Related papers: Further testing the validity of generalized hetero…
To better understand the surprising low-frequency vibrational modes in structural glasses, we study the spectra of a large ensemble of sparse random matrices where disorder is controlled by the distribution of bond weights and network…
Using large-scale molecular dynamics simulations for a system of $10^6$ particles, the response of a dense amorphous solid to the continuous expansion of its volume is investigated. We find that the spatially uniform glassy state becomes…
Despite the presence of topological disorder, phonons seem to exist also in glasses at very high frequencies (THz) and they remarkably persist into the supercooled liquid. A universal feature of such a systems is the Boson peak, an excess…
Many systems, including polymers and molecular liquids, when adequately cooled and/or compressed, solidify into a disordered solid, i.e., a glass. The~transition is not abrupt, featuring progressive decrease of the microscopic mobility and…
Some facets of the way sound waves travel through glasses are still unclear. Recent works have shown that in the low-temperature harmonic limit a crucial role in controlling sound damping is played by local elastic heterogeneity. Sound…
Insisting on the relevance of spin-statistics theorem, I propose that anomalous low-energy excitations of strongly-noncrystalline solids (SNSs), observed at low temperatures T < 1 K, are fermions, which are localized and weakly interacting.…
Amorphous solids manifest puzzling effects of mysterious degrees of freedom that give rise to a heat capacity and phonon scattering in great excess over what would be expected for a solid that has a unique vibrational ground state. Of…
The work of this thesis concerns the problem of linear low energy excitations of vector spin glass models. An analytical and numerical study is carried out, considering a fully connected random-field Heisenberg model at zero temperature, a…
We perform molecular-dynamics simulations of the vibrational and the elasto-plastic properties of polymeric glasses and crystals and corresponding atomic systems. We evidence that the elastic scaling of the density of states in the…
The structure and vibrational density of states (VDOS) of polymer glasses are investigated using numerical simulations based on the classical Kremer-Grest bead-spring model. We focus on the roles of chain length and bending stiffness, the…
Implications of reduction procedures applied to the low energy part of the vibrational density of states in glasses and supercooled liquids are considered by advancing a detailed comparison between the excess - over the Debye limit -…
High Entropy Alloys (HEAs) are designed by mixing multiple metallic species in nearly the same amount to obtain crystalline or amorphous materials with exceptional mechanical properties. Here we use molecular dynamics simulations to…
Several puzzling regularities concerning the low temperature excitations of glasses are quantitatively explained by quantizing domain wall motions of the random first order glass transition theory. The density of excitations agrees with…
A lot has been said about the vibrational density of states (DoS) in liquids. A more recent discussion introduces contradictions with earlier results, and here I briefly review several pieces of evidence from modeling, experiments and…
The vibrational properties of three sodosilicate glasses have been investigated in the framework of Density Functional Theory. The pure vibrational density of states has been calculated for all systems and the different vibrational modes…
Comprehending sound damping is integral to understanding the anomalous low temperature properties of glasses. Despite decades of studies, the underlying mechanism of sound damping in glasses is still debated. In this perspective we review…
We report the first measurements of the effect of pressure on vibrational modes in emulsions, which serve as a model for soft frictionless spheres at zero temperature. As a function of the applied pressure, we find that the density of…
We present an implementation of the analytical string theory recently applied to the description of glasses. These are modeled as continuum media with embedded elastic string heterogeneities, randomly located and randomly oriented, which…
The topological nature of the disorder of glasses and supercooled liquids strongly affects their high-frequency dynamics. In order to understand its main features, we analytically studied a simple topologically disordered model, where the…
We show that thermodynamic scaling can be derived by combining the Murnaghan equation of state (EOS) with the generalized entropy theory (GET) of glass formation. In our theory, thermodynamic scaling arises in the non-Arrhenius relaxation…