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Density-functional theory (DFT) has revolutionized computer simulations in chemistry and material science. A faithful implementation of the theory requires self-consistent calculations. However, this effort involves repeatedly diagonalizing…

Quantum Physics · Physics 2023-07-17 Taehee Ko , Xiantao Li , Chunhao Wang

Adaptive perturbation is a new method for perturbatively computing the eigenvalues and eigenstates of quantum mechanical Hamiltonians that heretofore were not believed to be obtainable by such methods. The novel feature of adaptive…

High Energy Physics - Theory · Physics 2007-05-23 Marvin Weinstein

The combination of density functional theory with dynamical mean-field theory (DFT+DMFT) has become a powerful first-principles approach to tackle strongly correlated materials in condensed matter physics. The wide use of this approach…

Strongly Correlated Electrons · Physics 2022-05-10 Xin Qu , Peng Xu , Rusong Li , Gang Li , Lixin He , Xinguo Ren

We generalise the non-affine theory of viscoelasticity for use with large, well-sampled systems of arbitrary chemical complexity. Having in mind predictions of mechanical and vibrational properties of amorphous systems with atomistic…

Disordered Systems and Neural Networks · Physics 2020-07-27 Ivan Kriuchevskyi , Vladimir V. Palyulin , Rico Milkus , Robert M. Elder , Timothy W. Sirk , Alessio Zaccone

In the present work we have performed an ab initio calculation of vibrational properties of CuTe2O5 by means of density functional theory method. One has compared calculated values with known experimental data on Raman and infrared…

Materials Science · Physics 2015-06-22 Y. V. Lysogorskiy , R. M. Eremina , T. P. Gavrilova , O. V. Nedopekin , D. A. Tayurskii

In this paper, we consider an anharmonic perturbation to the harmonic oscillator in the classical and the quantum regimes. We analyse a relativistic particle subjected to such a potential and then proceed to study a gas of such particles.…

Quantum Physics · Physics 2018-06-27 Nikhil Kalyanapuram

We consider the Dirac equation with a generalized uncertainty principle in the presence of the Harmonic interaction and an external magnetic field. By doing the study in the momentum space, the problem solved in an exact analytical manner…

Quantum Physics · Physics 2014-01-23 Hassan Hassanabadi , Saber Zarrinkamar , Elham Maghsoodi

We prove that the theorems of TDDFT can be applied to a class of qubit Hamiltonians that are universal for quantum computation. The theorems of TDDFT applied to universal Hamiltonians imply that single-qubit expectation values can be used…

Quantum Physics · Physics 2011-08-20 David G. Tempel , Alan Aspuru-Guzik

Mean-field theories have proven to be efficient tools for exploring diverse phases of matter, complementing alternative methods that are more precise but also more computationally demanding. Conventional mean-field theories often fall short…

Strongly Correlated Electrons · Physics 2024-09-04 Junyi Zhang , Zhengqian Cheng

We present time-dependent density functional theory (TDDFT) calculations for single and dimerized Coumarin-343 molecules in order to investigate the quantum mechanical effects of chromophore aggregation in extended systems designed to…

Chemical Physics · Physics 2013-09-23 Donghyun Lee , Loren Greenman , Mohan Sarovar , K. Birgitta Whaley

A one-electron Schroedinger equation based on special one-electron potentials for atoms is shown to exist that produces orbitals for an arbitrary molecule that are sufficiently accurate to be used without modification to construct single-…

Chemical Physics · Physics 2022-05-16 Jerry L. Whitten

We present an accurate and efficient finite-difference formulation and parallel implementation of Kohn-Sham Density (Operator) Functional Theory (DFT) for non periodic systems embedded in a bulk environment. Specifically, employing…

Computational Physics · Physics 2020-11-30 Swarnava Ghosh , Kaushik Bhattacharya

The harmonic oscillator is one of the most studied systems in Physics with a myriad of applications. One of the first problems solved in a Quantum Mechanics course is calculating the energy spectrum of the simple harmonic oscillator with…

Classical Physics · Physics 2024-12-30 Murilo B. Alves

We present a new hybrid method to solve the relativistic Hartree-Fock-Roothan equations where the one- and two-electron radial integrals are evaluated numerically by defining the basis functions on a grid. This procedure reduces the…

Atomic Physics · Physics 2009-10-31 Rajat K. Chaudhuri , Prafulla K. Panda , B. P. Das

An algorithm for the calculation of hyperfine structure and spectra of diatomic molecules based on the variational nuclear motion is presented. Hyperfine coupling terms considered are Fermi-contact, nuclear spin-electron spin dipole-dipole,…

Chemical Physics · Physics 2022-02-15 Qianwei Qu , Sergei N. Yurchenko , Jonathan Tennyson

In this paper we examine how the predictions of conformal invariance can be widely exploited to overcome the difficulties of the density-matrix renormalization group near quantum critical points. The main idea is to match the set of…

Statistical Mechanics · Physics 2007-05-23 C. Degli Esposti Boschi , F. Ortolani

We develop a hybrid oscillator-qubit processor framework for quantum simulation of strongly correlated fermions and bosons that avoids the boson-to-qubit mapping overhead encountered in qubit hardware. This framework gives exact…

By modifying and generalizing known supersymmetric models we are able to find four different sets of one-dimensional Hamiltonians for the inverted harmonic oscillator. The first set of Hamiltonians is derived by extending the supersymmetric…

High Energy Physics - Theory · Physics 2019-02-05 R. D. Mota , D. Ojeda-Guillén , M. Salazar-Ramírez , V. D. Granados

Plane-wave electronic-structure predictions based upon orbital-dependent density-functional theory (OD-DFT) approximations, such as hybrid density-functional methods and self-interaction density-functional corrections, are severely affected…

Materials Science · Physics 2011-10-19 Yanli Li , Ismaila Dabo

We present in details a numerical approach for solving supersymmetric quantum mechanical systems with a gauge symmetry valid in all fermionic sectors. The method uses a recursive algorithm to calculate matrix elements of any gauge invariant…

High Energy Physics - Theory · Physics 2011-03-17 Piotr Korcyl