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Materials that exhibit high nonlinear optical (NLO) susceptibilities are considered as promising candidates for a wide range of photonic and electronic applications. Here we argue that the ferroelectric nematic (NF) materials have…

Soft Condensed Matter · Physics 2022-03-22 C. L. Folcia , J. Ortega , R. Vidal , T. Sierra , J. Etxebarria

Ferroelectric nematic fluids are promising materials for tunable nonlinear photonics, with applications ranging from second harmonic generation to sources of entangled photons. However, the few reported values of second-order…

The recent discovery of ferroelectric nematic liquid crystalline phases marks a major breakthrough in soft matter research. An intermediate phase, often observed between the nonpolar and the ferroelectric nematic phase, shows a distinct…

Ferroelectric nematic phase (NF) represents an attractive and foremost field of liquid crystals, combining fluidity with ferroelectricity. NF materials exhibit large polarization values and remarkable non-linear optical properties. We have…

Soft Condensed Matter · Physics 2026-03-06 Martin Cigl , Natalia Podoliak , Dalibor Repček , Pavlo Golub , Marta Lavrič , Vladimíra Novotná

The organic mesogens RM734 and DIO are members of separate molecular families featuring distinct molecular structures. These families, at the present time, are the only ones known to exhibit a ferroelectric nematic liquid crystal (LC)…

Fluid molecular ferroelectrics are a new class of organic materials where ferroelectricity is found in conjunction with 3D fluidity whilst still retaining spontaneous polarization values comparable to their traditional solid state…

Soft Condensed Matter · Physics 2026-02-19 Calum J Gibb , Jordan Hobbs , William C Ogle , Richard J Mandle

Nematic liquid crystals exhibit nanosecond electro-optic response to an applied electric field which modifies the degree of orientational order without realigning the molecular orientation. However, this nanosecond electrically-modified…

Soft Condensed Matter · Physics 2024-10-31 Kamal Thapa , Sathyanarayana Paladugu , Oleg D. Lavrentovich

Ferroelectric nematic (NF) liquid crystals combine liquid-like fluidity and orientational order of conventional nematics with macroscopic electric polarization comparable in magnitude to solid state ferroelectric materials. Here, we present…

Soft Condensed Matter · Physics 2025-02-04 Calum J. Gibb , Jordan Hobbs , Richard J. Mandle

The recently discovered ferroelectric nematic liquid-crystal material DIO exhibits an antiferroelectric (AF) phase, characterized by a sinusoidally modulated structure between the paraelectric (P) and ferroelectric (F) nematic phases.…

Soft Condensed Matter · Physics 2025-02-11 Hiroya Nishikawa , Péter Salamon , Marcell Tibor Máthé , Antal Jákli , Fumito Araoka

We have carried out a spectroscopic study on a prototype ferroelectric nematic material (RM7343) doped with a non-polar chiral compound. The mixture presents two chiral nematic phases, one conventional (N*) and the other polar (NF*), whose…

Soft Condensed Matter · Physics 2022-06-13 J. Ortega , C. L. Folcia , J. Etxebarria , T. Sierra

The recent discovery of a new ferroelectric nematic (NF) liquid crystalline phase became of utmost interest for the liquid crystal (LC) and the whole soft and condensed matter fields. Contrary to the previously known ferroelectric LC…

Recent experimental realization of ferroelectric nematic liquid crystalline phases stimulated material development and numerous experimental studies of these new phases, guided by their fundamental and applicative interest. In this…

Soft Condensed Matter · Physics 2022-08-18 Nerea Sebastián , Martin Čopič , Alenka Mertelj

The rapid advancement of communication technology necessitates the development of hybrid optical modulators that integrate silicon photonics with electro-optic (EO) materials to enable ultrafast, low-power, and compact photonic devices.…

We report the experimental determination of the structure and response to applied electric field of the lower-temperature nematic phase of the previously reported calamitic compound 4-[(4-nitrophenoxy)carbonyl]phenyl2,4-dimethoxybenzoate…

We report the smectic $A_F$, a new liquid crystal phase of the ferroelectric nematic realm. The smectic $A_F$ is a phase of small polar, rod-shaped molecules which form two-dimensional fluid layers spaced by approximately the mean molecular…

Since the recent discoveries, ferroelectric nematics became of upmost interest due to their outstanding ferroelectric properties. In this work, we prepared a series of polar molecules revealing a ferroelectric nematic phase (NF) with a very…

Ferroelectric nematic (NF) phase and related polar liquid-crystalline phases form a new class of strongly polarized yet fluid soft matter. Well-recognized heliconical ferroelectric phases such as NTBF and SmC_P^H exist, but their…

Soft Condensed Matter · Physics 2026-05-01 Hiroya Nishikawa , Dennis Kwaria , Atsuko Nihonyanagi , Koki Sano , Hiroyuki Yoshida , Fumito Araoka

Ferroelectric ordering in liquids is a fundamental question of physics. Here, we show that ferroelectric ordering of the molecules causes formation of recently reported splay nematic liquid-crystalline phase. As shown by dielectric…

We present a liquid-crystal laser device based on the chiral ferroelectric nematic phase (NF*). The laser medium is obtained by mixing a ferroelectric nematic material with a chiral agent and a small proportion of a fluorescent dye.…

A number of highly polar three ring rod-shaped compounds with a terminal thiophene ring have been synthesized and the physical properties of a subset are reported in detail. On cooling from the isotropic fluid, they directly transition to a…

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