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Germanium telluride (GeTe), a phase-change material, is known to exhibit four different structural phases: three at room temperature (one amorphous and two crystalline, $\alpha$ and $\gamma$) and one at high temperature (crystalline…

Single crystal synchrotron X-ray diffraction as a function of temperature and pressure has revealed a complex biphase mixture in superconducting FeSe. Based on our experimental results we construct a phase diagram where structural behavior…

Superconductivity · Physics 2017-08-02 V. Svitlyk , M. Raba , V. Dmitriev , P. Rodiere , P. Toulemonde , D. Chernyshov , M. Mezouar

Layered transition-metal trichalcogenides have become one of the research frontiers as two-dimensional magnets and candidate materials used for phase-change memory devices. Herein we report the high-pressure synchrotron X-ray diffraction…

Strongly Correlated Electrons · Physics 2019-06-03 Zhenhai Yu , Wei Xia , Kailang Xu , Ming Xu , Hongyuan Wang , Xia Wang , Na Yu , Zhiqiang Zou , Jinggeng Zhao , Lin Wang , Xiangshui Miao , Yanfeng Guo

Germanium antimony telluride has been the most used and studied phase-change material for electronic memory due to its suitable crystallization temperature, amorphous to crystalline resistance contrast, and stability of the amorphous phase.…

Materials Science · Physics 2020-01-23 Shalini Tripathi , Paul Kotula , Manish Singh , Chanchal Ghosh , Gokhan Bakan , Helena Silva , Barry Carter

Germanium is the base element in many phase-change materials, i.e. systems that can undergo reversible transformations between their crystalline and amorphous phases. They are widely used in current digital electronics and hold great…

Materials Science · Physics 2015-04-28 Celia Reina , Luis Sandoval , Jaime Marian

In the search for phase change materials (PCM) that may rival traditional random access memory, a complete understanding of the amorphous to crystalline phase transition is required. For the well-known Ge2Sb2Te5 (GST) and GeTe (GT)…

Materials Science · Physics 2015-06-19 James L. Bosse , Ilya Grishin , Bryan D. Huey , Oleg V. Kolosov

We study an insulator-metal transition in a ternary chalcogenide glass (GeSe$_3$)$_{1-x}$Ag$_x$ for $x$=0.15 and 0.25. The conducting phase of the glass is obtained by using "Gap Sculpting" (Prasai et al, Sci. Rep. 5:15522 (2015)) and it is…

Materials Science · Physics 2018-01-26 Kiran Prasai , Gang Chen , David Drabold

One of the most widely used active materials for phase-change memories (PCM), the ternary stoichiometric compound Ge$_2$Sb$_2$Te$_5$ (GST), has a low crystallization temperature of around 150$^\circ$C. One solution to achieve higher…

Materials Science · Physics 2024-09-11 Robin Miquel , Thomas Cabout , Olga Cueto , Benoît Sklénard , Mathis Plapp

The primary mechanism of optical memristive devices relies on the phase transitions between amorphous-crystalline states. The slow or energy hungry amorphous-crystalline transitions in optical phase-change materials are detrimental to the…

Crystalline phase transitions in two-dimensional materials enable precise control over electronic and ferroic properties, making them attractive materials for memory and energy storage applications. In$_2$Se$_3$ is particularly promising…

Materials Science · Physics 2026-03-03 Joseph L. Spellberg , Lina Kodaimati , Atreyie Ghosh , Prakriti P. Joshi , Sarah B. King

We harness non-volatile, amorphous-crystalline transitions in the chalcogenide phase-change medium germanium antimony telluride (GST) to realize optically-switchable, all-dielectric metamaterials. Nanostructured, subwavelength-thickness…

Mesoscale and Nanoscale Physics · Physics 2016-08-04 Artemios Karvounis , Behrad Gholipour , Kevin F. MacDonald , Nikolay I. Zheludev

Realization of superconductivity in Group IV semiconductors could have a strong impact in the direction quantum technologies will take in the future. Therefore, it is imperative to understand the nature of the superconducting phases in…

Disordering of solids typically leads to amorphization, but polymorph transitions, facilitated by favorable atomic rearrangements, may temporarily help to maintain long-range periodicity in the solid state. In far-from-equilibrium…

Ternary alloys of Ge-Sb-Te (GST) have been extensively studied due to their unique ability display a reversible change in their phase upon stimulation by optical pulses i.e., amorphous (a-GST) to crystalline (c-GST) and vice-versa. The two…

Materials Science · Physics 2022-06-17 Aditya Muralidharan

Phase change materials can be reversibly switched between amorphous and crystalline states and often show strong contrast in the optical and electrical properties of these two phases. They are now in widespread use for optical data storage,…

Mesoscale and Nanoscale Physics · Physics 2012-11-06 Nicholas P. Breznay , Hanno Volker , Alexander Palevski , Riccardo Mazzarello , Aharon Kapitulnik , Matthias Wuttig

Engineering phase change materials (PCM) to realize superior data storage devices requires a detailed understanding of crystallization kinetics and its temperature dependence. The temperature dependence of crystallization differs distinctly…

Materials Science · Physics 2021-03-12 Julian Pries , Julia Sehringer , Shuai Wei , Pierre Lucas , Matthias Wuttig

We examine the ultrafast optical response of the crystalline and amorphous phases of the phase change material Ge$_2$Sb$_2$Te$_5$ below the phase transformation threshold. Simultaneous measurement of the transmissivity and reflectivity of…

Materials Science · Physics 2016-07-19 Timothy A. Miller , Miquel Rudé , Valerio Pruneri , Simon Wall

We suggest a phenomenological description of the photo-conversion in Ge-Sb-Te phase-change memory alloys from amorphous to crystalline phase which explains why both photo-excitation and high temperatures T > 160C are required for the…

Materials Science · Physics 2016-01-20 S. M. Yakubenya , A. S. Mishchenko

We present a joint theoretical and experimental study to investigate polymorphism in $\alpha$-sexithiophene (6T) crystals. By means of density-functional theory calculations, we clarify that the low-temperature phase is favorable over the…

Materials Science · Physics 2016-06-29 Bernhard Klett , Caterina Cocchi , Linus Pithan , Stefan Kowarik , Claudia Draxl

Phase-change materials based on Ge-Sb-Te alloys are widely used in industrial applications such as nonvolatile memories, but reaction pathways for crystalline-to-amorphous phase-change on picosecond timescales remain unknown. Femtosecond…

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