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Phonon interactions from lattice anharmonicity govern thermal properties and heat transport in materials. These interactions are described by n-th order interatomic force constants (n-IFCs), which can be viewed as high-dimensional tensors…

Materials Science · Physics 2025-08-12 Yao Luo , Dhruv Mangtani , Shiyu Peng , Jia Yao , Sergei Kliavinek , Marco Bernardi

The microscopic origin of the large negative thermal expansion of cubic scandium trifluorides (ScF3) is investigated by performing a set of anharmonic free-energy calculations based on density functional theory. We demonstrate that the…

Materials Science · Physics 2019-03-13 Yusuke Oba , Terumasa Tadano , Ryosuke Akashi , Shinji Tsuneyuki

We propose a harmonic linear response (HLR) method to calculate the phonon dispersion relations of two-dimensional (2D) layers from equilibrium simulations at finite temperature. This HLR approach is based on the linear response of the…

Mesoscale and Nanoscale Physics · Physics 2020-01-14 R. Ramirez , C. P. Herrero

We examine the temperature dependence of thermal conductivity of one dimensional nonlinear (anharmonic) lattices with and without on-site potential. It is found from computer simulation that the heat conductivity depends on temperature via…

Disordered Systems and Neural Networks · Physics 2007-05-23 Nianbei Li , Baowen Li

Raman spectra from silicon nanostructures, recorded using excitation laser power density of 1.0 kW/cm^2, is employed here to reveal the dominance of thermal effects at temperatures higher than the room temperature. Room temperature Raman…

Mesoscale and Nanoscale Physics · Physics 2012-01-25 Rajesh Kumar , Vivek Kumar , A. K. Shukla

Polarized Raman, IR and time-domain THz spectroscopy of orthorhombic lead zirconate single crystals yielded a comprehensive picture of temperature-dependent quasiharmonic frequencies of its low-frequency phonon modes. It is argued that…

Materials Science · Physics 2014-05-21 J. Hlinka , T. Ostapchuk , E. Buixaderas , C. Kadlec , P. Kuzel , I. Gregora , J. Kroupa , M. Savinov , J. Drahokoupil , J. Dec

We review our recent development of a first-principles lattice dynamics method that can treat anharmonic effects nonperturbatively. The method is based on the self-consistent phonon theory and temperature-dependent phonon frequencies can be…

Materials Science · Physics 2018-01-29 Terumasa Tadano , Shinji Tsuneyuki

We report an ultrafast optical spectroscopy study on the coherent phonon dynamics in the topological semimetal CeBi and its nonmagnetic isostructural compound LaBi, revealing profound insights into their electronic and magnetic…

Strongly Correlated Electrons · Physics 2025-07-15 Xu-Chen Nie , Chen Zhang , Qi-Yi Wu , Hao Liu , Jie Pang , You-Guo Shi , Zhi-An Xu , Yan-Feng Guo , Ya-Hua Yuan , H. Y. Liu , Yu-Xia Duan , Jian-Qiao Meng

Particle tracking and displacement covariance matrix techniques are employed to investigate the phonon dispersion relations of two-dimensional colloidal glasses composed of soft, thermoresponsive microgel particles whose…

Soft Condensed Matter · Physics 2015-06-16 Tim Still , Carl P. Goodrich , Ke Chen , Peter J. Yunker , Samuel Schoenholz , Andrea J. Liu , A. G. Yodh

The coherence properties of mechanical resonators are often limited by multiple unavoidable forms of loss -- including phonon-phonon and phonon-defect scattering -- which result in the scattering of sound into other resonant modes and into…

Quantum Physics · Physics 2016-12-30 Xunnong Xu , Seunghwi Kim , Gaurav Bahl , Jacob M. Taylor

We investigate the anharmonic phonon scattering across a weakly interacting interface by developing a quantum mechanics-based theory. We find that the contribution from anharmonic three-phonon scatterings to interfacial thermal conductance…

Mesoscale and Nanoscale Physics · Physics 2022-02-23 Hangbo Zhou , Gang Zhang , Jian-Sheng Wang , Yong-Wei Zhang

Recently [1], we proposed a new way to engineer a flexible acoustomechanical coupling between the center-of-mass motion of an isolated micromagnet and one of its internal acoustic phonons by using a magnon as a passive mediator. In our…

Mesoscale and Nanoscale Physics · Physics 2020-03-11 C. Gonzalez-Ballestero , D. Hümmer , J. Gieseler , O. Romero-Isart

Based on thermodynamic principles, we derive expressions quantifying the non-harmonic vibrational behavior of materials, which are rigorous yet easily evaluated from experimentally available data for the thermal expansion coefficient and…

Materials Science · Physics 2016-07-29 Dipanshu Bansal , Amjad Aref , Gary Dargush , Olivier Delaire

Phonon measurements in the A15-type superconductors were complicated in the past because of the unavailability of large single crystals for inelastic neutron scattering, e.g., in the case of Nb$_3$Sn, or unfavorable neutron scattering…

Superconductivity · Physics 2019-04-19 A. Sauer , D. A. Zocco , A. H. Said , R. Heid , A. Böhmer , F. Weber

We study the dynamics of a symmetric two-level system strongly coupled to a broadened harmonic mode. Upon mapping the problem onto a spin-boson model with peaked spectral density, we show how analytic solutions can be obtained, at arbitrary…

Statistical Mechanics · Physics 2009-11-13 F. Nesi , M. Grifoni , E. Paladino

In recent years, nanostructuring of dielectric and semiconducting crystals has enhanced controllability of their thermal conductivity. To carry out computational material search for nanostructured materials with desirable thermal…

Mesoscale and Nanoscale Physics · Physics 2016-02-23 Takuma Shiga , Daisuke Aketo , Lei Feng , Junichiro Shiomi

Accurately simulating the atmospheric turbulence behaviour is always challenging. The well-known FFT based method falls short in correctly predicting both the low and high frequency behaviours. Sub-harmonic compensation aids in…

Instrumentation and Methods for Astrophysics · Physics 2022-08-15 Sorabh Chhabra , Jyotirmay Paul , A. N. Ramaprakash , Avinash Surendran

The characteristics of phonons, i.e. linearized normal modes of vibration, provide important insights into many aspects of crystals, e.g. stability and thermodynamics. In this paper, we use the Objective Structures framework to make…

Materials Science · Physics 2013-01-01 Amin Aghaei , Kaushik Dayal , Ryan S. Elliott

A combination of classical density-functional theory and thermodynamic perturbation theory is applied to a survey of finite-temperature trends in the relative stabilities of one-component crystals and quasicrystals interacting via effective…

Materials Science · Physics 2009-10-30 A. R. Denton , J. Hafner

The atomic, electronic structure and phonon frequencies have been calculated in a cubic and low-temperature tetragonal SrTiO3 phases at the ab initio level. We demonstrate that the use of hybrid exchange-correlation PBE0 functional gives…

Materials Science · Physics 2013-05-29 Robert A. Evarestov , Evgeny Blokhin , Denis Gryaznov , Eugene A. Kotomin , Joachim Maier