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Precise characterization of the graphene/water interface has been hindered by experimental inconsistencies and limited molecular-level access to interfacial structures. In this work, we present a novel integrated computational approach that…

Chemical Physics · Physics 2026-02-10 Xianglong Du , Jun Cheng , Fujie Tang

Graphene supported on a substrate in contact with water underpins a wide range of processes and technologies, yet its wettability remains controversial. Understanding how substrate charges and graphene's properties influence water…

Chemical Physics · Physics 2025-11-11 Yongkang Wang , Yair Litman , Minhaeng Cho , Stephen Cox , Mischa Bonn

The lubricating ability of graphite largely depends on the environmental humidity, essentially the amount of water in between its layers. In general, intercalated molecules in layered materials modify their extraordinary properties by…

Materials Science · Physics 2019-01-09 A. Qadir , Y. W. Sun , W. Liu , P. Goldberg Oppenheimer , Y. Xu , C. J. Humphreys , D. J. Dunstan

Graphene-water interaction has been under scrutiny ever since graphene discovery and realization of its exceptional properties. Several computational and experimental reports exist that have tried to look into the interactions involved,…

Materials Science · Physics 2020-02-19 Priyanka Solanky , Vidushi Sharma , Kamalika Ghatak , Jatin Kashyap , Dibakar Datta

Understanding the interactions of ambient molecules with graphene and adjacent dielectrics is of fundamental importance for a range of graphene-based devices, particularly sensors, where such interactions could influence the operation of…

Mesoscale and Nanoscale Physics · Physics 2015-11-30 Eric J. Olson , Rui Ma , Tao Sun , Mona A. Ebrish , Nazila Haratipour , Kyoungmin Min , Narayana R. Aluru , Steven J. Koester

Using molecular dynamics simulations, we investigated an integrated bio-nano interface consisting of a \b{eta}-sheet protein stacked onto graphene. We found that the stacking assembly of the model protein on graphene could be controlled by…

Biological Physics · Physics 2014-12-17 Wenping Lv , Guiju Xu , Hongyan Zhang , Xin Li , Shengju Liu , Huan Niu , Dongsheng Xu , Renan Wu

Graphene-based membranes have been investigated as promising candidates for water filtration and gas separation applications. Experimental evidences have shown that graphene oxide can be impermeable to liquids, vapors and gases, while…

Materials Science · Physics 2017-02-02 Daiane D. Borges , Cristiano F. Woellner , Pedro A. S. Autreto , Douglas S. Galvao

This work describes the behaviour of water molecules in 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid under nanoconfinement between graphene sheets. By means of molecular dynamics simulations, an adsorption of water molecules…

Various properties of water are affected by confinement as the space-filling of the water molecules is very different from bulk water. In our study, we challenged the creation of a stable system in which water molecules are permanently…

Mesoscale and Nanoscale Physics · Physics 2026-04-28 Tim Verhagen , Jiri Klimes , Barbara Pacakova , Martin Kalbac , Jana Vejpravova

In this paper we investigate the hydrodynamic permeance of water through graphene-based membranes, inspired by recent experimental findings on graphene-oxide membranes. We consider the flow across multiple graphene layers having nanoslits…

Mesoscale and Nanoscale Physics · Physics 2016-06-16 Hiroaki Yoshida , Lydéric Bocquet

A computational investigation was carried out to understand the aggregation of nanoscale graphene with two typical assembly pathways of stacking assembly and sliding assembly in water. The interfacial-organized monolayer water film (MWF)…

Soft Condensed Matter · Physics 2013-04-16 Wenping Lv , Renan Wu

It is generally accepted that the hydrophilic property of graphene can be affected by the underlying substrate. However, the role of intrinsic vs. substrate contributions and the related mechanisms are vividly debated. Here we show that the…

New interlayer intermolecular potential model was proposed and it represented ``ABAB'' staking of graphite. Hydrogen atom sputtering on graphite surface was investigated using molecular dynamics simulation. In the initial short time period,…

Materials Science · Physics 2007-11-26 Atsushi Ito , Hiroaki Nakamura

The wetting properties of graphene have proven controversial and difficult to assess. The presence of a graphene layer on top of a substrate does not significantly change the wetting properties of the solid substrate, suggesting that a…

Soft Condensed Matter · Physics 2017-02-10 Bijoyendra Bera , Noushine Shahidzadeh , Himanshu Mishra , Daniel Bonn

The interlayer gallery between two adjacent sheets of van der Waals materials is expected to modify properties of atoms and molecules confined at the atomic interfaces. Here, we directly image individual hydrogen atom intercalated between…

Mesoscale and Nanoscale Physics · Physics 2018-02-14 Wen-Xiao Wang , Yi-Wen Wei , Si-Yu Li , Xinqi Li , Xiaosong Wu , Ji Feng , Lin He

The air-water and graphene-water interfaces represent quintessential examples of the liquid-gas and liquid-solid boundaries, respectively. While the sum-frequency generation (SFG) spectra of these interfaces exhibit certain similarities, a…

Because of the dominant role of the surface of molecules and their individuality, molecules behave dis-tinctively in a confined space, which has far-reaching implications in many physical, chemical and bio-logical systems. Here, we…

Mesoscale and Nanoscale Physics · Physics 2014-04-29 DaeEung Lee , Gwanghyun Ahn , Sunmin Ryu

Water behaves very differently at surfaces and under extreme confinement, but the boundary between these two regimes has remained unclear. Despite evidence that interfacial effects persist under sub-nanometre confinement, the…

Chemical Physics · Physics 2025-12-15 Xavier R. Advincula , Christoph Schran , Angelos Michaelides

The interfacial behaviour of water remains a central question to fields as diverse as protein folding, friction and ice formation[1,2]. While the structural and dynamical properties of water at interfaces differ strongly from those in the…

Understanding the phase behaviors of nanoconfined water has driven notable research interests recently. In this work, we examine the structures and thermodynamics of water encapsulated under a graphene cover. We find layered water…

Statistical Mechanics · Physics 2016-07-19 Shuping Jiao , Chuanhua Duan , Zhiping Xu
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