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We develop a predictor-feedback control design for a class of linear systems with state-dependent switching. The main ingredient of our design is a novel construction of an exact predictor state. Such a construction is possible as for a…

Systems and Control · Electrical Eng. & Systems 2026-03-23 Andreas Katsanikakis , Nikolaos Bekiaris-Liberis , Delphine Bresch-Pietri

The variational principle for conformational dynamics has enabled the systematic construction of Markov state models through the optimization of hyperparameters by approximating the transfer operator. In this note we discuss why lag time of…

Biomolecules · Quantitative Biology 2019-11-26 Brooke E. Husic , Vijay S. Pande

We consider contractive systems whose trajectories evolve on a compact and convex state-space. It is well-known that if the time-varying vector field of the system is periodic then the system admits a unique globally asymptotically stable…

Systems and Control · Computer Science 2017-02-23 Michael Margaliot , Samuel Coogan

We study the stochastic motion of active particles that undergo spontaneous transitions between two distinct modes of motion. Each mode is characterized by a velocity distribution and an arbitrary (anti-)persistence. We present an…

Statistical Mechanics · Physics 2023-07-07 M. Reza Shaebani , Heiko Rieger , Zeinab Sadjadi

Whereas the importance of transient dynamics to the functionality and management of complex systems has been increasingly recognized, most of the studies are based on models. Yet in realistic situations the models are often unknown and what…

Adaptation and Self-Organizing Systems · Physics 2021-10-25 Huawei Fan , Liang Wang , Yao Du , Yafeng Wang , Jinghua Xiao , Xingang Wang

Stochastic reduced-order models are widely used to represent the effective dynamics of complex systems, but estimating their drift and diffusion coefficients from data remains challenging. Standard approaches often rely on short-time…

Machine Learning · Statistics 2026-04-28 Ludovico T. Giorgini

This work is devoted to the investigation of the most probable transition time between metastable states for stochastic dynamical systems. Such a system is modeled by a stochastic differential equation with non-vanishing Brownian noise, and…

Mathematical Physics · Physics 2021-08-11 Yuanfei Huang , Ying Chao , Wei Wei , Jinqiao Duan

The reaction coordinate describing a transition between reactant and product is a fundamental concept in the theory of chemical reactions. Within transition-path theory, a quantitative definition of the reaction coordinate is found in the…

Statistical Mechanics · Physics 2022-05-03 Miranda D. Louwerse , David A. Sivak

This paper addresses the challenge of achieving stable adaptive teleoperation and improving the convergence rate in the presence of high communication time delays. We employ a passivity-based formalism to establish stability using wave…

Optimization and Control · Mathematics 2024-08-16 Naveen Kumar Rajarajan , Sridhar Babu Mudhangulla , Olugbenga Moses Anubi

The committor functions are central to investigating rare but important events in molecular simulations. It is known that computing the committor function suffers from the curse of dimensionality. Recently, using neural networks to estimate…

Machine Learning · Statistics 2025-01-28 Yueyang Wang , Kejun Tang , Xili Wang , Xiaoliang Wan , Weiqing Ren , Chao Yang

Transition path theory (TPT) offers a powerful formalism for extracting the rate and mechanism of rare dynamical transitions between metastable states. Most applications of TPT either focus on systems with modestly sized state spaces or use…

Statistical Mechanics · Physics 2026-01-14 Nils E. Strand , Schuyler B. Nicholson , Hadrien Vroylandt , Todd R. Gingrich

Atomistic simulations are widely used to investigate reactive processes but are often limited by the rare event problem due to kinetic bottlenecks. We recently introduced an enhanced sampling approach based on the committor function,…

Computational Physics · Physics 2026-03-02 Enrico Trizio , Giorgia Rossi , Michele Parrinello

Adiabatic passage employs a slowly varying time-dependent Hamiltonian to control the evolution of a quantum system along the Hamiltonian eigenstates. For processes of finite duration, the exact time evolving state may deviate from the…

Quantum Physics · Physics 2021-06-18 Albert Benseny , Klaus Mølmer

When particles/molecules diffuse in systems that contain obstacles, the steady-state regime (during which the mean-square displacement scales linearly with time, $\left< r^2 \right> \sim t$) is preceded by a transient regime. It is common…

Biological Physics · Physics 2021-08-12 Nicholas Ilow , Gary W. Slater

We develop an input delay-compensating feedback law for linear switched systems with time-dependent switching. Because the future values of the switching signal, which are needed for constructing an exact predictor-feedback law, may be…

Systems and Control · Electrical Eng. & Systems 2025-03-19 Andreas Katsanikakis , Nikolaos Bekiaris-Liberis , Delphine Bresch-Pietri

Transition path sampling is a rare-event method that estimates state-to-state timecorrelation functions in many-body systems from samples of short trajectories. In this framework, it is proposed to bias the importance function using the…

Chemical Physics · Physics 2015-03-13 Manuel Athènes , Mihai-Cosmin Marinica , Thomas Jourdan

Milestoning is a computational procedure that reduces the dynamics of complex systems to memoryless jumps between intermediates, or milestones, and only retains some information about the probability of these jumps and the time lags between…

Mathematical Physics · Physics 2017-03-14 Ling Lin , Jianfeng Lu , Eric Vanden-Eijnden

When a chemical reaction is driven by an external field, the transition state that the system must pass through as it changes from reactant to product -for example, an energy barrier- becomes time-dependent. We show that for periodic…

Chemical Physics · Physics 2015-05-01 Galen T. Craven , Thomas Bartsch , Rigoberto Hernandez

Computing long-timescale kinetics of biomolecular processes remains a major challenge for atomistic simulations. A way out is to exploit local kinetic information to construct the global stationary flux across the reaction space. The…

Chemical Physics · Physics 2026-05-19 Ru Wang , Xiaojun Ji , Hao Wang , Wenjian Liu

Simulations with an adaptive time-dependent bias, such as metadynamics, enable an efficient exploration of the conformational space of a system. However, the dynamic information of the system is altered by the bias. With infrequent…