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Using the velocity map imaging technique, we studied and characterized the process of Dissociative Electron Attachment (DEA) in polyatomic molecules like Water, Hydrogen Sulphide, Ammonia, Methane, Formic Acid and Propyl Amine. We present…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , V. S. Prabhudesai , E. Krishnakumar

Dissociative electron attachment (DEA) is one of the processes that shows a strong coupling between the nuclear and electronic degrees of freedom in a molecule. This coupling results in an efficient transformation of the kinetic energy of…

Chemical Physics · Physics 2024-04-17 Suvasis Swain , Akshay Kumar , E. Krishnakumar , Vaibhav S. Prabhudesai

We present a kinematically complete study of dissociative electron attachment (DEA) in linear OCS molecules, focusing on how electrons resonantly attach and trigger dissociation. Near the Franck-Condon regime, DEA is dominated by molecular…

Atomic and Molecular Clusters · Physics 2025-05-02 Narayan Kundu , Meenakshi Rana , Aryya Ghosh , Dhananjay Nandi

In the present study, dissociative electron attachment (DEA) measurements with gas phase HMX, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine, $C_4H_8N_8O_8$, have been performed by means of a crossed electron-molecular beam experiment.…

Dissociative electron attachment (DEA) shows functional group-dependent site selectivity in the $H^-$ ion channel. In this context, the thiol functional group has yet to be studied in great detail, although this functional group carries…

Chemical Physics · Physics 2024-04-17 Sukanta Das , Vaibhav S. Prabhudesai

Momentum imaging measurements from two experiments are presented and interpreted with the aid of new ab initio theoretical calculations to describe the dissociative electron attachment (DEA) dynamics. We address the problem of how the 4 eV…

Kinetic energy and angular distributions of O$^-$ ions formed by dissociative electron attachment to CO molecule have been studied for 9, 9.5, 10, 10.5, 11, 11.5 eV incident electron energies around the resonance using time sliced velocity…

Atomic and Molecular Clusters · Physics 2015-02-10 Pamir Nag , Dhananjay Nandi

An observed broad resonance peak in dissociative electron attachment (DEA) cross sections to a molecule might be due to either closely lying or overlapping resonances involved in the process. We developed a state-of-the-art experimental…

Chemical Physics · Physics 2015-06-09 Pamir Nag , Dhananjay Nandi

The Ni(CO)4, Cr(CO)6, Co(CO)3NO are some of the most common precursors used for the focused electron-induced deposition. Some of the compounds, even though extensively used have high requirements when it comes to handling, being explosives,…

Materials Science · Physics 2022-01-27 Maria Pintea , Nigel Mason , Maria Tudorovskaya

Dissociative electron attachment (DEA) is an important tool for investigating negative ion resonances. We have studied the negative ion resonances of H2 at 10 eV and 14 eV using the improved velocity slice imaging technique. We obtained…

In this article, density functional theory (DFT) and natural bond orbital (NBO) calculations are performed to understand experimental observations of dissociative electron attachment (DEA) to SO$_2$. The molecular structure, fundamental…

Atomic and Molecular Clusters · Physics 2018-07-09 Irina Jana , Sumit Naskar , Mousumi Das , Dhananjay Nandi

Motivated by the huge need of data for non-equilibrium plasma modeling, a theoretical investigation of dissociative electron attachment to the NO molecule is performed. The calculations presented here are based on the…

Atomic Physics · Physics 2020-12-02 V. Laporta , I. F. Schneider , J. Tennyson

Absolute cross sections for the formation of OH- from 2-propanol (CH3CH(OH)CH3) via dissociative electron attachment (DEA) are reported in the incident electron energy range of 3.5-13 eV. Four fragment anions are observed: OH-, C2H2O-,…

Atomic Physics · Physics 2026-02-20 Siddique Ali , Meeneskhi Rana , Soumya Ghosh , Narayan Kundu , Aryya Ghosh , Dhananjay Nandi

We report the detailed dynamics of the site selectivity observed in the dissociative electron attachment (DEA) process in ethanol based on the momentum images obtained using the velocity slice imaging technique. The H- dissociation channel…

Chemical Physics · Physics 2023-08-15 Sukanta Das , Suvasis Swain , Vaibhav S. Prabhudesai

In this paper, we discuss the dissociative electron attachment process in Ammonia. Kinetic energy and angular distributions of H^{-} and NH_{2}^{-} fragment anions across the two well known resonances at 5.5 eV and 10.5 eV are reported. The…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , E. Krishnakumar

A first-principle theoretical approach to study the process of radiative electron attachment is developed and applied to the negative molecular ions CN$^-$, C$_4$H$^-$, and C$_2$H$^-$. Among these anions, the first two have already been…

We report a computational study of the anion states of the resveratrol (RV) and resorcinol (RS) molecules, also investigating dissociative electron attachment (DEA) pathways. RV has well known beneficial effects in human health, and its…

Atomic Physics · Physics 2022-11-08 Ely G. F. de Miranda , Lucas M. Cornetta , Márcio T. do N. Varella

Low energy electron attachment to mixed (H$_2$)$_x$/(O$_2$)$_y$ clusters and their deuterated analogues has been investigated for the first time. These experiments were carried out using liquid helium nanodroplets to form the clusters, and…

Atomic and Molecular Clusters · Physics 2018-05-03 Michael Renzler , Lorenz Kranabetter , Erik Barwa , Lukas Grubwieser , Paul Scheier , Andrew M. Ellis

Complete dissociation dynamics of low energy electron attachment to ammonia molecule has been studied using velocity slice imaging (VSI) spectrometer. One low energy resonant peak around 5.5 eV and a broad resonance around 10.5 eV incident…

Atomic and Molecular Clusters · Physics 2019-09-11 Dipayan Chakraborty , Aranya Giri , Dhananjay Nandi

The HeH$^+$ cation is the simplest molecular prototype of the indirect dissociative recombination (DR) process that proceeds through electron capture into Rydberg states of the corresponding neutral molecule. This Letter develops the first…

Chemical Physics · Physics 2020-02-05 Roman Čurík , Dávid Hvizdoš , Chris H. Greene
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