Strongly Correlated Electrons · Physics 2010-11-17 S. Nandi , A. Kreyssig , Y. Lee , Yogesh Singh , J. W. Kim , D. C. Johnston , B. N. Harmon , A. I. Goldman

The investigation of crystallographic, electronic, and magnetic characteristics, especially the mixed valences of Eu$^{2+}$ and Eu$^{3+}$ under pressure of a novel europium-based bismuth selenide compound, Eu$_4$Bi$_6$Se$_{13}$, presented.…

The solid solution 122 compounds, Eu(Co$_{1-x}$Ni$_{x}$)$_{2}$P$_{2}$, show valence transition between divalent state and intermediate valence states at Eu, which is firmly correlated to multiple degrees of freedom in the solid such as the…

We conducted a joint experimental-theoretical investigation of the high-pressure chemistry of europium polyhydrides at pressures of 86-130 GPa. We discovered several novel magnetic Eu superhydrides stabilized by anharmonic effects: cubic…

In rare-earth compounds with valence fluctuation, the proximity of the 4f level to the Fermi energy leads to instabilities of the charge configuration and the magnetic moment. Here, we provide direct experimental evidence for an induced…

Strongly Correlated Electrons · Physics 2023-01-31 K. Chen , C. Luo , Y. Zhao F. Baudelet , A. Maurya , A. Thamizhavel , U. K. Rößler , D. Makarov , F. Radu

The Eu-based compound, EuCu2As2, crystallizing in the ThCr2Si2-type tetragonal structure, has been synthesized and its magnetic behavior has been investigated by magnetization (M), heat-capacity (C) and electrical resistivity (rho)…

Strongly Correlated Electrons · Physics 2009-11-11 Kausik Sengupta , P. L. Paulose , E. V. Sampathkumaran , Th. Doert , J. P. F. Jemetio

X-ray magnetic circular dichroism (XMCD) at the Eu L-edge (2p->5d) in two compounds exhibiting valence fluctuation, namely EuNi2(Si0.18Ge0.82)2 and EuNi2P2, has been investigated at pulsed high magnetic fields of up to 40 T. A distinct XMCD…

Strongly Correlated Electrons · Physics 2009-06-19 Y. H. Matsuda , Z. W. Ouyang , H. Nojiri , T. Inami , K. Ohwada , M. Suzuki , N. Kawamura , A. Mitsuda , H. Wada

The compound EuCo{2-y}As2 with the tetragonal ThCr2Si2 structure is known to contain Eu{+2} ions with spin S = 7/2 that order below a temperature TN = 47 K into an antiferromagnetic (AFM) proper helical structure with the ordered moments…

Strongly Correlated Electrons · Physics 2018-04-25 N. S. Sangeetha , V. K. Anand , Eduardo Cuervo-Reyes , V. Smetana , A. -V. Mudring , D. C. Johnston

Among iron 122 pnictide superconductors, the EuFe$_2$As$_2$ series draws particular interest because, in addition to superconductivity or the long-range spin-density-wave order in the Fe subsystem, the localized Eu$^{2+}$ magnetic moments…

Superconductivity · Physics 2011-03-15 Sina Zapf , Dan Wu , Lapo Bogani , Hirale S. Jeevan , Philipp Gegenwart , Martin Dressel

Materials exhibiting electronic inhomogeneities at the nanometer scale have enormous potential for applications. Magnetic polarons are one such type of inhomogeneity which link the electronic, magnetic and lattice degrees of freedom in…

We present results of the magnetic susceptibility on high-quality single crystals of EuPd$_2$(Si$_{1-x}$Ge$_x$)$_2$ for Ge concentrations 0 $\leq x \leq$ 0.105 performed under varying hydrostatic (He-gas) pressure 0 $\leq p \leq$ 0.5 GPa.…

Strongly Correlated Electrons · Physics 2023-07-12 Bernd Wolf , Theresa Lundbeck , Jan Zimmermann , Marius Peters , Kristin Kliemt , Cornelius Krellner , Michael Lang

Successive magnetic phase transitions at $T_{\text{N}}$=12.2 K, $T_{\text{N}}^{\;\prime}$=7.0 K, and $T_{\text{N}}^{\;*}$=5.0 K in EuIrGe$_3$, an intermetallic compound with a body centered tetragonal lattice belonging to a polar space…

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